Microstructured fiber interface coatings for composites
Disclosed is a coated ceramic fiber including a silicon carbide coating layer adjacent to the ceramic fiber and a silicon dioxide coating layer adjacent to the silicon carbide coating layer, wherein the silicon dioxide coating layer forms micro cracks after a crystal structure transformation. The coated ceramic fiber may be included in a composite material having a ceramic matrix.
1. A coated ceramic fiber comprising:
a silicon carbide coating layer adjacent to the ceramic fiber, a portion of the silicon carbide layer oxidized to form amorphous silicon dioxide, and
a silicon dioxide coating layer adjacent to the silicon carbide coating layer, the silicon dioxide coating layer including the amorphous silicon dioxide,
an additional coating layer adjacent to the silicon dioxide coating layer;
wherein the silicon dioxide coating layer forms micro cracks after a crystal structure transformation;
wherein the additional coating layer does not include silicon carbide; and
wherein the silicon dioxide coating layer includes silicon dioxide in β cristobalite form which forms micro cracks after transforming to α cristobalite form.
2. The coated ceramic fiber of claim 1 , wherein the silicon dioxide coating layer has a thickness of 50 nm to 10,000 nm.
3. The coated ceramic fiber of claim 1 , wherein the silicon carbide coating layer has a thickness of 1000 nm to 20,000 nm.
4. A composite material comprising:
a ceramic matrix material and a plurality of ceramic fibers embedded within the ceramic matrix material;
wherein the plurality of ceramic fibers comprise a multi-layer interface coating and the multi-layer interface coating comprises a silicon carbide coating layer adjacent to the plurality of ceramic fibers, a portion of the silicon carbide layer oxidized to form amorphous silicon dioxide, and
a silicon dioxide coating layer deposited onto the silicon carbide coating layer, the silicon dioxide coating layer including the amorphous silicon dioxide,
an additional coating layer adjacent to the silicon dioxide coating layer;
wherein the silicon dioxide coating layer forms micro cracks after a crystal structure transformation;
wherein the additional coating layer does not include silicon carbide; and
wherein the silicon dioxide coating layer includes silicon dioxide in β cristobalite form which forms micro cracks after transforming to α cristobalite form.
5. The composite material of claim 4 , wherein the silicon dioxide coating layer has a thickness of 50 nm to 10,000 nm.
6. The composite material of claim 4 , wherein the silicon carbide coating layer has a thickness of 1000 nm to 20,000 nm.
7. The coated ceramic fiber of claim 1 , wherein the additional coating layer comprises zirconium or zirconium boride or combinations thereof.
8. The composite material of claim 4 , wherein the additional coating layer comprises zirconium or zirconium boride or combinations thereof.
9. A method for forming a multi-layer interface coating onto a ceramic fiber comprising:
depositing a silicon carbide coating layer onto the fiber,
oxidizing a portion of the silicon carbide coating layer to form an amorphous silicon dioxide coating layer, and
depositing an additional coating layer on the silicon dioxide coating layer; and
crystallizing the amorphous silicon dioxide layer to beta cristobalite;
wherein the additional coating layer does not include silicon carbide; and
wherein the beta cristobalite forms micro cracks in the silicon dioxide coating layer after transforming to a cristobalite form.