IP Library Granted Patent US 10,752,554
Granted Patent B1
US 10,752,554 · App. 16/690,367 · Granted Aug 25, 2020

Intermetallic matrix composite

Inventors: Dilip M. Shah (Glastonbury, CT); Venkatarama K. Seetharaman (Rocky Hill, CT)
Assignee: Raytheon Technologies Corporation
C04B35/58092C04B14/303C04B14/324C04B41/51
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Quick Facts
Patent No.
US 10,752,554
App. No.
16/690,367
Granted
Aug 25, 2020
Kind
B1
Abstract

An intermetallic matrix composite has an intermetallic matrix and a ceramic reinforcement. The intermetallic matrix comprises, in atomic percent: 28.0±2.0 Nb; 27.0±2.0 Mo; 27.0±2.0 Cr; 9.0 ±2.0 Si; 9.0 ±2.0 Al; and no more than 10.0 other alloying elements and impurities, if any.

Claims (53)

1. An intermetallic matrix composite comprising:

an intermetallic matrix; and

a ceramic reinforcement,

wherein the intermetallic matrix comprises, in atomic percent:

28.0±2.0 Nb;

27.0±2.0 Mo;

27.0±2.0 Cr;

9.0 ±2.0 Si;

9.0 ±2.0 Al; and

no more than 10.0 other alloying elements and impurities, if any.

2. The intermetallic matrix composite of claim 1 wherein the intermetallic matrix comprises a eutectic wherein two phases combine to form at least 60% by volume of the matrix and each is at least 25% by volume of the matrix.

3. The intermetallic matrix composite of claim 2 wherein the two phases are:

a first phase being of the type Cr 2 Nb with C14/C15 crystal structure; and

a second phase being of the type Cr 3 Si with A15 crystal structure.

4. The intermetallic matrix composite of claim 3 wherein the intermetallic matrix comprises a third phase forming 25% to 35% by volume of the matrix and comprising:

a majority by weight and volume Nb—Cr—Mo solid solution with A2 structure.

5. The intermetallic matrix composite of claim 1 wherein the intermetallic matrix comprises, in atomic percent:

28.0±1.0 Nb;

27.0±1.0 Mo;

27.0±1.0 Cr;

9.0±1.0 Si; and

9.0±1.0 Al.

6. The intermetallic matrix composite of claim 1 wherein the intermetallic matrix further comprises for said other alloying elements, in atomic percent:

0.2 to 2.0 Sn.

7. The intermetallic matrix composite of claim 1 wherein the intermetallic matrix further comprises for said other alloying elements, in atomic percent:

0.2 to 2.0 Re.

8. The intermetallic matrix composite of claim 1 wherein the intermetallic matrix further comprises for said other alloying elements, in atomic percent:

0.2 to 2.0 Sn and 0.2 to 2.0 Re.

9. The intermetallic matrix composite of claim 1 wherein the intermetallic matrix further comprises, in atomic percent:

no more than 5.0 total all other refractory elements and no more than 1.0 individual all other transition metals.

10. The intermetallic matrix composite of claim 1 wherein the intermetallic matrix is:

Nb-27Mo-27Cr-9Al-9Si (in at. %).

11. The intermetallic matrix composite of claim 1 wherein the intermetallic matrix has a melting point of:

3100° F. to 3400° F.

12. The intermetallic matrix composite of claim 1 wherein the ceramic reinforcement comprises:

alumina.

13. The intermetallic matrix composite of claim 1 wherein the ceramic reinforcement comprises:

coated SiC fiber.

14. The intermetallic matrix composite of claim 13 wherein the coating on the SiC fiber comprises:

at least one of mullite and alumina.

15. The intermetallic matrix composite of claim 1 wherein the ceramic reinforcement comprises:

a woven preform.

16. The intermetallic matrix composite of claim 1 wherein the ceramic reinforcement comprises:

fibers coated with A15(Cr 3 Si) phase-forming metallic elements replacing Si sites.

17. A turbine engine component comprising a body of the intermetallic matrix composite of claim 1 .

18. The turbine engine component of claim 17 further comprising:

a silicide coating on the body.

19. A method for manufacturing the intermetallic matrix composite of claim 1 , the method comprising:

providing a preform of the ceramic reinforcement;

infiltrating the preform with molten alloy at a temperature of 3100° F. to 3400° F.; and

allowing the alloy to solidify to from the intermetallic matrix.

20. The method of claim 19 wherein:

the infiltration is a vacuum infiltration or a pressure-assisted infiltration.

Assignments (4)
CHANGE OF NAME Recorded Jul 27, 2023
From: RAYTHEON TECHNOLOGIES CORPORATION
To: RTX CORPORATION
Reel/Frame 064714/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE SPELLING ON THE ADDRESS 10 FARM SPRINGD ROAD FARMINGTONCONNECTICUT 06032 PREVIOUSLY RECORDED ON REEL 057190 FRAME 0719. ASSIGNOR(S) HEREBY CONFIRMS THE CORRECT SPELLING OF THE ADDRESS 10 FARM SPRINGS ROAD FARMINGTON CONNECTICUT 06032. Recorded Aug 19, 2021
From: UNITED TECHNOLOGIES CORPORATION
To: RAYTHEON TECHNOLOGIES CORPORATION
Reel/Frame 057226/0390 →
CHANGE OF NAME Recorded Aug 16, 2021
From: UNITED TECHNOLOGIES CORPORATION
To: RAYTHEON TECHNOLOGIES CORPORATION
Reel/Frame 057190/0719 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 21, 2019
From: SHAH, DILIP M.; SEETHARAMAN, VENKATARAMA K.
To: UNITED TECHNOLOGIES CORPORATION
Reel/Frame 051074/0880 →