IP Library Granted Patent US 11,370,021
Granted Patent B2
US 11,370,021 · App. 16/691,670 · Granted Jun 28, 2022

Systems, formulations, and methods for removal of ceramic cores from turbine blades after casting

Inventors: Lei Jin (Unionville, CT); Ryan C. Breneman (Newington, CT); David Brayshaw (Glastonbury, CT)
Assignee: Raytheon Technologies Corporation
B22D29/002B22D29/003C23F11/124
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Quick Facts
Patent No.
US 11,370,021
App. No.
16/691,670
Granted
Jun 28, 2022
Kind
B2
Abstract

A solution is provided includes a strong base, a corrosion inhibitor, wherein the strong base is an alkali metal hydroxide, wherein the corrosion inhibitor is at least one of an organic acid having a-COOH functional group or an alkali metal salt of one of an organic acid having a-COOH functional group.

Claims (17)

1. A method comprising:

placing a metallic aircraft part having a ceramic material disposed therein into a vessel;

placing a solution into the vessel, the solution comprising:

a strong base; and

a corrosion inhibitor,

wherein the strong base is an alkali metal hydroxide,

wherein the corrosion inhibitor is at least one of an organic acid having a-COOH functional group or an alkali metal salt of one of an organic acid having a-COOH functional group, and

wherein the corrosion inhibitor is at least one of tartaric acid, sodium tartrate, citric acid, acetic acid, oxalic acid, malic acid, maleic acid, lactic acid, glycine, L-histidine, or DETPA (Diethylenetriaminepentaacetate),

wherein the strong base has a first concentration of between 5.54M to 11.09M.

2. The method of claim 1 , further comprising heating the vessel to an elevated temperature.

3. The method of claim 2 , further comprising increasing the pressure within the vessel to above atmospheric pressure.

4. The method of claim 3 , further comprising holding the vessel at the elevated temperature and above atmospheric pressure for between four hours and ninety six hours.

5. The method of claim 3 , further comprising holding the vessel at the elevated temperature and above atmospheric pressure until substantially all the ceramic material has dissolved.

6. The method of claim 3 , wherein the strong base is at least one of sodium hydroxide or potassium hydroxide.

7. The method of claim 1 , further comprising a solubility enhancer wherein the solubility enhancer is Ethylenediaminetetraacetic acid (EDTA).

8. The method of claim 7 , wherein the strong base is KOH.

9. The method of claim 8 , wherein the corrosion inhibitor is sodium tartrate, wherein the sodium tartrate has a second concentration of between 1 mg/L and 100 g/L.

Assignments (4)
CHANGE OF NAME Recorded Jul 27, 2023
From: RAYTHEON TECHNOLOGIES CORPORATION
To: RTX CORPORATION
Reel/Frame 064714/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE SPELLING ON THE ADDRESS 10 FARM SPRINGD ROAD FARMINGTONCONNECTICUT 06032 PREVIOUSLY RECORDED ON REEL 057190 FRAME 0719. ASSIGNOR(S) HEREBY CONFIRMS THE CORRECT SPELLING OF THE ADDRESS 10 FARM SPRINGS ROAD FARMINGTON CONNECTICUT 06032. Recorded Aug 19, 2021
From: UNITED TECHNOLOGIES CORPORATION
To: RAYTHEON TECHNOLOGIES CORPORATION
Reel/Frame 057226/0390 →
CHANGE OF NAME Recorded Aug 16, 2021
From: UNITED TECHNOLOGIES CORPORATION
To: RAYTHEON TECHNOLOGIES CORPORATION
Reel/Frame 057190/0719 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 22, 2019
From: JIN, LEI; BRENEMAN, RYAN C; BRAYSHAW, DAVID
To: UNITED TECHNOLOGIES CORPORATION
Reel/Frame 051095/0144 →