Systems, formulations, and methods for removal of ceramic cores from turbine blades after casting
A solution is provided includes a strong base, a corrosion inhibitor, wherein the strong base is an alkali metal hydroxide, wherein the corrosion inhibitor is at least one of an organic acid having a-COOH functional group or an alkali metal salt of one of an organic acid having a-COOH functional group.
1. A method comprising:
placing a metallic aircraft part having a ceramic material disposed therein into a vessel;
placing a solution into the vessel, the solution comprising:
a strong base; and
a corrosion inhibitor,
wherein the strong base is an alkali metal hydroxide,
wherein the corrosion inhibitor is at least one of an organic acid having a-COOH functional group or an alkali metal salt of one of an organic acid having a-COOH functional group, and
wherein the corrosion inhibitor is at least one of tartaric acid, sodium tartrate, citric acid, acetic acid, oxalic acid, malic acid, maleic acid, lactic acid, glycine, L-histidine, or DETPA (Diethylenetriaminepentaacetate),
wherein the strong base has a first concentration of between 5.54M to 11.09M.
2. The method of claim 1 , further comprising heating the vessel to an elevated temperature.
3. The method of claim 2 , further comprising increasing the pressure within the vessel to above atmospheric pressure.
4. The method of claim 3 , further comprising holding the vessel at the elevated temperature and above atmospheric pressure for between four hours and ninety six hours.
5. The method of claim 3 , further comprising holding the vessel at the elevated temperature and above atmospheric pressure until substantially all the ceramic material has dissolved.
6. The method of claim 3 , wherein the strong base is at least one of sodium hydroxide or potassium hydroxide.
7. The method of claim 1 , further comprising a solubility enhancer wherein the solubility enhancer is Ethylenediaminetetraacetic acid (EDTA).
8. The method of claim 7 , wherein the strong base is KOH.
9. The method of claim 8 , wherein the corrosion inhibitor is sodium tartrate, wherein the sodium tartrate has a second concentration of between 1 mg/L and 100 g/L.