Systems and methods for fluoride ceramic phosphors for LED lighting
The present disclosure relates to a lighting component which may comprise a light emitting diode (LED) or laser diode (LD) for generating at least one of blue light or ultraviolet light. A fluoride phosphor matrix may be included, which may be consolidated into a phosphor ceramic structure including at least one of a transparent fluoride ceramic structure or a translucent fluoride ceramic structure, and positioned adjacent to the LED or LD. The phosphor ceramic structure generates at least one of red or orange light when irradiated by the light emitted from the LED or LD. The phosphor ceramic structure exhibits reduced thermal quenching relative to a fluoride particulate structure irradiated by the LED or LD.
1. An LED component comprising:
a light emitting diode configured to generate a first wavelength comprising blue light; and
a single-layered phosphor composite structure positioned adjacent to the LED, the single-layered phosphor composite structure comprising:
a fluoride phosphor matrix configured to emit light at a second wavelength comprising orange or red light when irradiated by the first wavelength, and
a plurality of distinct additional phosphor particles homogenously integrated within the fluoride phosphor matrix, the distinct additional phosphor particles configured to emit light at a third wavelength that is different from the second wavelength when irradiated by the first wavelength, the third wavelength comprising cyan, green, or yellow light,
wherein a first amount of relative photon emission of the single-layered phosphor composite structure and a second amount of relative photon emission of the light emitting diode together generate white light, the first amount being greater than the second amount, and the first amount including a third amount of relative photon emission of the fluoride phosphor matrix and a fourth amount of relative photon emission of the distinct additional phosphor particles, the fourth amount being greater than the third amount.
2. The LED component of claim 1 , wherein the fluoride phosphor matrix includes a cubic or near-cubic K 2 PtCl 6 structure type.
3. The LED component of claim 1 , wherein the fluoride phosphor matrix comprises M 2 M′F 6 , where M is selected from the group consisting of: Li, Na, K, Rb, Cs, and combinations thereof, and M′ is selected from the group consisting of: Si, Ge, Sn, Ti, Zr, Hf, and combinations thereof.
4. The LED component of claim 1 , wherein the fluoride phosphor matrix comprises: K 2 SiF 6 , Li 2 SiF 6 , Na 2 SiF 6 , Rb 2 SiF 6 , Cs 2 SiF 6 , K 2 GeF 6 , Li 2 GeF 6 , Na 2 GeF 6 , Rb 2 GeF 6 , Cs 2 GeF 6 , Li 2 SnF 6 , Na 2 SnF 6 , Rb 2 SnF 6 , Cs 2 SnF 6 , K 2 ZrF 6 , Li 2 ZrF 6 , Na 2 ZrF 6 , Rb 2 ZrF 6 , Cs 2 ZrF 6 , K 2 HfF 6 , Li 2 HfF 6 , Na 2 HfF 6 , Rb 2 HfF 6 , Cs 2 HfF 6 , K 2 TiF 6 , Li 2 TiF 6 , Na 2 TiF 6 , Rb 2 TiF 6 , Cs 2 TiF 6 , or any mixtures or solid solutions thereof.
5. The LED component of claim 1 , wherein the fluoride phosphor matrix is doped with Mer.
6. The LED component of claim 5 , wherein a Mn 4+ doping level is between 0.01% to 30%.
7. The LED component of claim 5 , wherein the Mn 4+ doping level is between 0.01% and 5%.
8. The LED component of claim 1 , wherein the single-layered phosphor composite structure is formed by heating the fluoride phosphor matrix to a temperature above room temperature and below a melting or decomposition temperature of the fluoride phosphor matrix while under pressure, the pressure being applied by a hot-press.
9. The LED component of claim 1 , wherein the plurality of distinct additional phosphor particles comprises an oxide phosphor, the oxide phosphor including Ce-doped (Lu,Gd,Y) 3 (Al,Ga) 5 O 12 garnet compounds.
10. The LED component of claim 1 , wherein the plurality of distinct additional phosphor particles comprises an oxide phosphor, a nitride phosphor, an oxynitride phosphor, a sulfide phosphor, an oxysulfide phosphor, a selenide phosphor, or any combination thereof.
11. The LED component of claim 1 , wherein the single-layered phosphor composite structure is disposed in a heat-sink structure that is configured to remove heat from the single-layered phosphor composite structure.
12. The LED component of claim 1 , wherein the thermal conductivity of the single-layered phosphor composite structure exhibits a value of about k ˜1.0 W/m-K at 25° C.
13. The LED component of claim 1 , further comprising another phosphor in contact or not in contact with a surface of the single-layered phosphor composite structure as further distinct particles, the another phosphor emits light at a fourth wavelength that is different from the first and second wavelengths, the third wavelength is selected from the colors cyan, green or yellow.
14. The LED component of claim 13 , wherein the further distinct particles of the another phosphor are incorporated into an organic binder, and the organic binder comprises a polymer.
15. The LED component of claim 1 , wherein the single-layered phosphor composite structure has a density of 90% of a full density.
16. The LED component of claim 1 , wherein the single-layered phosphor composite structure has a density of 99% of a full density.
17. The LED component of claim 1 , wherein the third amount is greater than the second amount and the fourth amount is greater than the second amount.
18. The LED component of claim 1 ; wherein the first amount is about 87% and the second amount is about 13%.
19. The LED component of claim 1 , wherein the second amount is about 13%, the third amount is about 31%, and the fourth amount is about 56%.
20. The LED component of claim 1 , wherein the plurality of distinct additional phosphor particles is a first plurality of distinct additional phosphor particles and the single-layered phosphor composite structure further comprises a second plurality of distinct additional phosphor particles homogeneously integrated within the fluoride phosphor matrix, the second plurality of additional phosphor particles configured to emit light at a fourth wavelength that is different from the second wavelength and the third wavelength when irradiated by the first wavelength.
21. The LED component of claim 20 , wherein the third wavelength comprises green or yellow and the fourth wavelength comprises cyan.
22. A laser diode-based lighting component comprising:
a laser diode (LD) configured to generate a first wavelength comprising blue light; and
a single integrated phosphor composite structure positioned adjacent to the LD, the single integrated phosphor composite ceramic structure comprising:
a transparent or translucent fluoride phosphor ceramic configured to emit light at a second wavelength comprising orange or red light when irradiated by the first wavelength; and
a plurality of distinct phosphor particles homogeneously integrated within the fluoride phosphor ceramic, the distinct phosphor particles configured to emit light at a third second wavelength that is different from the second wavelength when irradiated by the first wavelength, the third wavelength comprising colors cyan, green, or yellow light,
wherein a first amount of relative photon emission of the single-layered phosphor composite structure and a second amount of relative photon emission of the laser diode together generate white light, the first amount being greater than the second amount, and the first amount including a third amount of relative photon emission of the fluoride phosphor ceramic and a fourth amount of relative photon emission of the distinct additional phosphor particles, the fourth amount being greater than the third amount.
23. The laser diode-based lighting component of claim 22 , wherein the LD is disposed adjacent to a minor length of the single integrated phosphor composite structure, generally perpendicular to an axis extending along a major length of the single integrated phosphor composite ceramic structure.
24. A laser diode excited phosphor comprising:
a single-layered integrated composite structure comprising:
a fluoride phosphor matrix configured to emit light at a first wavelength comprising orange or red light,
a plurality of additional phosphor particles homogeneously integrated within the fluoride phosphor matrix, the plurality of additional phosphor particles configured to emit light at a second wavelength that is different from the first wavelength, the second wavelength comprising colors cyan, green, or yellow light,
wherein the single-layered integrated composite structure is substantially free of an organic binder,
wherein the single-layered integrated composite structure is configured to be disposed adjacent to a laser diode excitation light source that emits light of a third wavelength that is different from the first and second wavelengths, the third wavelength comprising blue light, and
wherein the single-layered integrated ceramic structure is configured to modify the light of the third wavelength passing therethrough to emit white light, wherein the white light includes a first amount of relative photon emission of the single-layered integrated composite structure and a second amount of relative photon emission of the laser diode excitation light source, the first amount being greater than the second amount, and the first amount including a third amount of relative photon emission of the fluoride phosphor matrix and a fourth amount of relative photon emission of the distinct additional phosphor particles, the fourth amount being greater than the third amount.
25. The light emitting device of claim 24 , wherein the device further comprises at least one of additional phosphors, heat-sinks, electrical power conversion modules, arrays of additional blue light emitting diodes (LEDs), fixturing, electrodes for electrical contact, means physical support, and secondary optical components.
26. A light emitting component comprising:
a light emitting diode (LED) or laser diode (LD) operable to emit blue;
a phosphor ceramic adjacent to the light emitting diode or laser diode and operable to emit orange or red, the phosphor ceramic comprising K 2 SiF 6 :Mn +4 ; and
a plurality of phosphor particles homogeneously dispersed in the phosphor ceramic and operable to emit cyan, green, or yellow,
wherein the blue emitted by the light emitting diode or laser diode, the orange or red emitted by the phosphor ceramic, and the cyan, green, or yellow emitted by the plurality of phosphor particles together generate a white light, a relative photon emission of the light emitting diode or laser diode being less than a relative photon emission of the phosphor ceramic, and the relative photon emission of the phosphor ceramic being less than a relative photon emission of the plurality of phosphor particles.
27. The light emitting component of claim 26 , wherein the plurality of phosphor particles comprises Ce-doped garnet particles.
28. The light emitting component of claim 27 , wherein the Ce-doped garnet particles comprise YAG:Ce particles.