IP Library Granted Patent US 11,333,987
Granted Patent B2
US 11,333,987 · App. 16/700,363 · Granted May 17, 2022

Fluorine-containing resin particle, composition, layer-shaped article, electrophotographic photoreceptor, process cartridge, and image forming apparatus

Inventors: Wataru Yamada (Kanagawa, JP); Masahiro Iwasaki (Kanagawa, JP); Ryosuke Fujii (Kanagawa, JP); Keisuke Kusano (Kanagawa, JP); Yuto Okazaki (Kanagawa, JP); Taisuke Fukui (Kanagawa, JP)
Assignee: FUJIFILM Business Innovation Corp.
G03G5/071C08F114/26C08K5/16C08K5/17C08L27/12C08L27/14C08L27/16C08L27/18C08L27/20G03G5/056G03G15/75G03G21/1803
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,333,987
App. No.
16/700,363
Granted
May 17, 2022
Kind
B2
Abstract

A fluorine-containing resin particle contains 0 or more and 30 or less carboxyl groups per 10 6 carbon atoms and 0 ppm or more and 3 ppm or less of a basic compound.

Claims (33)

1. A fluorine-containing resin particle comprising:

7 or more and 30 or less carboxyl groups per 10 6 carbon atoms; and

0 ppm or more and 3 ppm or less of a basic compound,

wherein the fluorine-containing resin particles are selected from the group consisting of polytetrafluoroethylene (PTFE) particles, tetrafluoroethylene-hexafluoropropylene copolymer (FEP) particles, tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer (PFA) particles, ethylene-tetrafluoroethylene copolymer (ETFE) particles, and ethylene-chlorotrifluoroethylene copolymer (ECTFE) particles, and

wherein the basic compound is an amine compound.

2. The fluorine-containing resin particle according to claim 1 , comprising:

7 or more and 20 or less carboxyl groups per 10 6 carbon atoms.

3. The fluorine-containing resin particle according to claim 1 , comprising:

7 or more and 20 or less carboxyl groups per 10 6 carbon atoms; and

0 ppm or more and 1.5 ppm or less of the basic compound.

4. The fluorine-containing resin particle according to claim 1 , wherein the amine compound has a boiling point of 40° C. or more and 130° C. or less.

5. The fluorine-containing resin particle according to claim 1 , comprising 0 ppb or more and 25 ppb or less of perfluorooctanoic acid.

6. The fluorine-containing resin particle according to claim 5 , comprising 0 ppb or more and 20 ppb or less of perfluorooctanoic acid.

7. The fluorine-containing resin particle according to claim 1 , wherein the fluorine-containing resin particle is obtained without performing irradiation during a production process.

8. A composition comprising:

fluorine-containing resin particles;

a binder resin; and

a charge transporting material,

wherein the fluorine-containing resin particles comprise:

0 or more and 30 or less carboxyl groups per 10 6 carbon atoms, and

0 ppm or more and 3 ppm or less of a basic compound.

9. The composition according to claim 8 , wherein the composition is liquid or solid.

10. A layer-shaped article comprising the fluorine-containing resin particle according to claim 1 .

11. The fluorine-containing resin particle according to claim 1 , wherein an average particle diameter of the fluorine-containing resin particle is from 0.2 μm to 4.5 μm, a BET specific surface area of the fluorine-containing resin particle is from 5 m 2 /g to 15 m 2 /g, and an apparent density of the fluorine-containing resin particle is from 0.2 g/ml to 0.5 g/ml.

12. The fluorine-containing resin particle according to claim 1 , wherein the fluorine-containing resin particle has a fluorine atom-containing dispersant attached to a surface thereof.

13. The fluorine-containing resin particle according to claim 12 , wherein the fluorine-containing dispersant is a fluorinated alkyl group-containing polymer having a structural unit represented by formula (FA) below:

wherein, in formulae (FA), each R F1 independently represents a hydrogen atom or an alkyl group, each Q F1 independently represents —O— or —NH—, fl represents an integer of 1 or more, each fp independently represents 0 or an integer of 1 or more, and each ft independently represents an integer of 1 or more and 7 or less.

14. The composition according to claim 8 , comprising:

7 or more and 20 or less carboxyl groups per 10 6 carbon atoms;

0 ppm or more and 1.5 ppm or less of the basic compound; and

0 ppb or more and 20 ppb or less of perfluorooctanoic acid,

wherein the fluorine-containing resin particles are selected from the group consisting of polytetrafluoroethylene (PTFE) particles, tetrafluoroethylene-hexafluoropropylene copolymer (FEP) particles, tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer (PFA) particles, ethylene-tetrafluoroethylene copolymer (ETFE) particles, and ethylene-chlorotrifluoroethylene copolymer (ECTFE) particles, and

wherein the basic compound is an amine compound.

Assignments (2)
CHANGE OF NAME Recorded Apr 29, 2021
From: FUJI XEROX CO., LTD.
To: FUJIFILM BUSINESS INNOVATION CORP.
Reel/Frame 056092/0913 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 2, 2019
From: YAMADA, WATARU; IWASAKI, MASAHIRO; FUJII, RYOSUKE; KUSANO, KEISUKE; OKAZAKI, YUTO; FUKUI, TAISUKE
To: FUJI XEROX CO., LTD.
Reel/Frame 051152/0148 →
Priority Claims (2)
JP JP2019-020758 · Feb 7, 2019 · national
JP JP2019-173181 · Sep 24, 2019 · national
Continuity (1)
Related Publication 20200257210A1 · Aug 13, 2020