Fluorine-containing resin particle, composition, layer-shaped article, electrophotographic photoreceptor, process cartridge, and image forming apparatus
A fluorine-containing resin particle contains 0 or more and 30 or less carboxyl groups per 10 6 carbon atoms and 0 ppm or more and 3 ppm or less of a basic compound.
1. A fluorine-containing resin particle comprising:
7 or more and 30 or less carboxyl groups per 10 6 carbon atoms; and
0 ppm or more and 3 ppm or less of a basic compound,
wherein the fluorine-containing resin particles are selected from the group consisting of polytetrafluoroethylene (PTFE) particles, tetrafluoroethylene-hexafluoropropylene copolymer (FEP) particles, tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer (PFA) particles, ethylene-tetrafluoroethylene copolymer (ETFE) particles, and ethylene-chlorotrifluoroethylene copolymer (ECTFE) particles, and
wherein the basic compound is an amine compound.
2. The fluorine-containing resin particle according to claim 1 , comprising:
7 or more and 20 or less carboxyl groups per 10 6 carbon atoms.
3. The fluorine-containing resin particle according to claim 1 , comprising:
7 or more and 20 or less carboxyl groups per 10 6 carbon atoms; and
0 ppm or more and 1.5 ppm or less of the basic compound.
4. The fluorine-containing resin particle according to claim 1 , wherein the amine compound has a boiling point of 40° C. or more and 130° C. or less.
5. The fluorine-containing resin particle according to claim 1 , comprising 0 ppb or more and 25 ppb or less of perfluorooctanoic acid.
6. The fluorine-containing resin particle according to claim 5 , comprising 0 ppb or more and 20 ppb or less of perfluorooctanoic acid.
7. The fluorine-containing resin particle according to claim 1 , wherein the fluorine-containing resin particle is obtained without performing irradiation during a production process.
8. A composition comprising:
fluorine-containing resin particles;
a binder resin; and
a charge transporting material,
wherein the fluorine-containing resin particles comprise:
0 or more and 30 or less carboxyl groups per 10 6 carbon atoms, and
0 ppm or more and 3 ppm or less of a basic compound.
9. The composition according to claim 8 , wherein the composition is liquid or solid.
10. A layer-shaped article comprising the fluorine-containing resin particle according to claim 1 .
11. The fluorine-containing resin particle according to claim 1 , wherein an average particle diameter of the fluorine-containing resin particle is from 0.2 μm to 4.5 μm, a BET specific surface area of the fluorine-containing resin particle is from 5 m 2 /g to 15 m 2 /g, and an apparent density of the fluorine-containing resin particle is from 0.2 g/ml to 0.5 g/ml.
12. The fluorine-containing resin particle according to claim 1 , wherein the fluorine-containing resin particle has a fluorine atom-containing dispersant attached to a surface thereof.
13. The fluorine-containing resin particle according to claim 12 , wherein the fluorine-containing dispersant is a fluorinated alkyl group-containing polymer having a structural unit represented by formula (FA) below:
wherein, in formulae (FA), each R F1 independently represents a hydrogen atom or an alkyl group, each Q F1 independently represents —O— or —NH—, fl represents an integer of 1 or more, each fp independently represents 0 or an integer of 1 or more, and each ft independently represents an integer of 1 or more and 7 or less.
14. The composition according to claim 8 , comprising:
7 or more and 20 or less carboxyl groups per 10 6 carbon atoms;
0 ppm or more and 1.5 ppm or less of the basic compound; and
0 ppb or more and 20 ppb or less of perfluorooctanoic acid,
wherein the fluorine-containing resin particles are selected from the group consisting of polytetrafluoroethylene (PTFE) particles, tetrafluoroethylene-hexafluoropropylene copolymer (FEP) particles, tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer (PFA) particles, ethylene-tetrafluoroethylene copolymer (ETFE) particles, and ethylene-chlorotrifluoroethylene copolymer (ECTFE) particles, and
wherein the basic compound is an amine compound.