Ceramic complex light emitting device using the same, and method for producing ceramic complex
A ceramic complex that has improved optical characteristics including luminous efficiency is provided. A method for producing a ceramic complex, including: preparing a molded body containing rare earth aluminum garnet fluorescent material, aluminum oxide, and lutetium oxide, and having a content of the rare earth aluminum garnet fluorescent material in a range of 15% by mass or more and 50% by mass or less, and a content of the lutetium oxide in a range of 0.2% by mass or more and 4.5% by mass or less, based on the total amount of the rare earth aluminum garnet fluorescent material, the aluminum oxide, and the lutetium oxide; and calcining the molded body in an air atmosphere to provide a ceramic complex having a relative density in a range of 90% or more and less than 100%.
1. A ceramic complex comprising a rare earth aluminum garnet fluorescent material, aluminum oxide, and lutetium oxide, having a content of the rare earth aluminum garnet fluorescent material in a range of 15% by mass or more and 50% by mass or less, and a content of the lutetium oxide in a range of 0.2% by mass or more and 4.5% by mass or less, based on a total amount of the rare earth aluminum garnet fluorescent material, the aluminum oxide, and the lutetium oxide as 100% by mass.
2. The ceramic complex according to claim 1 , wherein the rare earth aluminum garnet fluorescent material has a composition represented by the following formula (I):
( Ln 1-a Ce a ) 3 (Al c Ga b ) 5 O 12 (I)
wherein Ln represents at least one rare earth element selected from the group consisting of Y, Gd, Lu, and Tb, and a, b, and c each satisfy 0<a≤0.022, 0≤b≤0.4, 0<c≤1.1, and 0.9≤b+c≤1.1.
3. The ceramic complex according to claim 1 , wherein the ceramic complex has a plate-like body that comprises a first principal surface serving as an incident surface of light and a second principal surface serving as an outgoing surface of light, which is positioned on an opposite side to the first principal surface, and a plate thickness of the plate-like body is in a range of 90 μm or more and 300 μm or less.
4. The ceramic complex according to claim 3 , wherein a ratio of a light diameter of outgoing light emitted from the second principal surface to a light diameter of incident light to be allowed to enter the first principal surface is in a range of 0.4 or more and less than 1.0.
5. A projector comprising the ceramic complex according to claim 1 , and an excitation light source including a semiconductor laser.
6. A method for producing a ceramic complex, comprising:
preparing a molded body containing rare earth aluminum garnet fluorescent material, aluminum oxide, and lutetium oxide, and having a content of the rare earth aluminum garnet fluorescent material in a range of 15% by mass or more and 50% by mass or less, and a content of the lutetium oxide in a range of 0.2% by mass or more and 4.5% by mass or less, based on the total amount of the rare earth aluminum garnet fluorescent material, the aluminum oxide, and the lutetium oxide as 100% by mass; and
calcining the molded body in an air atmosphere to obtain a ceramic complex having a relative density in a range of 90% or more and less than 100%.
7. The method for producing a ceramic complex according to claim 6 , wherein a temperature in calcining is in a range of 1,400° C. or more and 1,800° C. or less.
8. The method for producing a ceramic complex according to claim 6 , further comprises: subjecting the ceramic complex to an annealing treatment in a reducing atmosphere, after calcining.
9. The method for producing a ceramic complex according to claim 8 , wherein a temperature in the annealing treatment is in a range of 1,000° C. or more and 1,600° C. or less.
10. The method for producing a ceramic complex according to claim 6 , wherein the rare earth aluminum garnet fluorescent material has a composition represented by the following formula (I):
( Ln 1-a Ce a ) 3 (Al c Ga b ) 5 O 12 (I)
wherein Ln represents at least one rare earth element selected from the group consisting of Y, Gd, Lu, and Tb, and a, b, and c each satisfy 0<a≤0.022, 0≤b≤0.4, 0<c≤1.1, and 0.9≤b+c≤1.1.