Method and system for sulfur and sulfur-containing chemicals as cathode additives for silicon anode-based lithium ion batteries
Systems and methods for sulfur-containing chemicals as cathode additives for silicon-based lithium ion batteries may include a silicon-based anode, an electrolyte, and a cathode. The cathode may include an active material and a sulfur-containing additive. The cathode active material may include one or more of nickel cobalt aluminum oxide (NCA), nickel cobalt manganese oxide (NCM), lithium iron phosphate (LFP), lithium cobalt oxide (LCO), and lithium manganese oxide (LMO). The sulfur-containing additive may include elemental sulfur and/or Li 2 S. The sulfur-containing additive may include one or more of lithium polysulfides (Li 2 S n , where n=2-8), polysulfides, and organic polysulfides. The sulfur-containing additive may include one or more of metal sulfides, transition metal polysulfide complexes, S-containing organic polymers or copolymer, polymeric sulfur, and transition metal sulfides. The sulfur-containing additive may include 5% or less by weight of the active material, or 1% or less by weight of the active material.
1 . A battery, the battery comprising:
a silicon-based anode, an electrolyte, and a cathode, wherein the cathode comprises an active material and a sulfur-containing additive;
wherein said sulfur-containing additive is a transition metal polysulfide complex and wherein said transition metal polysulfide complex is (C 5 H 5 ) 2 TiS 5 , [Ni(S 4 ) 2 ] 2− , or [Pt(S 5 ) 3 ] 2− ;
wherein the sulfur-containing additive comprises 5% or less by weight of the active material;
wherein the cathode active material comprises one or more of: nickel cobalt aluminum oxide (NCA), nickel cobalt manganese oxide (NCM), lithium cobalt oxide (LCO), lithium manganese oxide (LMO), Ni-rich layered oxides, Li-rich layered oxides, and spinel oxides LiNi 0.5 Mn 1.5 O 4 ; and
wherein the anode comprises an active material that comprises between 50% to 95% silicon by weight.
2 . The battery according to claim 1 , wherein the sulfur-containing additive comprises 1% or less by weight of the active material.
3 . The battery according to claim 1 , wherein the battery comprises a lithium ion battery.
4 . The battery according to claim 1 , wherein the electrolyte comprises a liquid, solid, or gel.
5 . A method of forming a battery, the method comprising:
forming a battery comprising a silicon-based anode, an electrolyte, and a cathode, wherein the cathode comprises an active material and a sulfur-containing additive;
wherein said sulfur-containing additive is a transition metal polysulfide complex and wherein said transition metal polysulfide complex is (C 5 H 5 ) 2 TiS 5 , [Ni(S 4 ) 2 ] 2− , or [Pt(S 5 ) 3 ] 2− ;
wherein the sulfur-containing additive comprises 5% or less by weight of the active material;
wherein the cathode active material comprises one or more of: nickel cobalt aluminum oxide (NCA), nickel cobalt manganese oxide (NCM), lithium cobalt oxide (LCO), lithium manganese oxide (LMO), Ni-rich layered oxides, Li-rich layered oxides, and spinel oxides LiNi 0.5 Mn 1.5 O 4 ; and
wherein the anode comprises an active material that comprises between 50% to 95% silicon by weight.
6 . The method according to claim 5 , wherein the sulfur-containing additive comprises 1% or less by weight of the active material.
7 . The method according to claim 5 , wherein the battery comprises a lithium ion battery and the electrolyte comprises a liquid, solid, or gel.
8 . A battery, the battery comprising:
a battery comprising a silicon-dominant anode, an electrolyte, and a cathode, wherein the cathode comprises an active material and a sulfur-containing additive;
wherein said sulfur-containing additive is a transition metal polysulfide complex and wherein said transition metal polysulfide complex is (C 5 H 5 ) 2 TiS 5 , [Ni(S 4 ) 2 ] 2− , or [Pt(S 5 ) 3 ] 2− ;
and wherein the sulfur-containing additive comprises 5% or less by weight of the active material;
wherein the cathode active material comprises one or more of: nickel cobalt aluminum oxide (NCA), nickel cobalt manganese oxide (NCM), lithium cobalt oxide (LCO), lithium manganese oxide (LMO), Ni-rich layered oxides, Li-rich layered oxides, and spinel oxides LiNi 0.5 Mn 1.5 O 4 ; and
wherein the anode comprises an active material that comprises between 50% to 95% silicon by weight.