Method for fabricating a rubber-based elastomeric glove/material
Methods for fabricating rubber-based elastomeric materials are disclosed. In an embodiment, a method for fabricating a rubber-based elastomeric glove includes milling diene rubber to form first and second milled diene rubber portions; forming a first mixture by mixing a silica reinforcing component and a first antiozonant wax with the first milled diene rubber portion; forming a second mixture by mixing a second antiozonant wax with the second milled diene rubber portion; mixing the first mixture, the second mixture, and a solvent to form a viscous solution; and dipping a glove mold into the viscous solution for a selected number of dips, and evaporating the solvent from the glove mold between dips to form the rubber-based elastomeric glove, wherein the elastomeric glove has a thickness of at least about 30 mils, and wherein the elastomeric glove exhibits a flexural modulus of less than about 0.06 MPa.
1. A method for fabricating a rubber-based elastomeric glove, the method comprising:
milling diene rubber to form a first milled diene rubber portion and a second milled diene rubber portion;
forming a first mixture by mixing a silica reinforcing component and a first antiozonant wax with the first milled diene rubber portion;
forming a second mixture by mixing a second antiozonant wax with the second milled diene rubber portion;
mixing the first mixture, the second mixture, and a solvent to form a viscous solution; and
dipping a glove mold into the viscous solution for a selected number of dips, and evaporating the solvent from the glove mold between dips to form the rubber-based elastomeric glove, wherein the elastomeric glove has a thickness of at least about 30 mils, and wherein the elastomeric glove exhibits a flexural modulus of less than about 0.06 MPa.
2. The method of claim 1 wherein the elastomeric glove includes the silica reinforcing component in a total amount of about 0.5 to about 1.5 parts per hundred rubber (PHR), the first antiozonant wax in a total amount of about 0.2 to about 1.0 PHR; and the second antiozonant wax in a total amount of about 0.75 to about 2.5 PHR.
3. The method of claim 2 wherein the elastomeric glove includes the silica reinforcing component in a total amount of about 0.5 to about 1.5 parts per hundred rubber (PHR), the first antiozonant wax in a total amount of about 0.2 to about 0.4 PHR; and the second antiozonant wax in a total amount of about 0.75 to about 1.5 PHR.
4. The method of claim 2 wherein the first antiozonant wax has a first kinematic viscosity at 100° C., wherein the first antiozonant wax has a first congealing point, wherein the second antiozonant wax has a second kinematic viscosity at 100° C. greater than the first kinematic viscosity, and wherein the second antiozonant wax has a second congealing point greater than the first congealing point.
5. The method of claim 1 wherein:
forming the first mixture comprises mixing the silica reinforcing component, the first antiozonant wax, a first antidegradant, a first vulcanizing agent, and a first vulcanization accelerator with the first milled diene rubber portion; and
forming the second mixture comprises mixing the second antiozonant wax, a second antidegradant, a second vulcanizing agent, a second vulcanization activator, a second vulcanization accelerator, and a pigment with the second milled diene rubber portion.
6. The method of claim 5 wherein:
forming the first mixture comprises excluding the second antiozonant wax from the first mixture; and
forming the second mixture comprises excluding the silica reinforcing component from the second mixture.
7. The method of claim 5 wherein:
the first mixture consists essentially of the first antiozonant wax, the silica reinforcing component and the first milled diene rubber portion; and
the second mixture consists essentially of the second antiozonant wax and the second milled diene rubber portion.
8. The method of claim 5 wherein:
the first mixture consists of the first milled diene rubber component, the silica reinforcing component, the first antiozonant wax, a first antidegradant, a first vulcanizing agent, and a first vulcanization accelerator; and
the second mixture consists of the second milled diene rubber component, the second antiozonant wax, a second antidegradant, a second vulcanizing agent, a second vulcanization activator, a second vulcanization accelerator, and a pigment.
9. A method for fabricating a rubber-based elastomeric material, the method comprising:
milling diene rubber to form a first milled diene rubber portion and a second milled diene rubber portion;
forming a first mixture by mixing a silica reinforcing component and a first antiozonant wax with the first milled diene rubber portion;
forming a second mixture by mixing a second antiozonant wax with the second milled diene rubber portion;
mixing the first mixture, the second mixture, and a solvent to form a viscous solution; and
dipping a mold into the viscous solution for a selected number of dips and evaporating the solvent from the mold between dips to form the rubber-based elastomeric material, wherein the rubber-based elastomeric material is provided in the form of a film having a thickness of at least about 30 mils, and wherein the film exhibits a flexural modulus of less than about 0.06 MPa.
10. The method of claim 9 wherein the film has a thickness of at least about 70 mils.
11. The method of claim 9 wherein the film exhibits a flexural modulus of less than about 0.04 MPa.
12. The method of claim 9 wherein the diene rubber comprises natural rubber.
13. The method of claim 9 wherein each antiozonant wax comprises a microcrystalline/paraffinic wax.
14. The method of claim 9 wherein the elastomeric material includes the silica reinforcing component in a total amount of about 0.5 to about 1.5 parts per hundred rubber (PHR), the first antiozonant wax in a total amount of about 0.2 to about 1.0 PHR; and the second antiozonant wax in a total amount of about 0.75 to about 2.5 PHR.
15. The method of claim 14 wherein the elastomeric material includes the silica reinforcing component in a total amount of about 0.5 to about 1.5 parts per hundred rubber (PHR), the first antiozonant wax in a total amount of about 0.2 to about 0.4 PHR; and the second antiozonant wax in a total amount of about 0.75 to about 1.5 PHR.
16. The method of claim 14 wherein the first antiozonant wax has a first kinematic viscosity at 100° C., wherein the first antiozonant wax has a first congealing point, wherein the second antiozonant wax has a second kinematic viscosity at 100° C. greater than the first kinematic viscosity, and wherein the second antiozonant wax has a second congealing point greater than the first congealing point.
17. The method of claim 9 wherein:
forming the first mixture comprises mixing the silica reinforcing component, the first antiozonant wax, a first antidegradant, a first vulcanizing agent, and a first vulcanization accelerator with the first milled diene rubber portion; and
forming the second mixture comprises mixing the second antiozonant wax, a second antidegradant, a second vulcanizing agent, a second vulcanization activator, a second vulcanization accelerator, and a pigment with the second milled diene rubber portion.
18. The method of claim 9 wherein:
forming the first mixture comprises excluding the second antiozonant wax from the first mixture; and
forming the second mixture comprises excluding the silica reinforcing component from the second mixture.
19. The method of claim 9 wherein:
the first mixture consists essentially of the first antiozonant wax, the silica reinforcing component and the first milled diene rubber portion; and
the second mixture consists essentially of the second antiozonant wax and the second milled diene rubber portion.
20. The method of claim 9 wherein:
the first mixture consists of the first milled diene rubber component, the silica reinforcing component, the first antiozonant wax, a first antidegradant, a first vulcanizing agent, and a first vulcanization accelerator; and
the second mixture consists of the second milled diene rubber component, the second antiozonant wax, a second antidegradant, a second vulcanizing agent, a second vulcanization activator, a second vulcanization accelerator, and a pigment.