Crosslinkable polymer composition and cable with advantageous electrical properties
A polymer composition includes a crosslinked polyolefin with improved DC electrical properties. Prior to crosslinking, the polymer composition includes a polyolefin and peroxide, in which the peroxide is in an amount of less than 35 mmol —O—O— per kilogram of the polymer composition. A cable can be surrounded by at least one layer including the polymer composition.
1. A crosslinked direct current (DC) power cable, comprising a conductor which is surrounded by at least an inner semiconductive layer comprising a first semiconductive composition, an insulation layer consisting of a polymer composition and an outer semiconductive layer comprising a second semiconductive composition, in that order,
wherein the polymer composition of insulation layer consists of, prior to crosslinking, a polyolefin, an antioxidant, a peroxide and optionally a scorch retarder,
wherein said peroxide is present in an amount of less than 30 mmol —O—O—/kg polymer composition, and
wherein the polyolefin is, before crosslinking, an unsaturated LDPE polymer, which is selected from an unsaturated LDPE homopolymer or an unsaturated LDPE copolymer of ethylene with one or more comonomer(s), wherein the unsaturated LDPE polymer contains vinyl groups and the total amount of vinyl groups present in the unsaturated LDPE is higher than 0.05/1000 carbon atoms and 0.82/1000 carbon atoms or less, and wherein the polymer composition has an electrical conductivity of 45 fS/m or less.
2. The cable according to claim 1 , wherein the crosslinked polymer composition has an electrical conductivity of 40 fS/m or less.
3. The cable according to claim 1 , wherein the crosslinked polymer composition has a PENT (Pennsylvania Notch Test) life time of 800 hours or more, when measured according to PENT test under load at 2 MPa and at ageing temperature of 70° C.
4. The cable according to claim 1 , wherein the crosslinked polymer composition has a Stress at Break at 70° C. of 7 . 0 MPa or more, or at −10° C. of 25.0 MPa or more.
5. The cable according to claim 1 , wherein the crosslinked polymer composition has an electrical conductivity of from 0.5 to 35 fS/m.
6. The crosslinked DC power cable according to claim 1 , wherein the crosslinked polymer composition has a Strain at break (%) at 70° C. of 450% or more, or at −10° C. of 400% or more.
7. The crosslinked DC power cable according to claim 1 , wherein the polyolefin comprises a total amount of carbon-carbon double bonds/1000 carbon atoms of more than 0.4/1000 carbon atoms.
8. The crosslinked DC power cable according to claim 1 , wherein the polyolefin is before crosslinking an unsaturated LDPE copolymer of ethylene with at least one polyunsaturated comonomer and optionally with one or more other comonomer(s).
9. The crosslinked DC power cable according to claim 1 , wherein the polyolefin contains before crosslinking vinyl groups in total amount of more than 0.20/1000 carbon atoms.
10. The crosslinked DC power cable as claimed in claim 8 wherein the polyunsaturated comonomer consists of a straight carbon chain with at least 8 carbon atoms and at least 4 carbons between the non-conjugated double bonds, of which at least one is terminal.
11. The crosslinked DC power cable as claimed in claim 8 wherein the polyunsaturated comonomer is a diene which is selected from C 8 - to C 14 -non-conjugated diene or mixtures thereof.
12. The crosslinked DC power cable as claimed in claim 8 wherein the polyunsaturated comonomer is selected from 1,7-octadiene, 1,9-decadiene, 1,11-dodecadiene, 1,13-tetradecadiene, 7-methyl-1,6-octadiene, 9-methyl-1,8-decadiene, or mixtures thereof.