Method and system for multiple carbon precursors for enhanced battery electrode robustness
Systems and methods for multiple carbon precursors for enhanced battery electrode robustness may include an electrode having an active material on a current collector, the active material including two or more carbon precursor materials, and an additive, wherein the carbon precursor materials have different pyrolysis temperatures. A battery may include the electrode. The carbon precursor materials may include polyimide (PI) and polyamide-imide (PAI). The active material may be pyrolyzed at a temperature such that a first carbon precursor material is partially pyrolyzed and a second carbon precursor material is completely pyrolyzed. The carbon precursor materials may include two or more of PI, PAI, carboxymethyl cellulose (CMC), styrene-butadiene rubber (SBR), polyacrylonitrile (PAN), and sodium alginate. The active material may include silicon constituting at least 50% of weight of a formed anode after pyrolysis. The active material may include silicon constituting up to 97% of weight of a formed electrode after pyrolysis.
1. An electrode, the electrode comprising:
an active material on a current collector, the active material comprising two or more pyrolyzed carbon precursor materials and an additive, wherein the carbon precursors have been pyrolyzed at a temperature such that a first precursor is 70% or less pyrolyzed and a second precursor is 95% or more pyrolyzed.
2. The electrode according to claim 1 , wherein a battery comprises the electrode.
3. The electrode according to claim 1 , wherein the carbon precursor materials comprise polyimide (PI) and polyamide-imide (PAI).
4. The electrode according to claim 1 , wherein the active material is pyrolyzed at a temperature such that a first carbon precursor material is partially pyrolyzed and a second carbon precursor material is completely pyrolyzed.
5. The electrode according to claim 4 , wherein a ratio of a Young's modulus of the second carbon precursor material after pyrolysis to that of a Young's modulus of the first carbon precursor after pyrolysis is 5 or more.
6. The electrode according to claim 1 , wherein the carbon precursor materials comprise two or more of PI, PAI, carboxymethyl cellulose (CMC), styrene-butadiene rubber (SBR), polyacrylonitrile (PAN), and sodium alginate.
7. The electrode according to claim 1 , wherein the active material comprises silicon constituting at least 50% of weight of a formed anode after pyrolysis.
8. The electrode according to claim 1 , wherein the active material comprises silicon constituting up to 97% of weight of a formed electrode after pyrolysis.
9. The electrode according to claim 1 , wherein the current collector comprises copper, nickel, titanium, steel, or aluminum.
10. The electrode according to claim 1 , wherein the active material on the current collector does not crack when wound around a 2 mm diameter rod.
11. The electrode according to claim 1 , wherein the additive comprises conductive carbon sources.
12. A method comprising:
forming an electrode comprising an active material on a current collector, the active material comprising two or more pyrolyzed carbon precursor materials and an additive, wherein the pyrolyzed carbon precursor materials are pyrolyzed at a temperature such that a first precursor is 70% or less pyrolyzed and a second precursor is 95% or more pyrolyzed.
13. The method according to claim 12 , wherein a battery comprises the electrode.
14. The method according to claim 12 , wherein the carbon precursor materials comprise polyimide (PI) and polyamide-imide (PAI).
15. The method according to claim 12 , comprising pyrolyzing the active material at a temperature such that a first carbon precursor material is partially pyrolyzed and a second carbon precursor material is completely pyrolyzed.
16. The method according to claim 15 , wherein a ratio of a Young's modulus of the second carbon precursor material after pyrolysis to that of a Young's modulus of the first carbon precursor material after pyrolysis is 5 or more.
17. The method according to claim 12 , wherein the carbon precursor materials comprise two or more of PI, PAI, carboxymethyl cellulose (CMC), styrene-butadiene rubber (SBR), polyacrylonitrile (PAN), and sodium alginate.
18. The method according to claim 12 , wherein the active material comprises silicon constituting at least 50% of weight of a formed anode after pyrolysis.
19. The method according to claim 12 , wherein the additive comprises conductive carbon sources.
20. The method according to claim 12 , wherein the current collector comprises copper, nickel, titanium, steel, or aluminum.
21. The method according to claim 12 , wherein the active material on the current collector does not crack when wound around a 2 mm diameter rod.
22. An electrode, the electrode comprising:
an active material on a current collector, the active material comprising pyrolyzed polyimide (PI) and polyamide-imide (PAI) carbon precursor materials and an additive, wherein the PI is pyrolyzed less than 70% and the PAI is pyrolyzed more than 95%.