Preparation of 7XXX aluminum alloys for adhesive bonding
A preparation method for adhesive bonding of magnesium-containing aluminum alloy products includes a magnesium-containing aluminum alloy product including a matrix and a surface oxide layer overlying the matrix. The magnesium-containing aluminum alloy product also includes intermetallic particles at least proximal the surface oxide layer. The method also includes ablating at least some of the intermetallic particles via an energy source, and in the absence of melting of the matrix of the magnesium-containing aluminum alloy product.
1. A method for preparing magnesium-containing aluminum alloy products for adhesive bonding, the method comprising:
(a) receiving a magnesium-containing aluminum alloy product, wherein the magnesium-containing aluminum alloy product comprises a matrix and a surface oxide layer overlying the matrix;
(i) wherein the surface oxide layer comprises an as-received thickness;
(ii) wherein the magnesium-containing aluminum alloy product comprises intermetallic particles proximal the surface oxide layer; and
(iii) wherein the intermetallic particles comprise Cu-bearing intermetallic particles; and
(b) laser ablating at least some of the intermetallic particles and in the absence of melting of the matrix of the magnesium-containing aluminum alloy product.
2. The method of claim 1 , wherein the laser ablating step comprises volatilizing the intermetallic particles.
3. The method of claim 1 , wherein, after the laser ablating step, the magnesium-containing aluminum alloy product comprises an ablated portion having a plurality of ablation voids proximal the surface oxide layer.
4. The method of claim 3 , wherein the intermetallic particles define pre-ablation volumes, and wherein, due to the laser ablating, at least some of the plurality of ablation voids are greater in volume than the pre-ablation volumes.
5. The method of claim 1 , wherein the intermetallic particles have a size of from 100 nm to 10 μm.
6. The method of claim 1 , wherein the laser ablating step comprises maintaining the surface oxide layer at the as-received thickness.
7. The method of claim 1 , wherein the surface oxide layer comprises MgO.
8. The method of claim 7 , wherein, after the laser ablating step, the surface oxide layer comprises at least 10 atomic % Mg.
9. The method of claim 1 , comprising selectively laser ablating at least some of the intermetallic particles during the laser ablating step, thereby creating an ablated portion surrounded by an unablated portion.
10. The method of claim 1 , comprising:
(a) determining locations of the intermetallic particles; and
(b) selectively laser ablating at least some of the located intermetallic particles during the laser ablating step.
11. The method of claim 1 , comprising:
determining at least one bonding location associated with the magnesium-containing aluminum alloy product; and
after the determining step, completing the laser ablating step relative to the at least one bonding location, thereby creating an ablated portion.
12. The method of claim 11 , wherein, after the laser ablating step, the magnesium-containing aluminum alloy product comprises the ablated portion surrounded by an unablated portion.
13. The method of claim 12 , comprising, after the laser ablating step, contacting the magnesium-containing aluminum alloy product with a functionalization solution.
14. The method of 12 , comprising selectively contacting the ablated portion with a functionalization solution, thereby creating a pretreated portion of the magnesium-containing aluminum alloy product.
15. The method of claim 14 , wherein the selectively contacting step comprises restricting contact between the unablated portion and the functionalization solution.