IP Library Granted Patent US 11,117,851
Granted Patent B2
US 11,117,851 · App. 16/727,319 · Granted Sep 14, 2021

Reactor layout for methanol production from low quality synthesis gas

Inventor: Hassan Modarresi (Lyngby, DK)
Assignee: Haldor Topsoe A/S
C07C29/1518B01J8/001B01J8/0453B01J8/0457B01J8/0492B01J8/0496B01J19/0013B01J19/0053C07C29/15C07C31/04B01J2208/0053B01J2208/00061B01J2208/00176B01J2208/00274B01J2208/00716B01J2219/00105B01J2219/00202B01J2219/00213B01J2219/00231B01J2219/00389C07C2521/04C07C2523/80
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Quick Facts
Patent No.
US 11,117,851
App. No.
16/727,319
Granted
Sep 14, 2021
Kind
B2
Abstract

A reactor layout for a process of methanol production from low quality synthesis gas, in which relatively smaller adiabatic reactors can be operated more efficiently, some of the inherent disadvantages of adiabatic reactors for methanol production are avoided. This is done by controlling the outlet temperature in the pre-converter by rapid adjustment of the recycle gas, i.e. by manipulating the gas hourly space velocity in the pre-converter.

Claims (13)

1. A reactor layout for carrying out a process for methanol production from synthesis gas, said reactor layout comprising:

one or more methanol pre-converters/guard reactors, in which the synthesis gas is partially converted to methanol over a heterogeneous catalyst to generate an effluent gas without impurities,

a feed-effluent heat exchanger for pre-heating the synthesis gas and for cooling the effluent gas from the one or more methanol pre-converters/guard reactors, and

a methanol synthesis loop comprising:

a main methanol converter for converting a mixture of recycle gas and the cooled effluent gas from the one or more methanol pre-converters/guard reactors,

a main feed-effluent heat exchanger,

a cooler or a series of coolers,

a high pressure gas-liquid separator, which splits the inlet flow into raw methanol and recycle gas,

a recycle compressor,

a loop purge, wherein the loop purge is drawn from the recycle gas before the recycle compressor, and

means for defining and controlling a maximum allowable outlet temperature using a cold recycle gas stream which is injected into the one or more methanol pre-converters/guard reactors via a control valve.

2. The reactor layout according to claim 1 , which has fresh feed gas splitting located on the cold side, before the feed-effluent heat exchanger.

3. The reactor layout according to claim 1 , which enables on-stream catalyst replacement in the one or more pre-converters/guard reactors.

Assignments (1)
CHANGE OF NAME Recorded Oct 3, 2023
From: HALDOR TOPSØE A/S
To: TOPSOE A/S
Reel/Frame 065108/0028 →
Priority Claims (1)
DK PA 2015 00464 · Aug 12, 2015 · national
Continuity (2)
Division 15749607
Related Publication 20200131105A1 · Apr 30, 2020