Compound, display panel and display apparatus
A compound having a D-(π)-σ-(π)-A chemical structure and improving brightness and efficiency of light-emitting is described. In an embodiment, the compound has a chemical structure according to Formula (I), in which L 1 and L 2 are each at least one of a single bond, C1-C20 alkylene, C3-C20 cycloalkylene, C3-C20 heterocyclic alkylene, C6-C40 arylene, C4-C40 heteroarylene, C10-C60 fused arylene, or C10-C60 fused heteroarylene; the electron donor D is C1-C20 alkyl, C3-C20 cycloalkyl, C1-C20 alkoxy, C3-C20 heterocyclic group, C6-C40 aryl, C4-C40 heteroaryl, C10-C60 fused arylene, C10-C60 fused heteroarylene, C12-C40 carbazolyl and its derivative groups, C12-C40 diphenylamino and its derivative groups, C18-C60 triphenylamino and its derivative groups, or C12-C40 acridinyl and its derivative groups; and the electron acceptor A is a nitrogen-containing heterocyclic group, a cyano-containing group, a triarylboron-based group, a benzophenone-based group, an aromatic heterocyclic ketone-based group, a sulfone-based group, or a phosphoroso-containing groups.
1. A compound having a chemical structure according to Formula (I):
wherein D is an electron donor, A is an electron acceptor; m is a number of the electron donors D, n is a number of the electron acceptors A, and m and n are each an integer independently selected from 1, 2 and 3; p is a number of L 1 , q is a number of L 2 , and p and q are each an integer independently selected from 0, 1, or 2;
L 1 and L 2 are each independently selected from the group consisting of a single bond, a substituted or unsubstituted C1-C20 alkylene, a substituted or unsubstituted C3-C20 cycloalkylene, a substituted or unsubstituted C3-C20 heterocyclic alkylene, a substituted or unsubstituted C6-C40 arylene, a substituted or unsubstituted C4-C40 heteroarylene, a substituted or unsubstituted C10-C60 fused arylene, a substituted or unsubstituted C10-C60 fused heteroarylene, and combinations thereof;
D is selected from the group consisting of a substituted or unsubstituted C1-C20 alkyl, a substituted or unsubstituted C3-C20 cycloalkyl, a substituted or unsubstituted C1-C20 alkoxy, a substituted or unsubstituted C3-C20 heterocyclic group, a substituted or unsubstituted C6-C40 aryl, a substituted or unsubstituted C4-C40 heteroaryl, a substituted or unsubstituted C10-C60 fused arylene, a substituted or unsubstituted C10-C60 fused heteroarylene, a substituted or unsubstituted C12-C40 carbazolyl and its derivative groups, a substituted or unsubstituted C12-C40 diphenylamino and its derivative groups, a substituted or unsubstituted C18-C60 triphenylamino and its derivative groups, a substituted or unsubstituted C12-C40 acridinyl and its derivative groups, and combinations thereof; and
A is selected from the group consisting of a nitrogen-containing heterocyclic group, a cyano-containing group, a triarylboron-based group, a benzophenone-based group, an aromatic heterocyclic ketone-based group, a sulfone-based group, a phosphoroso-containing groups, and combinations thereof;
wherein L1 and L2 are identical and are phenyl, m and n are each 1;
wherein D is any one of the following groups:
and
wherein A is any one of the following groups:
wherein R is selected from the group consisting of a hydrogen atom, C1-C20 alkyl, C1-C20 alkoxy, C4-C8 cycloalkyl, C6-C40 aryl, and C4-C40 heteroaryl; and
# indicates a bonding position.
2. The compound according to claim 1 , wherein L 1 and L 2 are different.
3. The compound according to claim 1 , wherein p is 0, and q is 1.
4. The compound according to claim 1 , wherein D is any one of the following formulas:
wherein m, n and p are each an integer independently selected from 0, 1, 2 or 3;
U 1 , U 2 , and U 3 are each independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted C1-C30 alkyl, a substituted or unsubstituted silylene, a substituted or unsubstituted C3-C20 cycloalkyl, a substituted or unsubstituted C1-C30 alkoxy, a substituted or unsubstituted C6-C30 aryl, a substituted or unsubstituted C10-C30 fused aryl, and combinations thereof; and
# indicates a bonding position.
5. The compound according to claim 4 , wherein the electron donor D is any one of the following groups:
wherein R is selected from the group consisting of a hydrogen atom, a substituted or unsubstituted C1-C20 alkyl, a substituted or unsubstituted silylene, a substituted or unsubstituted C3-C20 cycloalkyl, a substituted or unsubstituted C1-C20 alkoxy, a substituted or unsubstituted C3-C20 heterocyclic group, a substituted or unsubstituted C6-C40 aryl, a substituted or unsubstituted C10-C30 fused aryl, and a substituted or unsubstituted C4-C40 heteroaryl.
6. The compound according to claim 1 , D is any one of the following groups:
wherein Z is selected from the group consisting of a carbon atom, a nitrogen atom, an oxygen atom, a sulfur atom and a silicon atom;
X is selected from the group consisting of a carbon atom, a nitrogen atom, an oxygen atom and a sulfur atom;
m, n, p and q are each an integer independently selected from 0, 1, 2 or 3;
U 1 , U 2 , U 3 and U 4 are each independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted C1-C30 alkyl, a substituted or unsubstituted silylene, a substituted or unsubstituted C3-C20 cycloalkyl, a substituted or unsubstituted C1-C30 alkoxy, a substituted or unsubstituted C6-C30 aryl, and a substituted or unsubstituted C10-C30 fused aryl;
when Z or X is an oxygen atom or a sulfur atom, p or q is 0; and
# indicates a bonding position.
7. The compound according to claim 6 , wherein D is any one of the following groups:
wherein R 1 , R 2 , R 3 and R 4 are each independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted C1-C20 alkyl, a substituted or unsubstituted C3-C20 cycloalkyl, a substituted or unsubstituted C1-C20 alkoxy, a substituted or unsubstituted C3-C20 heterocyclic group, a substituted or unsubstituted C6-C40 aryl, and a substituted or unsubstituted C4-C40 heteroaryl.
8. The compound according to claim 1 , wherein A is any one of the following groups:
wherein # indicates a bonding position.
9. The compound according to claim 1 , wherein A is any one of the following groups:
wherein # indicates a bonding position.
10. The compound according to claim 1 , wherein A is any one of the following groups:
wherein # indicates a bonding position.
11. The compound according to claim 1 , wherein the compound is any one of the following compounds:
12. A display panel, comprising an organic light-emitting device,
wherein the organic light-emitting device comprises an anode, a cathode arranged opposite to the anode, a capping layer disposed at a side of the cathode facing away from the anode, and an organic layer disposed between the anode and the cathode, the organic layer comprising an electron transmission layer, a hole transmission layer, and a light-emitting layer, wherein at least one of the capping layer, the electron transmission layer, the hole transmission layer, and the light-emitting layer is made of the compound according to claim 1 .
13. A display apparatus, comprising the display panel according to claim 12 .