IP Library Granted Patent US 11,821,287
Granted Patent B2
US 11,821,287 · App. 16/747,604 · Granted Nov 21, 2023

Geothermal well stimulation and silca based deposit removal

Inventors: Logan Muller (Wilmington, DE); Paul Hewson (Wilmington, DE); Maria Nydia Lynch (Avondale, PA); Michael Bluemle (Wilmington, DE); Peter Slijp (Wilmington, DE); William S. Carey (Wilmington, DE)
Assignee: SOLENIS TECHNOLOGIES, L.P.
E21B37/06
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Quick Facts
Patent No.
US 11,821,287
App. No.
16/747,604
Granted
Nov 21, 2023
Kind
B2
Abstract

In a geothermal plant, alternately injecting an acid composition and a caustic composition removes or inhibits scale build-up.

Claims (17)

1. A method of removing built up scale in a conduit of a geothermal plant, in which conduit a fluid comprising mineralized water is flowing, wherein the conduit is chosen from a reinjection well, a production well line, and/or a production well, wherein the production well line leads from the production well to a separator, a steam turbine runs off steam from the separator, and a return line provides water from the separator to the reinjection well, the method comprising alternately treating the fluid in the conduit with an acid composition and a caustic composition, wherein treating is carried out without stopping the fluid flow in the conduit, and wherein the acid composition and the caustic composition are injected directly into the fluid in the conduit via a lance.

2. The method according to claim 1 , wherein the acid composition and the caustic composition are injected into the conduit upstream of the location where it is desired to remove the scale or to inhibit the deposition of scale.

3. The method according to claim 1 , wherein the built-up scale comprises an alkali metal aluminosilicate or an alkaline earth metal aluminosilicate-based scale, and wherein the acid composition and the caustic composition do not come into direct contact with the scale but are diluted by the fluid flowing in the conduit.

4. The method according to claim 1 , wherein the fluid is first treated with the acid composition.

5. The method according to claim 1 , wherein the fluid is first treated with the caustic composition.

6. The method according to claim 1 , comprising continuously feeding the acid composition and the caustic composition into the conduit during the treating step.

7. The method according to claim 1 , comprising batch addition of the acid composition and the caustic composition into the conduit during the treating step.

8. The method according to claim 1 , wherein the caustic composition comprises an alkali and a chelator.

9. The method according to claim 8 , wherein the caustic composition further comprises a surfactant.

10. The method according to claim 1 , wherein the acid composition and the caustic composition are injected via the lance into a main flow of the re-injection line of the geothermal plant.

11. The method according to claim 10 , comprising injecting the acid composition and the caustic composition into a location where scale build-up is observed.

12. The method according to claim 11 , wherein the built-up scale comprises an alkali metal aluminosilicate or an alkaline earth metal aluminosilicate-based scale, and wherein the acid composition and the caustic composition do not come into direct contact with the scale but are diluted by the fluid flowing in the conduit.

13. The method according to claim 10 , comprising continuously feeding the acid composition and the caustic composition into the conduit during the treating step.

14. The method according to claim 10 , comprising batch addition of the acid composition and the caustic composition into the conduit during the treating step.

15. The method according to claim 10 , wherein the caustic composition comprises an alkali and a chelator.

16. The method according to claim 15 , wherein the caustic composition further comprises a surfactant.

17. The method according to claim 1 , wherein the conduit is the production well line.

Assignments (11)
SECURITY INTEREST Recorded Nov 14, 2025
From: CHEM-AQUA, INC.; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; NCH CORPORATION; NCH LIFE SCIENCES LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073570/0838 →
RELEASE OF SECURITY INTEREST Recorded Nov 14, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073564/0864 →
SECURITY AGREEMENT (NOTES) Recorded Oct 10, 2025
From: DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073061/0885 →
RELEASE OF 2023 NOTES PATENT SECURITY INTERESTS Recorded Oct 10, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073074/0198 →
SECURITY AGREEMENT (2024 NOTES) Recorded Jun 24, 2024
From: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 067824/0278 →
2023 NOTES PATENT SECURITY AGREEMENT Recorded Jul 7, 2023
From: BIRKO CORPORATION; SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE GLOBAL CORPORATION
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 064225/0170 →
SECURITY AGREEMENT (NOTES) Recorded Sep 14, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
Reel/Frame 061432/0821 →
NOTES SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 058103/0066 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: GOLDMAN SACHS BANK USA
Reel/Frame 058102/0407 →
ABL PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A.
Reel/Frame 058102/0122 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 21, 2020
From: MULLER, LOGAN; HEWSON, PAUL; LYNCH, MARIA NYDIA; BLUEMLE, MICHAEL; SLIJP, PETER; CAREY, WILLIAM SEAN
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 051567/0509 →