Use of sacrificial agents in manufacture of gypsum wallboard
The present invention relates to the use of sacrificial agents to counteract the deleterious impact of gypsum contaminants on the effectiveness of certain stucco additives, particularly, water reducing agents and foaming agents, in a stucco slurry used to make gypsum wallboard.
1. A method for preparing a stucco slurry, the method comprising:
combining water with stucco and a sacrificial agent to form a mixture, wherein the stucco comprises a clay contaminant, and wherein the sacrificial agent comprises an alcohol, a polyglycol other than polyethylene glycol, an ether, an ester, an aromatic sulfonate, an amine, an amide, an ammonium salt, or a mixture thereof, the sacrificial agent having a hydrophilic-lipophilic balance of 5 to 20; and
combining the mixture with a foaming agent to yield the stucco slurry;
wherein the sacrificial agent neutralizes the clay contaminant to prevent the clay contaminant from adsorbing the foaming agent.
2. The method of claim 1 , wherein the sacrificial agent comprises a mixture of two or more compounds that together have a hydrophilic-lipophilic balance of 5 to 20.
3. The method of claim 1 , wherein the sacrificial agent comprises an amine compound having the chemical structure NR1R2R3, wherein:
R1 is selected from substituted or unsubstituted non-alkoxylated C5-22 alkyls, substituted or unsubstituted non-alkoxylated C5-22 alkenyls, substituted or unsubstituted non-alkoxylated C5-22 alkynyls, substituted or unsubstituted C2-22 alkoxylated alkyls, substituted or unsubstituted C2-22 alkoxylated alkenyls, and substituted or unsubstituted C2-22 alkoxylated alkynyls; and
R2 and R3 are non-alkoxylated and are independently selected from hydrogen, substituted or unsubstituted C1-22 alkyls, substituted or unsubstituted C2-22 alkenyls, and substituted or unsubstituted C2-22 alkynyls.
4. The method of claim 1 , wherein the stucco slurry comprises about 0.05% to about 0.5% of the sacrificial agent by weight, based on the dry stucco weight.
5. The method of claim 1 , wherein the stucco slurry comprises about 0.1% to about 0.4% of the foaming agent by weight, based on the dry stucco weight.
6. The method of claim 1 , wherein the stucco slurry further comprises about 0.25% to about 0.5% of a dispersant by weight, based on the dry stucco weight, the dispersant having a different chemical composition than the foaming agent.
7. The method of claim 1 , wherein combining the water with the stucco and the sacrificial agent to form the mixture comprises combining the sacrificial agent with the stucco, wherein the stucco is dry, and then adding the water to the combined stucco and sacrificial agent.
8. The method of claim 1 , further comprising placing the stucco slurry between two sheets to form a gypsum wallboard.
9. The method of claim 8 , wherein the two sheets comprise a fibrous material.
10. A method for preparing a stucco slurry, the method comprising:
preparing a dry mixture by combining stucco with a sacrificial agent having a hydrophilic-lipophilic balance of 5 to 20, wherein the stucco comprises a clay contaminant;
preparing a foam by combining water with a foaming agent and a dispersant having a chemical composition different than the foaming agent; and
combining the dry mixture with the foam;
wherein the sacrificial agent neutralizes the clay contaminant to prevent the clay contaminant from adsorbing the foaming agent.
11. The method of claim 10 , wherein the sacrificial agent comprises an alcohol, a polyglycol other than polyethylene glycol, an ether, an ester, an aromatic sulfonate, an amine, an amide, an ammonium salt, or a mixture thereof.
12. The method of claim 10 , wherein the sacrificial agent comprises an amine compound having the chemical structure NR1R2R3, wherein:
R1 is selected from substituted or unsubstituted non-alkoxylated C5-22 alkyls, substituted or unsubstituted non-alkoxylated C5-22 alkenyls, substituted or unsubstituted non-alkoxylated C5-22 alkynyls, substituted or unsubstituted C2-22 alkoxylated alkyls, substituted or unsubstituted C2-22 alkoxylated alkenyls, and substituted or unsubstituted C2-22 alkoxylated alkynyls; and
R2 and R3 are non-alkoxylated and are independently selected from hydrogen, substituted or unsubstituted C1-22 alkyls, substituted or unsubstituted C2-22 alkenyls, and substituted or unsubstituted C2-22 alkynyls.
13. The method of claim 10 , wherein the sacrificial agent comprises a mixture of two or more compounds that together have a hydrophilic-lipophilic balance of 5 to 20.
14. The method of claim 10 , wherein the stucco slurry comprises about 0.05% to about 0.5% of the sacrificial agent by weight, based on the dry stucco weight.
15. The method of claim 10 , wherein the stucco slurry comprises about 0.1% to about 0.4% of the foaming agent by weight, based on the dry stucco weight.
16. A stucco slurry comprising:
water;
stucco;
a sacrificial agent comprising an amine compound having the chemical structure NR1R2R3, wherein:
R1 is selected from substituted or unsubstituted non-alkoxylated C5-22 alkyls, substituted or unsubstituted non-alkoxylated C5-22 alkenyls, substituted or unsubstituted non-alkoxylated C5-22 alkynyls, substituted or unsubstituted C2-22 alkoxylated alkyls, substituted or unsubstituted C2-22 alkoxylated alkenyls, and substituted or unsubstituted C2-22 alkoxylated alkynyls; and
R2 and R3 are non-alkoxylated and are independently selected from hydrogen, substituted or unsubstituted C1-22 alkyls, substituted or unsubstituted C2-22 alkenyls, and substituted or unsubstituted C2-22 alkynyls; and
a foaming agent.
17. The stucco slurry of claim 16 , wherein the sacrificial agent has a hydrophilic-lipophilic balance of 5 to 20.
18. The stucco slurry of claim 16 , wherein the stucco slurry comprises about 0.1% to about 0.4% of the foaming agent by weight, based on the dry stucco weight.
19. The stucco slurry of claim 16 , wherein the stucco slurry further comprises a dispersant having a chemical composition different than the foaming agent.
20. The stucco slurry of claim 19 , wherein the stucco slurry comprises about 0.25% to about 0.5% of the dispersant by weight, based on the dry stucco weight.