IP Library Granted Patent US 12,049,431
Granted Patent B2
US 12,049,431 · App. 16/751,441 · Granted Jul 30, 2024

Agricultural adjuvant comprising microfibrillated cellulose

Inventors: Humberto Benito Lopez (Chino Hills, CA); Lisiane Zeni (Newport Beach, CA)
Assignee: AMVAC Chemical Corporation (Subsidiary of American Vanguard Corporation)
C05B15/00A01N25/02A01N25/04A01N25/26A01N25/30A01N53/00A01N57/12C05G3/44C05G3/60C05G5/12C05G5/18C05G5/20C08L1/02
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Quick Facts
Patent No.
US 12,049,431
App. No.
16/751,441
Granted
Jul 30, 2024
Kind
B2
Abstract

An agricultural adjuvant includes microfibrillated cellulose, a dispersant or wetting agent, in a liquid carrier that has been subjected to shear conditions. The resultant adjuvant displays useful rheological structure and the adjuvant is added to agricultural formulations to stabilize and impart useful rheology to the formulations.

Claims (15)

1. A method comprising:

(i) subjecting an adjuvant composition to shear conditions sufficient to increase the storage modulus (G′) or the loss modulus (G″) of the adjuvant composition, the adjuvant composition comprising:

(a) 0.01% by weight to 5% by weight of a chemically unmodified microfibrillated cellulose (MFC);

(b) a surfactant or dispersant; and

(c) a liquid carrier; and

(ii) adding the adjuvant composition to a fertilizer or high ionic strength solution,

wherein the shear conditions comprise shearing the adjuvant composition at 5000 RPM to 10,000 RPM with a blade for at least 4 minutes to achieve a G′ of at least 57 Pascals and a G″ of at least 9.7 Pascals, and

wherein the high ionic strength solution comprises at least 5% saturation of a functional ion.

2. The method of claim 1 , wherein the shear conditions are sufficient to decrease the temperature dependence of the storage modulus (G′) and the loss modulus (G″).

3. The method of claim 1 , wherein the amount of the adjuvant added is sufficient to suspend a particulate form of an agricultural formulation for a target period of time to allow uniform application of the agricultural formulation to a crop.

4. The method of claim 1 , wherein the amount of the adjuvant added provides drip resistance and/or rain-fastness in foliar applications.

5. The method of claim 1 , wherein the amount of the adjuvant added is sufficient to prevent run-off.

6. The method of claim 1 , wherein the adjuvant composition further comprises a rain fastener.

7. The method of claim 1 , wherein an amount of adjuvant added provides a target viscosity to an agrochemical formulation.

8. The method of claim 1 , wherein the shear conditions comprise shearing the adjuvant composition at 5000 RPM to 10,000 RPM with a blade for a sufficient period of time to achieve a G′ of from 57 Pascals to 125 Pascals and a G″ of from 9.7 Pascals to 21 Pascals.

Assignments (3)
SECURITY INTEREST Recorded Mar 24, 2026
From: AMVAC CHEMICAL CORPORATION; TYRATECH, INC.
To: BMO BANK N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 075188/0405 →
SECURITY INTEREST Recorded Mar 13, 2026
From: AMVAC CHEMICAL CORPORATION
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 075093/0243 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 22, 2020
From: LOPEZ, HUMBERTO BENITO; ZENI, LISIANE
To: AMVAC CHEMICAL CORPORATION
Reel/Frame 052734/0582 →
Continuity (4)
Provisional Application 62916764 · Oct 17, 2019
Provisional Application 62896762 · Sep 6, 2019
Provisional Application 62797124 · Jan 25, 2019
Related Publication 20200260721A1 · Aug 20, 2020