Water blocking material
Provided is a water blocking material prepared by reacting and foaming a starting material composition that contains a polyol, a polyisocyanate, a catalyst, a foaming agent, a foam stabilizer and a crosslinking agent, in which the polyol contains a dimer acid polyol, the content of the dimer acid polyol in the starting material composition is 85% by mass or more of the entire polyol, the polyisocyanate contains a diphenylmethane diisocyanate, the content of the diphenylmethane diisocyanate in the starting material composition is 70 to 85% by mass of the entire polyisocyanate, and the foam stabilizer contains a reactive silicone. The water blocking material is excellent in heat resistance and water blocking performance and is further excellent in flexibility.
1. A water blocking material prepared by reacting and foaming a starting material composition that contains a polyol, a polyisocyanate, a catalyst, a foaming agent, a foam stabilizer and a crosslinking agent, wherein:
the polyol contains a dimer acid polyol,
the content of the dimer acid polyol in the starting material composition is 85% by mass or more of the entire polyol,
the polyisocyanate contains a diphenylmethane diisocyanate,
the content of the diphenylmethane diisocyanate in the starting material composition is 70 to 75% by mass of the entire polyisocyanate,
the foam stabilizer contains a reactive silicone, and
the crosslinking agent is a trifunctional crosslinking agent having a trimethylolpropane skeleton.
2. The water blocking material according to claim 1 , wherein the foaming agent contains water, and the content of water in the starting material composition is 2.4 to 3.2 parts by mass relative to 100 parts by mass of the polyol.
3. The water blocking material according to claim 1 , wherein the polyisocyanate further contains a tolylene diisocyanate.
4. The water blocking material according to claim 1 , wherein the catalyst does not contain an organic metal catalyst or the content of an organic metal catalyst in the starting material composition is less than 0.2 parts by mass relative to 100 parts by mass of the polyol.
5. The water blocking material according to claim 1 , wherein the content of the crosslinking agent in the starting material composition is 1.5 to 3 parts by mass relative to 100 parts by mass of the polyol.
6. The water blocking material according to claim 1 , wherein the content of the foam stabilizer in the starting material composition is 3.0 to 6.0 parts by mass relative to 100 parts by mass of the polyol.
7. The water blocking material according to claim 1 , having a density of 30 to 50 kg/m 3 .
8. The water blocking material according to claim 1 , wherein the number of cells that the water blocking material has is 60 cells/25 mm or more.
9. The water blocking material according to claim 2 , wherein the polyisocyanate further contains a tolylene diisocyanate.
10. The water blocking material according to claim 2 , wherein the catalyst does not contain an organic metal catalyst or the content of an organic metal catalyst in the starting material composition is less than 0.2 parts by mass relative to 100 parts by mass of the polyol.
11. The water blocking material according to claim 2 , wherein the content of the crosslinking agent in the starting material composition is 1.5 to 3 parts by mass relative to 100 parts by mass of the polyol.
12. The water blocking material according to claim 2 , wherein the content of the foam stabilizer in the starting material composition is 3.0 to 6.0 parts by mass relative to 100 parts by mass of the polyol.
13. The water blocking material according to claim 2 , having a density of 30 to 50 kg/m 3 .
14. The water blocking material according to claim 2 , wherein the number of cells that the water blocking material has is 60 cells/25 mm or more.
15. The water blocking material according to claim 3 , wherein the catalyst does not contain an organic metal catalyst or the content of an organic metal catalyst in the starting material composition is less than 0.2 parts by mass relative to 100 parts by mass of the polyol.
16. The water blocking material according to claim 3 , wherein the content of the crosslinking agent in the starting material composition is 1.5 to 3 parts by mass relative to 100 parts by mass of the polyol.
17. The water blocking material according to claim 3 , wherein the content of the foam stabilizer in the starting material composition is 3.0 to 6.0 parts by mass relative to 100 parts by mass of the polyol.
18. The water blocking material according to claim 1 , wherein the catalyst does not contain an organic metal catalyst.
19. The water blocking material according to claim 1 , wherein the water content is 2.0 to 3.2 parts by mass relative to 100 parts by mass of the polyol.
20. The water blocking material according to claim 1 , wherein the catalyst contains a reactive amine catalyst and a nonreactive amine catalyst.