POLYMERIC PRODUCTS HAVING LAYER-LIKE MORPHOLOGY FORMED FROM MASTERBATCHES
Disclosed herein are polymeric products, along with masterbatches and methods of making polymeric films, sheets, and extruded articles from the masterbatches, in which the films and polymeric products exhibit layer-like morphology and retain good barrier properties to a permeant of interest. The masterbatches include one or more structural and barrier polymers and a compatibilizer.
1 . A method of forming a polymeric body having enhanced barrier properties to a permeant of interest, comprising:
providing a masterbatch comprising from 30 to 70 weight percent of a structural polymer, from 30 to 70 weight percent of a barrier polymer for the permeant of interest, and from about 3 to about 10 weight percent of a functionalized polyolefin;
melting the masterbatch in a first heated extruder;
extruding the melted masterbatch to form the polymeric body comprising the structural polymer, the barrier polymer and the functionalized polyolefin, wherein the body possesses a layer-like morphology.
2 . A method of forming barrier film for a permeant of interest, comprising:
providing a masterbatch comprising from 30 to 70 weight percent of a structural polymer, from 30 to 70 weight percent of a barrier polymer, and from about 3 to about 10 weight percent functionalized polyolefin;
melting the masterbatch in a heated extruder;
passing the melted masterbatch through a die to form a molten polymer extrudate; and
cooling the molten polymer extrudate to form a barrier film having a layer-like morphology.
3 . The method according to claim 1 wherein the polymeric body comprises a first barrier film layer, wherein the melted masterbatch is extruded through a die to form a first molten extrudate, the method further comprising:
cooling and thinning the first molten extrudate to form the first barrier film layer having the layer-like morphology.
4 . The method according to claim 2 for forming a multilayer barrier film for the permeant of interest, the method further comprising:
providing a second polymer;
melting the second polymer in a second heated extruder;
coextruding the melted masterbatch and the melted second polymer through the die to form a molten multilayer polymer extrudate; and
cooling the molten multilayer polymer extrudate to form the multilayer barrier film comprising the first barrier film layer and a second layer, wherein the first barrier film layer has a layer-like morphology.
5 . The method of claim 4 , wherein the second polymer is selected from the group consisting of polyolefins, polyamides, polyesters, polystyrene, polylactic acid, polyhydroxyalkanoate and combinations thereof.
6 . The method of claim 1 , wherein the structural polymer is selected from a group consisting of polyolefins, polyesters, polystyrene, polylactic acid, polyhydroxyalkanoate and combinations thereof, and wherein the barrier polymer is selected from a group consisting of copolymers of ethylene vinyl alcohol, polyvinyl alcohol, polyvinylidene chloride, polyamides, nitrile polymers and combinations thereof.
7 . (canceled)
8 . (canceled)
9 . (canceled)
10 . The method of claim 2 , wherein a molten multilayer polymer extrudate is formed and wherein the polyolefin comprises polypropylene homopolymer or copolymer, wherein the cooling of the molten multilayer polymer extrudate forms an unstretched barrier film, and further comprising the step of biaxially stretching the unstretched barrier film to form a stretched barrier film that has a thickness that is less than the thickness of the unstretched barrier film, and wherein the stretched barrier film possesses layer-like morphology.
11 . The method of claim 1 , wherein the permeant is oxygen and wherein the masterbatch comprises from 35 to 65 weight percent of the structural polymer and from 35 to 65 weight percent of the barrier polymer and wherein the masterbatch comprises from 5 to 10 weight percent of the functionalized polyolefin.
12 . The method of claim 1 , the functionalized polyolefin is selected from a group consisting of copolymers of ethylene and/or propylene and one or more unsaturated polar monomers, and polyolefins that are graft-modified with a maleic acid or a maleic anhydride.
13 . (canceled)
14 . (canceled)
15 . (canceled)
16 . (canceled)
17 . The method of claim 1 , wherein the polymeric body is selected from the group consisting of a packaging film, a film for packaging food, a film for packaging pharmaceutical or healthcare products, a lidding film, an agricultural film, an industrial film, a tubing, a pipe, a cap, a closure, a film for silage, a film for fumigation or mulch, a three dimensional body, a container, a bottle, a pouch, a tank, and a package for food, beverage or for an industrial, pharmaceutical or cosmetic product.
18 . A polymeric body having enhanced barrier properties to a permeant of interest, the body comprising from 30 to 70 weight percent structural polymer, from 30 to 70 weight percent barrier polymer for the permeant of interest, and from about 3 to about 10 weight percent functionalized polyolefin, wherein the body possesses layer-like morphology.
19 . The polymeric body of claim 18 , wherein the polymeric body is selected from the group consisting of a packaging film, a film for packaging food, an agricultural film, an industrial film, a tubing, a pipe, a cap, a closure, a film for silage, a film for fumigation or mulch, a three dimensional body, a container, a bottle, a pouch, a tank, and a package for food, beverage or for an industrial, pharmaceutical or cosmetic product.
20 . (canceled)
21 . The polymeric body of claim 18 , wherein the polymeric body is a barrier film, wherein the barrier film comprises from 35 to 65 weight percent of the structural polymer, from 35 to 65 weight percent of the barrier polymer, and from 5 to 10 weight percent of the functionalized polyolefin.
22 . A multilayer barrier film comprising the barrier film of claim 21 with at least one second layer, the second layer comprised of a second polymer, wherein the first barrier layer possesses layer-like morphology.
23 . The multilayer barrier film according to claim 22 wherein the second polymer is selected from the group consisting of polyolefins, polyamides, polyesters, polystyrene, polylactic acid, polyhydroxyalkanoate and combinations thereof.
24 . The method of claim 2 , wherein the structural polymer is selected from a group consisting of polyolefins, polyesters, polystyrene, polylactic acid, polyhydroxyalkanoate and combinations thereof, and wherein the barrier polymer is selected from a group consisting of copolymers of ethylene vinyl alcohol, polyvinyl alcohol, polyvinylidene chloride, polyamides, nitrile polymers and combinations thereof.
25 . The method of claim 2 , wherein the permeant is oxygen and wherein the masterbatch comprises from 35 to 65 weight percent of the structural polymer and from 35 to 65 weight percent of the barrier polymer and wherein the masterbatch comprises from 5 to 10 weight percent of the functionalized polyolefin.
26 . The method of claim 2 , wherein the functionalized polyolefin is selected from a group consisting of copolymers of ethylene and/or propylene and one or more unsaturated polar monomers, and polyolefins that are graft-modified with a maleic acid or a maleic anhydride.