Hole transport material, preparation method thereof, and electroluminescent device
The present invention provides a hole transport material, a preparation method thereof, and an electroluminescent device. Through ingenious molecular design, a xanthracene structure is combined with different electron-donating groups to synthesize a series of hole transport materials with a suitable highest occupied molecular orbital (HOMO) energy level and a suitable lowest unoccupied molecular orbital (LUMO) energy level, and a series of high-performance display devices can be manufactured using the hole transport materials provided by the present invention.
1. A hole transport material, comprising a compound consisting of a donor AN and an acceptor B, the compound having a general chemical structure as shown in Formula 1:
AN-BMN Formula 1,
wherein the donor AN is selected from any one of the following structural formulas:
and
the acceptor BMN is selected from any one of the following structural formulas:
wherein the compound AN-BMN has any one of the following structural formulas:
2. A method of preparing a hole transport material, comprising the following steps:
Step S1, adding an acceptor compound BMN-X, a donor compound AN-H, and a catalyst into an organic solvent containing an alkali under an inert gas environment to conduct a reaction for a first time period at a first temperature to obtain a first reaction solution, wherein X is halogen, the donor AN is selected from any one of the following structural formulas:
and the acceptor BMN is selected from any one of the following structural formulas:
wherein the catalyst comprises palladium acetate and tri-tert-butylphosphine tetrafluoroborate, and the compound AN-BMN has any one of the following structural formulas:
Step S2, cooling the first reaction solution to a second temperature to obtain a mixture; and
Step S3, separating the hole transport material from the mixture, the hole transport material comprising a compound having a general chemical structural formula shown in Formula 1:
AN-BMN Formula 1.
3. The method of preparing the hole transport material according to claim 2 , wherein the first temperature ranges from 80° C. to 150° C., and the first time period ranges from 12 hours to 36 hours.
4. The method of preparing the hole transport material according to claim 2 , wherein the second temperature is room temperature.
5. The method of preparing the hole transport material according to claim 2 , wherein in the step S1, the organic solvent is toluene, the alkali is sodium tert-pentyloxylate, and the catalyst comprises a palladium catalyst and phosphine ligand catalyst.
6. The method of preparing the hole transport material according to claim 2 , wherein the step S2 further comprises: subjecting the first reaction solution to extraction, water washing, dehydration, filtration, and centrifugal drying to obtain the mixture.
7. The method of preparing the hole transport material according to claim 2 , wherein in the step S3, the separating is performed by column chromatography with an eluent of dichloromethane and n-hexane in a volume ratio of 1:3.
8. An electroluminescent device, comprising:
a substrate;
a hole injection layer disposed on the substrate;
a hole transport layer disposed on the injection layer;
an electron blocking layer disposed on the hole transport layer;
a light-emitting layer disposed on the electron blocking layer;
a hole blocking layer disposed on the light-emitting layer;
an electron transport layer disposed on the hole blocking layer;
an electron injection layer disposed on the electron transport layer;
an electrode layer disposed on the electron injection layer; and
a light-coupling output layer disposed on the electrode layer,
wherein the hole transport layer comprises the hole transport material according to claim 1 .