Lithographic printing plate precursor
A lithographic printing plate precursor includes a photopolymerizable coating and an overcoat which is deactivated after imagewise exposure and preheating of the precursor.
1. A method for making a printing plate comprising:
image-wise exposing a lithographic printing plate precursor to heat and/or light;
heating the printing plate precursor; and
developing the printing plate precursor, wherein the developing is performed on press by mounting the exposed printing plate precursor on a plate cylinder of a lithographic printing press and rotating the plate cylinder while supplying dampening liquid and/or ink to the photopolymerizable coating, and
wherein the lithographic printing plate precursor comprises:
a support;
a photopolymerizable coating provided on the support; and
an overcoat provided on the photopolymerizable coating, wherein the overcoat includes a compound that is able to generate a volatile decomposition product.
2. The method according to claim 1 , wherein the image-wise exposing includes image-wise exposing the printing plate precursor with laser light having a wavelength between 350 nm and 450 nm.
3. The method according to claim 1 , wherein the heating includes heating the printing plate precursor at a temperature between 80° C. and 300° C.
4. The method according to claim 1 , wherein the heating includes heating the printing plate precursor for a dwell time between 2 seconds and 30 minutes.
5. The method according to claim 1 , wherein the compound includes a heat decomposable compound.
6. The method according to claim 1 , wherein the compound includes a blowing agent.
7. The method according to claim 5 , wherein the heat decomposable compound is selected from the group consisting of carbonates, carbamates, and hydrazides.
8. The method according to claim 6 , wherein the heat decomposable compound is selected from the group consisting of ammonium carbonate, ammonium hydrogen carbonate, ammonium carbamate, benzenesulfonyl hydrazide, and p-toluenesulfonyl hydrazide.
9. The method according to claim 1 , wherein the volatile decomposition product is an inert gas or a gas that is not condensable at room temperature.
10. The method according to claim 1 , wherein the volatile decomposition product is selected from the group consisting of carbon dioxide, carbon mono-oxide, ammonia, oxygen, hydrogen gas, and/or nitrogen gas.
11. The method according to claim 1 , wherein the compound is present in the overcoat between 10 wt. % and 60 wt. %.
12. The method according to claim 1 , wherein the photopolymerizable coating includes a polymerizable compound and a free radical initiator.
13. The method according to claim 1 , wherein the support is grained and anodized aluminum post treated with polyvinylphosphonic acid, polyvinylmethylphosphonic acid, phosphoric acid esters of polyvinyl alcohol, polyvinylsulphonic acid, polyvinylbenzenesulphonic acid, sulphuric acid esters of polyvinyl alcohol, and/or acetals of polyvinyl alcohols formed by reaction with a sulphonated aliphatic aldehyde.