Anti-reflective film, polarizing plate, and display apparatus
The present invention relates to an anti-reflective film including: a hard coating layer; and a low refractive index layer containing a binder resin containing a copolymer of a polyfunctional (meth)acrylate-based monomer, and inorganic particles dispersed in the binder resin, wherein the polyfunctional (meth)acrylate-based monomer includes a 2- to 4-functional (meth)acrylate-based monomer and a 5- to 6-functional (meth)acrylate-based monomer in a weight ratio of 9:1 to 6:4, and a polarizing plate and a display apparatus using the same.
1. An anti-reflective film comprising: a hard coating layer; and
a low refractive index layer containing a binder resin containing a copolymer of a polyfunctional (meth)acrylate-based monomer, a fluorine-based compound containing a photoreactive functional group and inorganic particles dispersed in the binder resin,
wherein the inorganic particles comprise solid inorganic particles having a diameter of 0.5 to 100 nm and hollow inorganic particles having a diameter of 1 to 200 nm,
wherein the polyfunctional (meth)acrylate-based monomer includes a 2- to 4-functional (meth)acrylate-based monomer and a 5- to 6-functional (meth)acrylate-based monomer in a weight ratio of 9:1 to 8:2.
2. The anti-reflective film of claim 1 , wherein the 2- to 4-functional (meth)acrylate-based monomer is pentaerythritol di(meth)acrylate, pentaerythritol tri(meth)acrylate, or a mixture thereof.
3. The anti-reflective film of claim 1 , wherein the 5- to 6-functional (meth)acrylate-based monomer is dipentaerythritol penta(meth)acrylate, dipentaerythritol hexa(meth)acrylate, or a mixture thereof.
4. The anti-reflective film of claim 1 , wherein the low refractive index layer includes the inorganic particles in an amount of 30 to 500 parts by weight based on 100 parts by weight of the copolymer of the polyfunctional (meth)acrylate-based monomer.
5. The anti-reflective film of claim 1 , wherein the low refractive index layer has a refractive index of 1.2 to 1.55.
6. The anti-reflective film of claim 1 , wherein the low refractive index layer has a degree of crosslinking of 85% or more.
7. The anti-reflective film of claim 1 , wherein the hard coating layer includes a binder resin containing a photocurable resin, and organic or inorganic fine particles dispersed in the binder resin.
8. The anti-reflective film of claim 1 , wherein the hard coating layer has a thickness of 1 to 100 μm.
9. The anti-reflective film of claim 1 , wherein the anti-reflective film has an average reflectance of less than 3% in a wavelength region of 380 nm to 780 nm.
10. The anti-reflective film of claim 1 , further comprising a light-transmissive substrate having retardation (Rth) in a thickness direction of 3000 nm or more as measured at a wavelength of 400 nm to 800 nm.
11. A polarizing plate comprising the anti-reflective film of claim 1 .
12. A display apparatus comprising the anti-reflective film of claim 1 .
13. The anti-reflective film of claim 1 , wherein the photoreactive functional group includes a (meth)acrylate group, an epoxide group, a vinyl group, a thiol group or a mixture thereof.