Gear lubricant composition
A gear lubricant composition includes at least 97% by weight, based on the total weight of the lubricant composition, of at least one hydrocarbon-based oil that includes a weight content of isoparaffins ranging from 90 to 0%, a weight content of normal paraffins ranging from 0 to 10% and a carbon content of biological origin greater than or equal to 90% relative to the total weight of the oil, at least 0.01% by weight, based on the total weight of the lubricant composition, of at least one additive selected among the anti-wear additives, extreme pressure additives, anti-corrosion additives, additives having metal-deactivating properties, anti-foam additives, anti-oxidant additives selected among the phenolic anti-oxidants, and the mixtures thereof.
1. A method for lubricating a gear, the method comprising applying a lubricant composition onto gears, the lubricant composition comprising:
at least 97 weight %, relative to the total weight of the lubricant composition, of at least one hydrocarbon oil which has a weight content of isoparaffins ranging from 95 to 100%, a weight content of normal paraffins ranging from 0 to 5% and a carbon content of biological origin equal to or higher than 90% relative to the total weight of the hydrocarbon oil, wherein the hydrocarbon oil has a distillation range ranging from 230 to 340° C., measured according to standard ASTM D86, wherein the hydrocarbon oil has a weight content of aromatic compounds equal to or less than 100 ppm, relative to the total weight of the hydrocarbon oil; and
at least 0.01 weight %, relative to the total weight of the lubricant composition, of at least one additive selected from among anti-wear additives, extreme-pressure additives, anticorrosion additives, metal-deactivators, anti-foam additives, antioxidant additives selected from among phenolic antioxidants, and mixtures thereof.
2. The method according to claim 1 , wherein the composition comprises:
from 97 to 99.95 weight % of hydrocarbon oil relative to the total weight of the lubricant composition; and
from 0.05 to 3 weight %, relative to the total weight of the lubricant composition, of at least one additive selected from among anti-wear additives, extreme-pressure additives, anticorrosion additives, metal-deactivators, anti-foam additives, antioxidants and mixtures thereof.
3. The method according to claim 1 , wherein:
the anti-wear additives are selected from among triaryl thiophosphates, carbamates and thiocarbamates; and/or
the extreme-pressure additives are selected from among ashless phosphorus or sulfur-phosphorus additives; and/or
the anticorrosion additives are selected from among N-acyl sarcosine compounds; and/or
the metal-deactivators are selected from among tolutriazole, derivatives of tolutriazole or dimercaptothiadiazoles; and/or
the anti-foam additives are selected from among silicone compounds; and/or
the antioxidant additives are selected from among phenolic antioxidants and mixtures thereof.
4. The method according to claim 1 , wherein said at least one additive is a phenolic antioxidant.
5. The method according to claim 4 , wherein the antioxidant is selected from among compounds comprising a phenol group in which at least one vicinal carbon of the carbon carrying the alcohol function is substituted by at least one C 1 -C 10 alkyl group.
6. The method according to claim 1 , wherein the composition comprises at least 0.01 weight %, relative to the total weight of the composition, of at least one additive selected from among:
anti-wear additives selected from among triaryl thiophosphates, carbamates and thiocarbamates;
extreme-pressure additives selected from among ashless phosphorus and sulfur-phosphorus additives;
metal-deactivators selected from among tolutriazole, derivatives of tolutriazole or dimercaptothiadiazoles; and
mixtures thereof.
7. The method according to claim 1 , wherein the hydrocarbon oil is selected from among non-cyclic isoparaffins having 14 to 18 carbon atoms.
8. The method according to claim 1 , wherein the hydrocarbon oil comprises:
a carbon content of biological origin equal to or higher than 95%; and/or
a weight content of naphthenic compounds equal to or lower than 1%, relative to the total weight of the hydrocarbon oil.
9. The method according to claim 1 , wherein the hydrocarbon oil has:
a biodegradability at 28 days of at least 60%, measured according to standard OECD 306; and/or
a flash point equal to or higher than 110° C. according to standard EN ISO 2719; and/or
a kinematic viscosity at 40° C. equal to or less than 5 cSt.
10. The method according to claim 1 , wherein the hydrocarbon oil has:
a distillation range ranging from 290° C. to 325° C., measured according to standard ASTM D86; and
a kinematic viscosity at 40° C. equal to less than 5 cSt.
11. The method according to claim 1 , wherein the hydrocarbon oil is obtained by a catalytic hydrogenation process at a temperature of from 80 to 180° C. and at a pressure of from 50 to 160 bar of a deoxygenated and/or isomerized feedstock of biological origin.
12. The method according to claim 1 , wherein the composition comprises:
from 97 to 99.9 weight %, relative to the total weight of the lubricant composition, of a hydrocarbon oil which comprises at least 98 weight % of isoparaffins, less than 2 weight % of normal paraffins, and a carbon content of biological origin equal to or higher than 90% relative to the total weight of the hydrocarbon oil, said hydrocarbon oil having a kinematic viscosity at 40° C. equal to or less than 5 cSt;
from 0.1 to 3 weight %, relative to the total weight of the lubricant composition of at least one additive selected from among:
anti-wear additives selected from among triaryl thiophosphates, carbamates and thiocarbamates;
extreme-pressure additives selected from among ashless phosphorus or sulfur-phosphorus additives;
metal-deactivators selected from among tolutriazole, derivatives of tolutriazole or dimercaptothiadiazoles;
antioxidants selected from among phenolic antioxidants; and
mixtures thereof.
13. The method according to claim 1 , wherein the temperature of application of the composition ranges from 50 to 400° C.
14. A gear lubricant composition comprising:
at least 97 weight %, relative to the total weight of the lubricant composition, of a hydrocarbon oil which has a weight content of isoparaffins in the range of from 95 to 100%, a weight content of normal paraffins in the range of from 0 to 5%, and a carbon content of biological origin equal to or higher than 90% relative to the total weight of the hydrocarbon oil, wherein the hydrocarbon oil has a distillation range ranging from 230 to 340° C., measured according to standard ASTM D86, wherein the hydrocarbon oil has a weight content of aromatic compounds equal to or less than 100 ppm, relative to the total weight of the hydrocarbon oil; and
at least 0.01 weight %, relative to the total weight of the lubricant composition, of at least one additive selected from among anti-wear additives, extreme-pressure additives, anticorrosion additives, metal-deactivators, anti-foam additives, phenolic antioxidant additives, and mixtures thereof, and
with the proviso that if said additive is a phenolic antioxidant, then said phenolic antioxidant is contained in an amount of a least 0.015 weight % relative to the total weight of the lubricant composition.
15. The lubricant composition according to claim 14 , comprising at least 0.1 weight %, relative to the total weight of the lubricant composition, of at least one additive selected from among anti-wear additives, extreme-pressure additives, anticorrosion additives, metal-deactivators, anti-foam additives, phenolic antioxidant additives, and mixtures thereof.
16. The composition according to claim 14 , comprising one or more of the following features:
the anti-wear additives are selected from among triaryl thiophosphates, carbamates and thiocarbamates; and/or
the extreme-pressure additives are selected from among ashless phosphorus or sulfur-phosphorus additives; and/or
the anticorrosion additives are selected from among N-acyl sarcosine compounds; and/or
the metal-deactivators are selected from among tolutriazole, derivatives of tolutriazole or dimercaptothiadiazoles; and/or
the anti-foam additives are selected from among silicone compounds; and/or
the antioxidant additives are selected from among phenolic antioxidants and mixtures thereof; and/or
the at least one additive selected from among:
anti-wear additives selected from among triaryl thiophosphates, carbamates and thiocarbamates;
extreme-pressure additives selected from among ashless phosphorus and sulfur-phosphorus additives;
metal-deactivators selected from among tolutriazole, derivatives of tolutriazole or dimercaptothiadiazoles;
and mixtures thereof; and/or
the hydrocarbon oil is selected from among non-cyclic isoparaffins having 14 to 18 carbon atoms;
the hydrocarbon oil comprises:
a carbon content of biological origin equal to or higher than 95%; and/or
a weight content of naphthenic compounds equal to or lower than 1%, relative to the total weight of the hydrocarbon oil; and/or
the hydrocarbon oil has:
a biodegradability at 28 days of at least 60%, measured according to standard OECD 306; and/or
a flash point equal to or higher than 110° C. according to standard EN ISO 2719; and/or
a kinematic viscosity at 40° C. equal to or less than 5 cSt.
17. The composition according to claim 16 , wherein the hydrocarbon oil has:
a distillation range ranging from 290° C. to 325° C., measured according to standard ASTM D86; and
a kinematic viscosity at 40° C. equal to less than 5 cSt.