IP Library Granted Patent US 11,492,478
Granted Patent B2
US 11,492,478 · App. 16/761,743 · Granted Nov 8, 2022

Polymer composition with improved paint adhesion

Inventors: Claudia Kniesel (Linz, DE); Thomas Lummerstorfer (Linz, DE); Anton Sageder (Linz, DE); Michael Otte (Linz, DE); Andreas Jahn (Linz, DE); Angelica Maëlle Delphine Legras (Linz, DE)
Assignee: Borealis AG
C08L23/14C08K3/34C08L23/0815C08K2201/005C08L2203/30C08L2205/035C08L2207/02
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Quick Facts
Patent No.
US 11,492,478
App. No.
16/761,743
Granted
Nov 8, 2022
Kind
B2
Abstract

The invention is directed at a polypropylene composition comprising a heterophasic propylene copolymer, a plastomer and an inorganic filler. Furthermore, the invention directed at an article comprising the polypropylene composition and the use of the polypropylene composition to improve the adhesion performance of an article.

Claims (66)

1. A polypropylene composition (C) comprising

(a) 55 to 95 parts per weight of a heterophasic propylene copolymer (HECO);

(b) 1 to 20 parts per weight of a plastomer (PL); and

(c) 4 to 25 parts per weight of an inorganic filler (F);

based on the total parts per weight of compounds (a), (b) and (c);

wherein the heterophasic propylene copolymer (HECO) has an amount of xylene cold soluble (XCS) fraction in the range of 22 to 45 wt. %; and

wherein the inorganic filler (F) is mica having a median particle size (D 50 ) in the range of 1.5 to 8.0 μm.

2. The polypropylene composition (C) according to claim 1 , wherein the polypropylene composition (C) has:

(a) a melt flow rate MFR 2 (230° C., 2.16 kg) measured according to ISO 1133 of at least 2 g/10 min;

and/or

(b) xylene soluble (XCS) fraction having an intrinsic viscosity (IV) of at least 3.0 dl/g.

3. The polypropylene composition (C) according to claim 1 , wherein the polypropylene composition (C) has:

(a) a tensile modulus measured according to ISO 527-2 of at least 1000 MPa;

and/or

(b) a tensile strength at yield measured according to ISO 527-2 of at least 5 MPa;

and/or

(c) a tensile stress at break measured according to ISO 527-2 of at least 5 MPa;

and/or

(d) a tensile elongation at break measured according to ISO 527-2 of not more than 100%;

and/or

(e) a Charpy Impact Strength (NIS+23) measured according to ISO 179-1eA:2000 at +23° C. of at least 20 kJ/m 2 ;

and/or

(f) a Charpy Impact Strength (NIS-20) measured according to ISO 179-1eA:2000 at −20° C. of at least 2 kJ/m 2 .

4. The polypropylene composition (C) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises

(a) 70 to 98 parts per weight of a first heterophasic propylene copolymer (HECO1); and

(b) 2 to 30 parts per weight of a second heterophasic propylene copolymer (HECO2);

wherein the first heterophasic propylene copolymer (HECO1) differs from the second heterophasic propylene copolymer (HECO2) in the comonomer content of the xylene cold soluble (XCS) fraction and/or in the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction.

5. The polypropylene composition (C) according to claim 4 , wherein the first heterophasic propylene copolymer (HECO1) and the second heterophasic propylene copolymer (HECO2) together fulfil in-equation (I):

C x (XCS)[HECO1]/ C x (XCS)[HECO2]>1.0  (I)

wherein

C x (XCS) [HECO1] is the comonomer content of the xylene cold soluble (XCS) fraction of the first heterophasic propylene copolymer (HECO1) and

C x (XCS) [HECO2] is the comonomer content of the xylene cold soluble (XCS) fraction of the second heterophasic propylene copolymer (HECO2).

6. The polypropylene composition (C) according to claim 4 , wherein the first heterophasic propylene copolymer (HECO1) and the second heterophasic propylene copolymer (HECO2) together fulfil in-equation (II):

IV(XCS)[HECO2]/IV(XCS)[HECO1]>1.0  (II)

wherein

IV (XCS) [HECO1] is the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the first heterophasic propylene copolymer (HECO1) and

IV (XCS) [HECO2] is the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the second heterophasic propylene copolymer (HECO2).

7. The polypropylene composition (C) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises

(a) 5 to 30 parts per weight of a first heterophasic propylene copolymer (HECO1);

(b) 5 to 30 parts per weight of a second heterophasic propylene copolymer (HECO2); and

(c) 40 to 90 parts per weight of a third heterophasic propylene copolymer (HECO3);

wherein the first heterophasic propylene copolymer (HECO1) differs from the second heterophasic propylene copolymer (HECO2) in comonomer content of the xylene cold soluble (XCS) fraction and/or the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction; and

wherein the third heterophasic propylene copolymer (HECO3) has a higher melt flow rate MFR 2 (230° C., 2.16 kg) measured according to ISO 1133 than the first heterophasic propylene copolymer (HECO1) and the second heterophasic propylene copolymer (HECO2) respectively.

8. The polypropylene composition (C) according to claim 7 , wherein

(a1) the first heterophasic propylene copolymer (HECO1) and the second heterophasic propylene copolymer (HECO2) together fulfil in-equation (I):

C x (XCS)[HECO1]/ C x (XCS)[HECO2]>1.0  (I)

wherein

C x (XCS) [HECO1] is the comonomer content of the xylene cold soluble (XCS) fraction of the first heterophasic propylene copolymer (HECO1);

C x (XCS) [HECO2] is the comonomer content of the xylene cold soluble (XCS) fraction of the second heterophasic propylene copolymer (HECO2);

and/or

(a2) the first heterophasic propylene copolymer (HECO1) and the second heterophasic propylene copolymer (HECO2) together fulfil in-equation (II):

IV(XCS)[HECO2]/IV(XCS)[HECO1]>1.0  (II)

wherein

IV (XCS) [HECO1] is the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the first heterophasic propylene copolymer (HECO1);

IV (XCS) [HECO2] is the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the second heterophasic propylene copolymer (HECO2); and

(b) the first heterophasic propylene copolymer (HECO1), the second heterophasic propylene copolymer (HECO2) and the third heterophasic propylene copolymer (HECO3) together fulfil in-equation (III):

2×MFR[HECO3]/MFR[HECO1]+[MFR[HECO2]>1.0  (III)

wherein

MFR [HECO1] is the melt flow rate MFR 2 (230° C., 2.16 kg) measured according to ISO 1133 of the first heterophasic propylene copolymer (HECO1);

MFR [HECO2] is the melt flow rate MFR 2 (230° C., 2.16 kg) measured according to ISO 1133 of the second heterophasic propylene copolymer (HECO2); and

MFR [HECO3] is the melt flow rate MFR 2 (230° C., 2.16 kg) measured according to ISO 1133 of the third heterophasic propylene copolymer (HECO3).

9. The polypropylene composition (C) according to claim 1 , wherein the plastomer (PL) is an elastomeric ethylene copolymer (EC) comprising units derivable from ethylene and at least one C 4 to C 20 α-olefin.

10. The polypropylene composition (C) according to claim 1 , wherein the polypropylene composition (C) does not comprise other polymers besides the heterophasic propylene copolymer (HECO) and and the plastomer (PL) in an amount exceeding 5 wt.-%, based on the weight of the polypropylene composition (C).

11. The polypropylene composition (C) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) and and the plastomer (PL) are the only polymers present in the the polypropylene composition (C).

12. An article comprising the polypropylene composition (C) according to claim 1 .

13. A method of enhancing paint adhesion of a moulded article comprising utilizing the polypropylene composition (C) according to claim 1 in producing the moulded article.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 5, 2020
From: KNIESEL, CLAUDIA; LUMMERSTORFER, THOMAS; SAGEDER, ANTON; OTTE, MICHAEL; JAHN, ANDREAS; LEGRAS, ANGELICA MAËLLE DELPHINE
To: BOREALIS AG
Reel/Frame 052577/0099 →
Priority Claims (1)
EP 17204058 · Nov 28, 2017 · regional
Continuity (1)
Related Publication 20200347216A1 · Nov 5, 2020
Cited By (5)
US 12,338,299 US 12,398,224 US 12,404,393 US 12,565,578 US 12,570,829