IP Library Granted Patent US 11,504,960
Granted Patent B2
US 11,504,960 · App. 16/762,014 · Granted Nov 22, 2022

Method for producing laminate

Inventors: Megumi Abe (Hiratsuka, JP); Yuichi Matsuki (Hiratsuka, JP)
Assignee: Sika Hamatite Co., Ltd.
B32B38/162B08B1/006B08B3/08B32B7/12B32B27/08B32B37/12B32B38/0008C08J5/128C08J7/123C11D7/3209C11D7/50B32B2310/14C08J2323/12
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Quick Facts
Patent No.
US 11,504,960
App. No.
16/762,014
Granted
Nov 22, 2022
Kind
B2
Abstract

The present invention is to provide a method for producing a laminate having excellent adhesion properties. An embodiment of the present invention is a method for producing a laminate, the method including: a step 1 of dry-treating a surface A of a plastic to obtain a dry-treated plastic having a surface B that has been dry-treated; a step 2 of wiping the surface B with a cleaning tool containing a composition for wiping, the composition containing at least one solvent selected from the group consisting of water and polar solvents, and a silane coupling agent, to obtain a cleaned plastic having a surface C that has been wiped with the cleaning tool; and a step 3 of applying at least one selected from the group consisting of adhesives and primers on the surface C to obtain a laminated body.

Claims (20)

1. A method for producing a laminate, the method comprising:

a step 1 of dry-treating a surface A of a plastic to obtain a dry-treated plastic having a surface B that has been dry-treated;

a step 2 of wiping the surface B with a cleaning tool containing a composition for wiping, the composition containing at least one solvent selected from the group consisting of water and polar solvents, and a silane coupling agent, to obtain a cleaned plastic having a surface C that has been wiped with the cleaning tool; and

a step 3 of applying at least one selected from the group consisting of adhesives and primers on the surface C to obtain a laminate.

2. The method for producing a laminate according to claim 1 , wherein the plastic is at least one selected from the group consisting of polyolefins, polyethylene terephthalates, polymethyl methacrylate resins, polycarbonate resins, polystyrene resins, acrylonitrile styrene copolymer resins, polyvinyl chloride resins, acetate resins, acrylonitrile butadiene styrene resins, polyester resins, and polyamide resins.

3. The method for producing a laminate according to claim 1 , wherein the dry treatment is at least one selected from the group consisting of plasma treatment, corona treatment, flame treatment, ITRO treatment, ultraviolet treatment, and excimer treatment.

4. The method for producing a laminate according to claim 1 , wherein, in the step 2, the surface B is wiped with the cleaning tool by applying a force from 25 to 0.25 kPa to the surface B.

5. The method for producing a laminate according to claim 1 , wherein the composition for wiping contains water as the solvent.

6. The method for producing a laminate according to claim 1 , wherein the silane coupling agent is an amine-based silane coupling agent.

7. The method for producing a laminate according to claim 1 , wherein

the silane coupling agent is at least one selected from the group consisting of

a silane compound having a hydrolyzable silyl group and an aliphatic hydrocarbon group having at least one selected from the group consisting of an amino group and an imino group,

a hydrolyzed condensate of the silane compound, and

an organic polymer-type silane coupling agent having a hydrolyzable silyl group and at least one selected from the group consisting of an amino group and an imino group and having an organic polymer as a main chain.

8. The method for producing a laminate according to claim 1 , wherein the silane coupling agent is water soluble.

9. The method for producing a laminate according to claim 1 , wherein a content of the silane coupling agent is from 0.01 to 30 mass % relative to a total amount of the composition for wiping.

10. The method for producing a laminate according to claim 1 , wherein a wetting tension of the surface B is 39 mN/m or greater.

11. The method for producing a laminate according to claim 1 , wherein a wetting tension of the surface C is 34 mN/m or greater.

12. The method for producing a laminate according to claim 1 , wherein the wetting tension of the surface B is greater than 65 mN/m.

13. The method for producing a laminate according to claim 12 , wherein the wetting tension of the surface C is greater than 45 mN/m.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 21, 2024
From: SIKA JAPAN LTD.
To: SIKA TECHNOLOGY AG
Reel/Frame 066641/0001 →
MERGER Recorded Feb 5, 2024
From: SIKA HAMATITE CO., LTD.
To: SIKA JAPAN LTD.
Reel/Frame 066493/0072 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 8, 2021
From: THE YOKOHAMA RUBBER CO., LTD.
To: SIKA HAMATITE CO., LTD.
Reel/Frame 058048/0083 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 6, 2020
From: ABE, MEGUMI; MATSUKI, YUICHI
To: THE YOKOHAMA RUBBER CO., LTD.
Reel/Frame 052590/0675 →
Priority Claims (1)
JP JP2017-217110 · Nov 10, 2017 · national
Continuity (1)
Related Publication 20200353740A1 · Nov 12, 2020