Polyolefin polymer composition
The present disclosure is generally directed to polyolefin polymers, such as polypropylene homopolymers, and propylene-ethylene copolymers that have improved flow properties. In one embodiment, the polymers can be produced using a solid catalyst component that includes a) dissolving a halide-containing magnesium compound in a mixture, the mixture including an epoxy compound, an organic phosphorus compound, and a hydrocarbon solvent to form a homogenous solution; b) treating the homogenous solution with an organosilicon compound during or after the dissolving step; c) treating the homogenous solution with a first titanium compound in the presence of a first non-phthalate electron donor, and an organosilicon compound, to form a solid precipitate; and d) treating the solid precipitate with a second titanium compound in the presence of a second non-phthalate electron donor to form the solid catalyst component, where the process is free of carboxylic acids and anhydrides.
1. A polymer composition comprising propylene-ethylene copolymer particles including propylene as a primary monomer, the propylene-ethylene copolymer particles comprising ethylene in an amount greater than 3% by weight, the propylene-ethylene copolymer exhibiting a melt flow rate according to ASTM D1238 at 230° C. and a weight of 2.16 kg, of about 50 g/10 min to about 500 g/10 min, and wherein the propylene-ethylene copolymer particles exhibit a Cup Test Index of 2 or less.
2. The polymer composition of claim 1 , wherein the propylene-ethylene copolymer contains ethylene in an amount greater than about 8% by weight.
3. The polymer composition of claim 1 , wherein the propylene-ethylene copolymer contains ethylene in an amount greater than about 10% by weight.
4. The polymer composition of claim 1 , wherein the propylene-ethylene copolymer particles exhibit a Cup Test time of less than 10 seconds.
5. The polymer composition of claim 1 , wherein the propylene-ethylene copolymer includes a first polymer phase combined with a second polymer phase comprising an elastomeric propylene-ethylene copolymer.
6. The polymer composition of claim 1 , wherein the propylene-ethylene copolymer particles have a D50 particle size of from about 300 microns to about 3000 microns and have a bulk density of from about 0.4 g/cm 3 to about 0.6 g/cm 3 .
7. The polymer composition of claim 1 , wherein the propylene-ethylene copolymer is produced in the presence of a catalyst system, the catalyst system comprising a solid catalyst component combined with an aluminum compound, at least one selectivity control agent, and optionally an activity limiting agent, the solid catalyst component comprising a reaction product of a magnesium compound with an epoxy compound, the solid catalyst component further comprising an organic phosphorus compound, a titanium compound, an organosilicon compound, and an internal electron donor.
8. The polymer composition of claim 1 , wherein the propylene-ethylene copolymer is produced in the presence of a catalyst system comprising a solid catalyst component combined with an aluminum compound, at least one selectively control agent, and optionally an activity limiting agent, the solid catalyst component comprising:
magnesium compound including a halide-containing magnesium compound and a reaction product of a magnesium compound with an epoxy compound;
an organic phosphorus compound;
a titanium compound;
an organosilicon compound;
an internal electron donor, the internal electron donor comprising an aryl diester, a diether, a succinate, an organic acid ester, a polycarboxylic acid ester, a polyhydroxy ester, a heterocyclic polycarboxylic acid ester, an inorganic acid ester, an alicyclic polycarboxylic acid ester, a hydroxy-substituted carboxylic acid ester compound having 2 to 30 carbon atoms, or a compound having at least one ether group and at least one ketone group, or mixtures thereof;
wherein the solid catalyst component is free of side reaction products between a carboxylic acid or an anhydride thereof and a magnesium compound or a titanium compound.
9. The polymer composition of claim 1 , wherein the propylene-ethylene copolymer is produced in the presence of a catalyst system that has an extended lifetime such that a catalyst activity of the catalyst system during a second hour of polymerization is no less than about 8% of a catalyst activity of the catalyst system during a first hour of polymerization.
10. A polymer composition comprising particles of polypropylene homopolymer, polypropylene copolymer, or a mixture thereof, wherein the particles have a D50 particle size of about 150 microns to about 3000 microns, the particles exhibit an aspect ratio, B/L3, of greater than about 0.6, and wherein the polymer composition exhibits a bulk density of greater than 0.415 g/cm 3 ; wherein the polypropylene homopolymer or polypropylene copolymer exhibits a melt flow rate according to ASTM D1238 at 230° C. and a weight of 2.16 kg from 50 g/10 min to 500 g/10 min; and wherein the particles comprise microspheres.
11. The polymer composition of claim 10 , wherein the particles have a B/L3 of from about 0.7 to about 1.0.
12. The polymer composition of claim 10 , wherein the polymer composition has a bulk density of from 0.42 g/cm 3 to 0.60 g/cm 3 .
13. The polymer composition of claim 10 , wherein the polypropylene polymer is produced in the presence of a catalyst system, the catalyst system comprising a solid catalyst component combined with an aluminum compound, at least one selectivity control agent, and optionally an activity limiting agent, the solid catalyst component comprising a reaction product of a magnesium compound with an epoxy compound, the solid catalyst component further comprising an organic phosphorus compound, a titanium compound, an organosilicon compound, and an internal electron donor.
14. The polymer composition of claim 13 , wherein the solid catalyst component further comprises a supportive donor, the supportive donor comprising a mono aryl ester, the internal electron donor is represented by one of the following formulas:
wherein:
each of R 1 through R 34 is independently H, F, Cl, Br, I, alkyl, cycloalkyl, cycloalkylalkyl, aryl, aralkyl, heterocyclyl, heterocyclylalkyl, heteroaryl, or heteroarylalkyl; and q is an integer from 0 to 12.
15. The polymer composition of claim 10 , wherein the polypropylene polymer comprises a polypropylene homopolymer.
16. The polymer composition of claim 10 , wherein the polypropylene polymer comprises a propylene-ethylene copolymer.
17. The polymer composition of claim 16 , wherein the polypropylene polymer comprises a heterophasic random copolymer.
18. The polymer composition of claim 10 , wherein the polypropylene polymer is produced in the presence of a catalyst system, the catalyst system comprising a solid catalyst component combined with an aluminum compound, at least one selectively control agent, and optionally an activity limiting agent, the solid catalyst component comprising:
magnesium compound including a halide-containing magnesium compound and a reaction product of a magnesium compound with an epoxy compound;
an organic phosphorus compound;
a titanium compound;
an organosilicon compound;
an internal electron donor, the internal electron donor comprising an aryl diester, a diether, a succinate, an organic acid ester, a polycarboxylic acid ester, a polyhydroxy ester, a heterocyclic polycarboxylic acid ester, an inorganic acid ester, an alicyclic polycarboxylic acid ester, a hydroxy-substituted carboxylic acid ester compound having 2 to 30 carbon atoms, or a compound having at least one ether group and at least one ketone group, or mixtures thereof; wherein the solid catalyst component is free of side reaction products between a carboxylic acid or an anhydride thereof and a magnesium compound or a titanium compound.