Positive electrode plate, electrochemical device and safety coating
The present application relates to a positive electrode plate, an electrochemical device and a safety coating. The positive electrode plate comprises a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, the safety coating comprising a fluorinated polyolefin and/or chlorinated polyolefin polymer matrix, a conductive material and an inorganic filler. The positive electrode plate can quickly disconnect circuit when the electrochemical device (such as a capacitor, primary battery, or secondary battery, and the like) is in a high temperature condition or an internal short circuit occurs, thereby improving high temperature safety performance of the electrochemical device.
1. A positive electrode plate, comprising a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, the safety coating comprising a polymer matrix, a conductive material and an inorganic filler,
wherein the polymer matrix is fluorinated polyolefin and/or chlorinated polyolefin;
wherein based on the total weight of the safety coating,
a weight percentage of the polymer matrix is from 35 wt % to 75 wt %,
a weight percentage of the conductive material is from 5 wt % to 25 wt %, and
a weight percentage of the inorganic filler is from 10 wt % to 60 wt %; and
wherein the inorganic filler is a carbon coating modified positive electrochemically active material.
2. The positive electrode plate as claimed in claim 1 , wherein the polymer matrix is at least one selected from polyvinylidene fluoride (PVDF), carboxylic acid modified PVDF, acrylic acid modified PVDF, polyvinylidene chloride (PVDC), carboxylic acid modified PVDC, acrylic acid modified PVDC, PVDF copolymer, or PVDC copolymer.
3. The positive electrode plate as claimed in claim 1 , wherein the conductive material is at least one selected from a conductive carbon-based material, a conductive metal material, or a conductive polymer material.
4. The positive electrode plate as claimed in claim 1 , wherein the inorganic filler is at least one selected from a conductive carbon coating modified lithium cobalt oxide, a conductive carbon coating modified lithium nickel manganese cobalt oxide, a conductive carbon coating modified lithium nickel manganese aluminum oxide, a conductive carbon coating modified lithium iron phosphate, a conductive carbon coating modified lithium vanadium phosphate, a conductive carbon coating modified lithium cobalt phosphate, a conductive carbon coating modified lithium manganese phosphate, a conductive carbon coating modified lithium iron silicate, a conductive carbon coating modified lithium vanadium silicate, a conductive carbon coating modified lithium cobalt silicate, a conductive carbon coating modified lithium manganese silicate, a conductive carbon coating modified spinel lithium manganese oxide, a conductive carbon coating modified spinel lithium nickel manganese oxide, or a conductive carbon coating modified lithium titanate.
5. The positive electrode plate as claimed in claim 1 , wherein the safety coating has a thickness H of 1 μm≤H≤20 μm.
6. The positive electrode plate as claimed in claim 1 , wherein in the carbon coating modified positive electrochemically active material, the weight percentage of carbon is from 0.5 wt % to 5 wt % based on the weight of the carbon coating modified positive electrochemically active material.
7. The positive electrode plate as claimed in claim 1 , wherein based on the total weight of the safety coating, the weight percentage of the polymer matrix is from 50 wt % to 75 wt %, the weight percentage of the conductive material is from 5 wt % to 15 wt %, and the weight percentage of the inorganic filler is from 15 wt % to 45 wt %.
8. An electrochemical device, comprising the positive electrode plate as claimed in claim 1 , which is a capacitor, a primary battery or a secondary battery.
9. A safety coating for a positive electrode plate, comprising a polymer matrix, a conductive material and an inorganic filler,
wherein the polymer matrix is a fluorinated polyolefin and/or chlorinated polyolefin polymer matrix;
wherein based on the total weight of the safety coating,
a weight percentage of the polymer matrix is from 35 wt % to 75 wt %,
a weight percentage of the conductive material is from 5 wt % to 25 wt %, and
a weight percentage of the inorganic filler is from 10 wt % to 60 wt %; and
wherein the inorganic filler is a carbon coating modified positive electrochemically active material.
10. The safety coating as claimed in claim 9 , wherein based on the total weight of the safety coating, the weight percentage of the polymer matrix is from 50 wt % to 75 wt %, the weight percentage of the conductive material is from 5 wt % to 15 wt %, and the weight percentage of the inorganic filler is from 15 wt % to 45 wt %.
11. The positive electrode plate as claimed in claim 3 , wherein the conductive carbon-based material is selected from at least one of conductive carbon black, acetylene black, graphite, graphene, carbon nanotubes, carbon nanofibers.
12. The positive electrode plate as claimed in claim 3 , wherein the conductive metal material is at least one selected from Al powder, Ni powder, or gold powder.
13. The positive electrode plate as claimed in claim 3 , wherein the conductive polymer material is at least one selected from conductive polythiophene, conductive polypyrrole, or conductive polyaniline.
14. The positive electrode plate as claimed in claim 1 , wherein the safety coating has a thickness H of 3 μm≤H≤10 μm.
15. The positive electrode plate as claimed in claim 2 , wherein in the carbon coating modified positive electrochemically active material, the weight percentage of carbon is from 0.5 wt % to 5 wt % based on the weight of the carbon coating modified positive electrochemically active material.
16. The positive electrode plate as claimed in claim 3 , wherein in the carbon coating modified positive electrochemically active material, the weight percentage of carbon is from 0.5 wt % to 5 wt % based on the weight of the carbon coating modified positive electrochemically active material.
17. The positive electrode plate as claimed in claim 4 , wherein in the carbon coating modified positive electrochemically active material, the weight percentage of carbon is from 0.5 wt % to 5 wt % based on the weight of the carbon coating modified positive electrochemically active material.