IP Library Granted Patent US 11,912,849
Granted Patent B2
US 11,912,849 · App. 16/763,014 · Granted Feb 27, 2024

Fiber reinforced polypropylene composition

Inventors: Michael Jerabek (Linz, AT); Wolfgang Stockreiter (Linz, AT); Thomas Lummerstorfer (Linz, AT)
Assignee: Borealis AG
C08L23/12C08J3/126C08K7/14C08L23/0815C08L51/003C08L51/06C08K2201/003C08K2201/004C08L2205/025C08L2205/035
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,912,849
App. No.
16/763,014
Granted
Feb 27, 2024
Kind
B2
Abstract

The present invention is directed to granules comprising a fiber reinforced composition (C), said composition comprising a propylene polymer (PP), an elastomeric ethylene copolymer (E) and long fibers (LF).

Claims (61)

1. Granules comprising a fiber reinforced composition (C), comprising

i) an at least bimodal propylene polymer (PP), wherein the propylene polymer (PP) has a xylene cold soluble (XCS) content of below 3.1 wt.-%,

ii) an elastomeric ethylene copolymer (E) which is a copolymer of ethylene and a C 4 -C 10 α-olefin,

iii) an adhesion promoter (AP), and

iv) long fibers (LF),

wherein said fiber reinforced composition (C) fulfils in-equation (Ia)

4

0

.

0

>

w

(

P

P

)

w

(

E

)

>

5

.

3

,

(

Ia

)

wherein w(PP) is the weight fraction [in wt.-%] of the propylene polymer (PP), based on the overall weight of the fiber reinforced composition (C), and w(E) is the weight fraction [in wt.-%] of the elastomeric ethylene copolymer (E), based on the overall weight of the fiber reinforced composition (C);

wherein the propylene polymer (PP) comprises

i′) a first propylene polymer (PP1) having a melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 of at least 100 g/10 min, and

ii′) a second propylene polymer (PP2) having a melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 below 150 g/10 min,

with the proviso that the first polypropylene (PP1) has a higher melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 than the second propylene polymer (PP2), and

wherein the granules comprise

a) an inner layer comprising the long fibers (LF) and the first propylene polymer (PP1), and

b) an outer layer coated onto the core comprising the second propylene polymer (PP2) and the elastomeric ethylene copolymer (E),

wherein the inner layer and/or the outer layer further comprises the adhesion promoter (AP).

2. The granules according to claim 1 , wherein the fiber reinforced composition (C) comprises

i) 30.0 to 80.0 wt.-% of the propylene polymer (PP),

ii) 2.0 to 12.0 wt.-% of the elastomeric ethylene copolymer (E),

iii) 0.1 to 5.0 wt.-% of the adhesion promoter (AP), and

iv) 10.0 to 60.0 wt.-% of the long fibers (LF),

based on the overall weight of the fiber reinforced composition (C).

3. The granules according to claim 1 , wherein the adhesion promoter (AP) is a polar modified polypropylene (PM-PP), which is a propylene homo- or copolymer grafted with maleic anhydride having a melt flow rate MFR (190° C., 2.16 kg) determined according to ISO 1133 of at least 50.0 g/10 min.

4. The granules according to claim 1 , wherein the elastomeric ethylene copolymer (E) has a melt flow rate MFR (190° C., 2.16 kg) determined according to ISO 1133 of at least 25.0 g/10 min.

5. The granules according to claim 1 , wherein the elastomeric ethylene copolymer (E) has a comonomer content of 2.0 to 25.0 mol-%.

6. The granules according to claim 1 , wherein the elastomeric ethylene copolymer (E) has a density below 0.900 g/cm 3 .

7. The granules according to claim 1 , wherein the elastomeric ethylene copolymer (E) is a copolymer of ethylene and 1-octene.

8. The granules according to claim 1 , wherein the propylene polymer (PP) is a propylene homopolymer.

9. The granules according to claim 1 , wherein the long fibers (LF) are selected from the group consisting of glass fibers, metal fibers, ceramic fibers, carbon fibers, and graphite fibers.

10. The granules according to claim 9 , wherein the long fibers (LF) are long glass fibres (LGF).

11. The granules according to claim 1 , wherein the long fibers have a diameter of at least 10 μm.

12. The granules according to claim 1 , wherein the second propylene polymer (PP2) is at least bimodal.

13. The granules according to claim 1 , wherein said granules are obtained by

a) contacting the long fibers (LF) with a melt of the first polypropylene (PP1) and the adhesion promoter (AP), thereby obtaining impregnated fibers,

b) contacting the impregnated fibers obtained in step a) with a melt of the second polypropylene (PP2) and the elastomeric ethylene copolymer (E), thereby obtaining a strand of fiber reinforced polypropylene, and

c) cutting the strand of fiber reinforced polypropylene obtained in step b) into granules.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 23, 2020
From: JERABEK, MICHAEL; STOCKREITER, WOLFGANG; LUMMERSTORFER, THOMAS
To: BOREALIS AG
Reel/Frame 053017/0596 →