Separator including active layer having lithium-occluding material, and electricity storage device including the same
Provided is a separator for electricity storage devices, which comprises an active layer that contains a material (A) that is capable of absorbing lithium (Li), and which has an air permeability of 650 s/100 ml or less.
1. A separator for an electricity storage device comprising
an active material having a conducting material (B), and a material (A) able to occlude lithium (Li),
wherein the separator for an electricity storage device has an air permeability of 650 s/100 ml or lower,
the active layer comprises the material (A) that is able to occlude lithium, and the conducting material (B),
the material (A) has a mean particle diameter at least 1.1 times and no greater than 500 times a mean particle diameter of the conducting material (B), and
the conducting material (B) comprises a conductive substance having an electrical resistivity of no higher than 0.1 Ωcm.
2. The separator according to claim 1 , wherein the mean particle diameter of the material (A) is 1 μm or larger and 30 μm or smaller, and the mean particle diameter of the conducting material (B) is 0.005 μm or larger and smaller than 1 μm.
3. The separator according to claim 2 , wherein the separator has at least one insulating layer, with the active layer being provided on the insulating layer.
4. The separator according to claim 3 , wherein the at least one insulating layer comprises a first insulating layer and a second insulating layer, with the active layer being sandwiched between the first insulating layer and the second insulating layer.
5. The separator according to claim 4 , wherein the first insulating layer and the second insulating layer comprise one or more selected from the group consisting of polyolefins, polyphenylene ethers, polysulfones, polyethersulfones, polyphenylene sulfides, polyetherimides, polyamideimides, polyamides, polyesters and inorganic particles.
6. The separator for an electricity storage device according to claim 4 , wherein an average number of pores in either or both of the first and second insulating layers is 10/μm 2 or greater.
7. The separator according to claim 4 , wherein an average number of pores in either or both of the first and second insulating layers is no greater than 200/μm 2 .
8. The separator according to claim 4 , 6 or 7 , wherein the first insulating layer or the second insulating layer comprises a polyolefin resin, the polyolefin resin content in the first insulating layer or second insulating layer being 30 weight % or greater and 100 weight % or less.
9. The separator according to claim 8 , wherein a mean pore size of either or both of the first and second insulating layers is 0.03 to 0.15 μm.
10. The separator according to claim 9 , wherein either or both of the first and second insulating layers comprise inorganic particles, and the inorganic particles have one or more shapes selected from the group consisting of scaly tabular and block shapes.
11. The separator according to claim 10 , wherein the material (A) able to occlude lithium is flaky, scaly, tabular, block-shaped or spherical.
12. The separator according to claim 11 , wherein a voltage value during short circuiting in a withstand voltage measurement test is 0.3 to 4.5 kV.
13. An electricity storage device comprising a positive electrode, the separator according to claim 12 , a negative electrode, and a lithium (Li)-conducting medium, wherein the Li-conducting medium is in liquid form, gel form or solid form.
14. The electricity storage device according to claim 13 , wherein a potential (vsLi + /Li) of the negative electrode during charge is lower than that of the material (A) able to occlude lithium (Li).
15. The electricity storage device according to claim 13 , which is a lithium battery or a lithium ion secondary battery.