Sealable and easy opening polyester films
The invention discloses a heat sealable coextruded multilayer polyester based lidding film that forms hermetic and easy opening seals onto polyester containers and its use in food packaging.
1 . A heat sealable, optionally oriented, coextruded multilayer polyester based lidding film comprising at least the following layers:
1) a heat-sealable layer 1) which is a first outer layer of the lidding film and is a polyester based first outer layer, comprising at least 60 wt % polyesters of aromatic dicarboxylic acids, the heat-sealable layer being heat sealable at a temperature of from 110° C. to 150° C. and the film having a Dopack value of at least 0.25 when the heat-sealable layer 1) is sealed to a CPET Faerch 2155-1E tray, using a Mecaplastic 1000 heat sealing machine with a sealing time of 1 second at a pressure of 2 to 10 bar;
2) an inner layer 2) comprising at least 95 wt % of a composition consisting of:
a) between 40 and 99 wt % of one or more polymers selected from ethylene (meth)acrylate/(meth)acrylic acid copolymers, anhydride modified ethylene(meth)acrylate/(meth)acrylic acid copolymers, anhydride modified ethylene alpha olefin copolymers and mixtures thereof,
b) between 1 and 60 wt % of one or more further polymers selected from polyolefins, ethylene vinyl acetate copolymers (EVA) and mixtures thereof;
3) a polyester based layer 3) comprising at least 60 wt % of polyesters of aromatic dicarboxylic acids; wherein layer 2) adheres to layer 1) and layer 3);
wherein the lidding film comprises at least 60 wt % polyesters;
the lidding film further comprising an antifog agent coated on the surface of the heat-sealable layer 1) in an amount of from 40 mg/sqm to 140 mg/sqm; and
a second outer layer of the lidding film, which is opposite to the heat sealable layer 1), comprises at least 90 wt % polyesters.
2 . A heat sealable film according to claim 1 , wherein the overall composition of the film comprises at least 60 wt % polyesters of aromatic dicarboxylic acids or polyesters of terephthalic acid.
3 . A heat sealable film according to claim 1 , having between 3 and 10 layers and having a total thickness between 3 and 100 microns and wherein heat-sealable layer 1) has a thickness comprised between 0.5 and 15 microns and layer 2) has a thickness comprised between 2 and 30 microns and layer 3) has a thickness comprised between 5 and 60 microns.
4 . A heat sealable film according to claim 1 , which is heat shrinkable film with a percentage of free shrink at 120° C. of at least 5% in longitudinal and/or transverse direction, measured in oil according to ASTM D 2732 and/or oriented, with an orientation ratio between about 2:1 and about 5:1 in both longitudinal and transverse direction.
5 . Heat sealable film according to claim 1 , wherein said composition of layer 2) comprises an amount of at least 45 wt % of one or more polymers selected from ethylene (meth)acrylate/(meth)acrylic acid copolymers, anhydride modified ethylene (meth)acrylate/(meth)acrylic acid copolymers and anhydride modified ethylene alpha olefin copolymers.
6 . Heat sealable film according to claim 1 , wherein said composition of layer 2) consists of 99 wt % of one or more polymers selected from ethylene (meth)acrylate/(meth)acrylic acid copolymers, anhydride modified ethylene (meth)acrylate/(meth)acrylic acid copolymers and anhydride modified ethylene alpha olefin copolymers and 1 wt % of one or more further polymers selected from polyolefins, ethylene vinyl acetate copolymers (EVA) and mixtures thereof.
7 . Heat sealable film according to claim 1 , wherein said ethylene (meth)acrylate copolymers are selected from ethylene C1-C4 alkyl (meth)acrylate copolymers comprising between 5 and 40 wt % methyl acrylate.
8 . Heat sealable film according to claim 1 , wherein the between 40 and 99 wt % of one or more polymers of inner layer 2) are anhydride modified ethylene (C4-C10) alpha olefin copolymers.
9 . Heat sealable film according to claim 1 , wherein said anhydride modified ethylene (meth)acrylate/(meth)acrylic acid copolymers are maleic anhydride modified and/or said ethylene (meth)acrylate/(meth)acrylic acid copolymers are ethylene methylacrylate copolymers.
10 . Heat sealable film according to claim 1 , wherein said polyolefins in the composition of layer 2) are selected from propylene/ethylene/butene copolymers and propylene/ethylene copolymers; polybutenes and ethylene alfa olefin copolymers, ethylene C4-C10 alpha olefin copolymers, linear low density polyethylenes and/or said ethylene vinyl acetate copolymers (EVA) are ethylene/vinyl acetate/carbon monoxide copolymers, with a comonomer content between 20 and 30 wt %.
11 . Heat sealable film according to claim 1 , wherein the heat sealable layer 1) comprises at least 90 wt % of one or more polyesters and the second outer layer of the film is the polyester based layer 3).
12 . Heat sealable film according to claim 1 , wherein the polyesters in heat-sealable layer 1) comprise at least 50 wt % of amorphous polyesters and/or said polyesters are copolyesters.
13 . Heat sealable film according to claim 1 , wherein the polyesters of an outer layer of the film, opposite to the heat-sealable layer 1, comprise at least 80 wt % of (semi) crystalline polyesters and an amount between 1 and 5 wt % of amorphous polyesters and/or said polyesters are copolyesters.
14 . Heat sealable film according to claim 1 , wherein the film has more than 3 layers and layer 3) comprises at least 90 wt % of one or more polyesters.
15 . Heat sealable film according to claim 14 , wherein said polyesters consist of an amount between 50 wt % and 100 wt % of (semi) crystalline polyesters and an amount between 0 and 50 wt % of amorphous polyesters and/or said polyesters are copolyesters.
16 . Heat sealable film according to claim 1 , further comprising an antifog agent coated on at least the surface of the heat-sealable layer 1).
17 . A heat sealable film according to claim 1 , wherein the overall composition of the film comprises at least 80 wt % of polyesters selected from aromatic dicarboxylic acids or terephthalic acid.
18 . Heat sealable film according to claim 1 , wherein the polyester based layer 3) is an inner layer of the film.