Graphite article and method of making same
A graphite article formed of a creped graphite sheet is provided. The creped graphite sheet has a first major surface and a second major surface oppositely disposed to the first major surface and a plurality of macrofolds, each macrofold having a plurality of associated microfolds, wherein each microfold is smaller than the associated macrofold. The creped graphite article has improved flexibility as compared to a graphite sheet which has not been creped. The creped graphite sheet can be formed of a sheet of flexible natural graphite or a sheet of synthetic graphite.
1. A graphite article comprising:
a graphite sheet expanded in Z-direction by creping, the creped graphite sheet having a first major surface and a second major surface oppositely disposed to the first major surface, the creped graphite sheet having a plurality of macrofolds, each macrofold having a plurality of associated microfolds, wherein each microfold is smaller than the associated macrofold, wherein the Z-direction is perpendicular to the plane of the creped graphite sheet, and wherein the plurality of macrofolds is nonuniform and/or the plurality of associated microfolds is nonuniform.
2. The graphite article of claim 1 wherein the macrofolds comprise convex macrofolds and concave macrofolds.
3. The graphite article of claim 1 wherein the macrofolds comprise alternating convex macrofolds and concave macrofolds.
4. The graphite article of claim 1 wherein the thickness (Tc) of the creped graphite sheet is 50 microns to 2 mm.
5. The graphite article of claim 1 wherein the height (H) of the graphite article is more than 100 times greater than the thickness (Tc) of the creped graphite sheet.
6. The graphite article of claim 1 wherein a macrofold comprises more than two microfolds.
7. The graphite article of claim 1 wherein the height ratio between at least one of the macrofolds and at least one of the microfolds is at least 3:1.
8. The graphite article of claim 1 arranged in a three-dimensional shape having a Z-direction measurement of at least 0.5 mm.
9. The graphite article of claim 1 wherein the graphite article further comprises oil contained in the macrofolds.
10. The graphite article of claim 1 wherein the graphite article exhibits elastic and/or plastic properties.
11. The graphite article of claim 1 wherein an elongation of the graphite article comprises at least 10% of the original length of the graphite article.
12. The graphite article of claim 1 wherein a difference of in-plane diffusivity in the x-y directions comprises at least 15%.
13. The graphite article of claim 1 wherein the graphite article comprises a thermal interface.
14. The graphite article of claim 1 wherein the graphite article exhibits a thermal impedance of less than 0.5° C.*cm 2 /W at a contact pressure of about 700 kPa.