Catalyst and preparation thereof
The present invention relates to a process for producing of solid particulate olefin polymerisation catalyst or catalyst carrier comprising forming a solution of the catalyst or a catalyst carrier in a solvent, subjecting the solution into an atomization by spraying the solution via a capillary vibrating spray nozzle with a capillary orifice having a diameter of 5 to 100 μm generating a laminar jet of liquid, which disintegrates into liquid droplets entering into the spray-dryer, transforming the droplets with aid of a gas to solid particulate catalyst or carrier in the spray-dryer and recovering the solid particulate olefin polymerisation catalyst or carrier having particle size distribution defined by a volumetric SPAN of 0.7 or less. The invention further relates to the catalyst produced by the methods, and use thereof in olefin polymerisation process.
1. A process for producing a solid particulate olefin polymerization catalyst or catalyst carrier, the process comprising the steps:
i) forming a solution of the catalyst or catalyst carrier in a solvent,
ii) subjecting the solution into an atomization by spraying the solution via a capillary vibrating spray nozzle with a capillary orifice having a diameter of 5 to 100 μm thereby generating a laminar jet of liquid, which disintegrates into liquid droplets entering into a spray-dryer,
iii) transforming the droplets to the solid particulate olefin polymerization catalyst or catalyst carrier in the spray-dryer with aid of a gas, and
iv) recovering the solid particulate olefin polymerization catalyst or catalyst carrier having a particle size distribution defined by a volumetric SPAN of 0.7 or less.
2. The process according to claim 1 , wherein the solid particulate olefin polymerization catalyst or catalyst carrier has a medium particle size in the range of 5 to 150 μm.
3. The process according to claim 1 , wherein in step iii) the gas is inert and is used as a co-current gas flow.
4. The process according to claim 1 , wherein the solid particulate olefin polymerization catalyst is a Ziegler-Natta catalyst.
5. The process according to claim 1 , wherein the catalyst carrier is treated with a compound of a transition metal, to obtain the polymerization catalyst in solid particulate form.
6. The process according to claim 1 , wherein the solid particulate olefin polymerization catalyst carrier is a MgCl 2 based carrier comprising an adduct of formula MgCl 2 *mROH, where R is a linear or branched alkyl group containing 1 to 12 carbon atoms.
7. The process according to claim 1 , wherein the solid particulate olefin polymerization catalyst or catalyst carrier has a volumetric SPAN of 0.5 or less.
8. A polymerization process for producing polymers of ethylene or α-olefin monomers of 3 to 10 C-atoms, or (co)polymers thereof with ethylene and/or other α-olefin comonomers of 3 to 12 C-atoms, the process comprising the steps of:
a) preparing a solid particulate catalyst carrier by the process of claim 1 and treating the solid particulate catalyst carrier with catalyst compounds to form a solid particulate olefin polymerization catalyst, and
b) polymerizing ethylene or α-olefinmonomers, optionally with comonomer(s), in the presence of the solid particulate olefin polymerization catalyst prepared in step a) under polymerization conditions in at least one polymerization reactor.