Method for forming printed material and system for forming printed material
A method for forming a printed material includes forming an image on a recording medium; applying particles to a surface of the recording medium, the surface having the image formed thereon; heating the particles applied to the recording medium; and pressurizing, in a thickness direction, a multilayer body obtained by folding the recording medium so that the heated particles are sandwiched between flaps of the recording medium or a multilayer body obtained by placing another medium on top of the recording medium with the heated particles therebetween. The particles contain a styrene resin and a (meth)acrylic acid ester resin. The (meth)acrylic acid ester resin contains two (meth)acrylic acid ester monomer units, and a mass ratio of the (meth)acrylic acid ester monomer units relative to a total of polymerization components is 90 mass % or more.
1. A method for forming a printed material, the method comprising:
forming an image on a recording medium;
applying particles to a surface of the recording medium, the surface having the image formed thereon;
heating the particles applied to the recording medium; and
pressurizing, in a thickness direction, a multilayer body obtained by folding the recording medium so that the heated particles are sandwiched between flaps of the recording medium or a multilayer body obtained by placing another recording medium on top of the recording medium with the heated particles therebetween,
wherein the particles contain a styrene resin and a (meth)acrylic acid ester resin,
the (meth)acrylic acid ester resin contains two (meth)acrylic acid ester monomer units, and a mass ratio of the (meth)acrylic acid ester monomer units relative to a total of polymerization components is 90 mass % or more,
the particles have two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature is 30° C. or more, and
the applying comprises electrophotographically applying the particles to the recording medium by using an electrostatic charge image developer containing the particles.
2. The method for forming a printed material according to claim 1 , wherein the heating involves heating the particles by causing a member to contact the particles, the member having a surface having a set temperature in a range of 130° C. to 200° C.
3. The method for forming a printed material according to claim 1 , wherein the heating further involves pressurizing the particles.
4. The method for forming a printed material according to claim 1 , wherein the pressurizing involves pressurizing the multilayer body in the thickness direction by causing the multilayer body to pass between a pair of rolls separated from each other by an interval C, and the interval C is in a range of 0.01 mm to 0.40 mm.
5. The method for forming a printed material according to claim 1 , wherein, in the pressurizing, a pressure applied in the thickness direction of the multilayer body is in a range of 48 MPa to 120 MPa as measured by using a pressure measuring film.
6. The method for forming a printed material according to claim 1 , wherein the electrostatic charge image developer contains color particles, and the forming involves using the electrostatic charge image developer to electrophotographically form the image formed of the color particles on the recording medium.
7. The method for forming a printed material according to claim 6 , wherein a ratio (D B /D A ) of a volume average particle diameter D B of the particles used in the applying to a volume average particle diameter D A of the color particles used in the forming is in a range of 0.5 to 3.0.
8. The method for forming a printed material according to claim 1 , wherein a ratio of styrene monomer unit to a total of polymerization components of the styrene resin in the particles is in a range of 60 mass % to 95 mass %.
9. The method for forming a printed material according to claim 1 , wherein a mass ratio between the two (meth)acrylic acid ester monomer units contained as polymerization components in the (meth)acrylic acid ester resin in the particles is in a range of 80:20 to 20:80.
10. The method for forming a printed material according to claim 1 , wherein the (meth)acrylic acid ester resin in the particles contains two (meth)acrylic acid alkyl ester monomer units, and a difference in the number of carbon atoms in an alkyl group between the two (meth)acrylic acid alkyl ester monomer units is in a range of 1 to 4.
11. The method for forming a printed material according to claim 1 , wherein the styrene resin in the particles further contains a (meth)acrylic acid ester monomer unit.
12. The method for forming a printed material according to claim 11 , wherein the (meth)acrylic acid ester monomer unit contained as a polymerization component in the styrene resin is selected from n-butyl acrylate and 2-ethylhexyl acrylate.
13. The method for forming a printed material according to claim 1 , wherein the styrene resin and the (meth)acrylic acid ester resin in the particles contain the same (meth)acrylic acid ester monomer unit.
14. The method for forming a printed material according to claim 1 , wherein the (meth)acrylic acid ester resin contains 2-ethylhexyl acrylate monomer unit and n-butyl acrylate monomer unit.
15. The method for forming a printed material according to claim 1 , wherein the particles have a sea phase containing the styrene resin and island phases containing the (meth)acrylic acid ester resin and being dispersed in the sea phase.
16. The method for forming a printed material according to claim 15 , wherein the island phases have an average size in a range of 200 nm to 500 nm.
17. The method for forming a printed material according to claim 1 , wherein a temperature at which the particles exhibit a viscosity of 10000 Pas at a pressure of 4 MPa is 90° C. or less.
18. A system for forming a printed material, the system comprising:
an image forming unit that forms an image on a recording medium;
a particle applying unit that electrophotographically applies particles to the recording medium having the image formed thereon;
a particle heating unit that heats the particles applied to the recording medium; and
a multilayer body pressurizing unit that pressurizes, in a thickness direction, a multilayer body obtained by folding the recording medium so that the heated particles are sandwiched between flaps of the recording medium or a multilayer body obtained by placing another recording medium on top of the recording medium with the heated particles therebetween,
wherein the particles contain a styrene resin and a (meth)acrylic acid ester resin,
the (meth)acrylic acid ester resin contains two (meth)acrylic acid ester monomer units, and a mass ratio of the (meth)acrylic acid ester monomer units relative to a total of polymerization components is 90 mass % or more, and
the particles have two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature is 30° C. or more.