Method for fabricating a ceramic material
A ceramic article includes a ceramic matrix composite that has a porous reinforcement structure and a ceramic matrix within pores of the porous reinforcement structure. The ceramic matrix composite includes a surface zone comprised of an exterior surface of the ceramic matrix composite and pores that extend from the exterior surface into the ceramic matrix composite. A glaze material seals the surface zone within the pores of the surface zone and on the exterior surface of the surface zone as an exterior glaze layer on the ceramic matrix composite. The glaze material is a glass or glass-ceramic material. The ceramic matrix composite includes an interior zone under the surface zone, and the interior zone is free of any of the glaze material and has a greater porosity than the surface zone.
1. A ceramic article comprising:
a ceramic matrix composite including a porous reinforcement structure and a ceramic matrix within pores of the porous reinforcement structure, the ceramic matrix composite including a surface zone comprised of an exterior surface of the ceramic matrix composite and pores that extend from the exterior surface into the ceramic matrix composite;
a glaze material sealing the surface zone within the pores of the surface zone and on the exterior surface of the surface zone as an exterior glaze layer on the ceramic matrix composite, wherein the glaze material is a glass-ceramic material, and the ceramic matrix composite including an interior zone under the surface zone, the interior zone being free of any of the glaze material and having a greater porosity than the surface zone;
wherein the glaze material defines a distinct border between the interior zone that has no glaze material and the surface zone that has the glaze material; and
wherein the glaze material comprises a glass-ceramic material that includes at least one rare earth metal from La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, including Sc, Y, and Hf, and combinations thereof.
2. The ceramic article as recited in claim 1 , wherein the glaze material includes at least one rare earth metal from Ce, Nd, Gd, Dy, Yb, including Y and Hf, and combinations thereof.
3. The ceramic article as recited in claim 1 , wherein the glaze material includes at least one element from boron, barium, calcium, magnesium, lithium, sodium, potassium, aluminum, phosphorus, strontium, zinc, and combinations thereof.
4. The ceramic article as recited in claim 1 , wherein the glaze material includes a nucleating agent forming crystalline phases with application of a heat treatment.
5. The ceramic article as recited in claim 4 , wherein the nucleating agent includes zirconium or a compound containing zirconium.
6. The ceramic article as recited in claim 1 , wherein the glaze material comprises a glass-ceramic from one of Li 2 O x-Al 2 O 3 y-nSiO 2 -System (LAS-System), MgO x-Al 2 O 3 y-nSiO 2 -System (MAS-System), ZnO x-Al 2 O 3 y-nSiO 2 -System (ZAS-System), CaO x-Al 2 O 3 y-nSiO 2 -System (CAS), BaO x-MgO y-Al 2 O 3 z-nSiO 2 -System (BMAS-System), CaO x-MgO y-Al 2 O 3 z-nSiO 2 -System (CMAS-System), BaO x-Al 2 O 3 y-nSiO 2 -System (BAS-System), SrO x-Al 2 O 3 y-nSiO 2 -System (SAS-System), and REO-x-Al 2 O 3 -nSiO 2 -Systems, where REO are oxides of the rare earth metals.
7. The ceramic article as recited in claim 6 , wherein the glaze material includes at least one element from Ce, Nd, Ti, Gd, Y, Dy, Yb, Hf, and combinations thereof.
8. The ceramic article as recited in claim 7 , wherein the glaze material comprises a glass-ceramic from at least one of BaO x-MgO y-Al 2 O 3 z-nSiO 2 -System (BMAS-System), SrO x-Al 2 O 3 y-nSiO 2 -System (SAS-System), and REO-x-Al 2 O 3 -nSiO 2 -Systems, where REO are oxides of the rare earth metals.
9. The ceramic article as recited in claim 8 , wherein the glaze material includes at least one element from Ce, Hf, Gd, Yb, and combinations thereof.
10. The ceramic article as recited in claim 1 , wherein the glaze material includes at least one element from boron, barium, calcium, magnesium, strontium and combinations thereof and at least one element from lithium, sodium, potassium, aluminum, phosphorus, zinc, and combinations thereof.