Negative electrode active material for lithium secondary battery, method for manufacturing the same, and lithium secondary battery comprising the same
Provided is a negative electrode active material for a lithium secondary battery according to the present invention, including a carbon-based particle including pores in an inner portion and/or a surface thereof; and a silicon-based coating layer positioned on a pore surface and/or a pore-free surface of the carbon-based particle and containing silicon carbon compound.
1. A negative electrode active material for a lithium secondary battery, the negative electrode active material comprising:
a carbon-based particle which is a particle of a substance containing carbon element and includes pores in an inner portion and/or a surface thereof; and
a silicon-based coating layer which is a coating layer of substances at least one of which contains a silicon substance or silicon element, positioned on a pore surface and/or a pore-free surface of the carbon-based particle and containing a matrix of silicon carbon compound and Si nano-particles dispersed in the matrix,
wherein the silicon-based coating layer further includes Si nano-particles having an average particle diameter of 3 nm or more and 10 nm or less,
wherein when the negative electrode active material is left in air at 25° C. and 1 atm for 24 hours, a thickness of an oxide film (SiO x , 0<x<2) formed on the surface of the silicon-based coating layer is 1% or more and 40% or less of the total thickness of the silicon-based coating layer including the oxide film after exposure to air.
2. The negative electrode active material of claim 1 , wherein the silicon carbon compound satisfies SiC x (0<x≤2).
3. The negative electrode active material of claim 1 , further comprising a carbon coating layer positioned on the silicon-based coating layer.
4. The negative electrode active material of claim 1 , wherein a degree of crystallinity of silicon contained in the silicon-based coating layer is 5% or more and 40% or less, and wherein the degree of crystallinity is obtained by dividing a peak area of crystalline silicon by the sum of a peak area of amorphous silicon and a peak area of crystalline silicon in the Raman spectrum.
5. The negative electrode active material of claim 1 , wherein a weight ratio of carbon:silicon contained in the silicon-based coating layer is 1:5 to 15.
6. The negative electrode active material of claim 1 , wherein the carbon-based particle includes pores in the inner portion and the surface thereof.
7. The negative electrode active material of claim 1 , wherein the pores of the carbon-based particle have an average diameter of 30 nm or more and 900 nm or less.
8. The negative electrode active material of claim 7 , wherein the number of pores most adjacent to one pore positioned in the inner portion of the carbon-based particle is 5 to 6 based on a cross section of the carbon-based particle.
9. The negative electrode active material of claim 1 , wherein the carbon-based particle has a BET specific surface area of 50 m 2 /g or more and 100 m 2 /g or less.
10. The negative electrode active material of claim 1 , wherein the silicon-based coating layer has a thickness of 5 nm or more and 100 nm or less.
11. The negative electrode active material of claim 1 , wherein the silicon-based coating layer is formed by a chemical vapor deposition (CVD) method.
12. A lithium secondary battery comprising the negative electrode active material of claim 1 .