Organic compound and organic electroluminescent element comprising same

1. An organic electroluminescent element comprising, in the order,

an anode;

a hole injection layer;

a hole transport layer;

a light emitting layer;

an auxiliary electron transport layer;

an electron transport layer;

an electron injection layer; and

a cathode, wherein at least one of the auxiliary electron transport layer and the electron transport layer comprises the compound represented by the following Formula 1:

wherein,

R a and R b are the same or different from each other and are each independently a C 1 -C 40 alkyl group or a C 6 -C 60 aryl group,

R 1 to R 3 are the same or different from each other and are each independently selected from the group consisting of a hydrogen, a deuterium, a halogen, a cyano group, a nitro group, an amino group, a C 1 -C 40 alkyl group, a C 2 -C 40 alkenyl group, a C 2 -C 40 alkynyl group, a C 3 -C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 -C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 -C 40 alkyloxy group, a C 6 -C 60 aryloxy group, a C 1 -C 40 alkylsilyl group, a C 6 -C 60 arylsilyl group, a C 1 -C 40 alkylboron group, a C 6 -C 60 arylboron group, a C 1 -C 40 phosphine group, a C 1 -C 40 phosphine oxide group, and a C 6 -C 60 arylamine group, or adjacent ones of R 1 to R 3 are taken together to form a fused ring,

L is selected from the group consisting of a single bond, phenylene, biphenylene, and a heteroarylene group having 5 to 18 nuclear atoms,

Z 1 to Z 5 are the same or different from each other and are each independently N or C(R 4 ), and provided that Z 1 to Z 5 include one or two N, and when C(R 4 ) is present in a plural number, plural substituents are the same as or different from each other,

c and e are each an integer of 0 to 4,

d is an integer of 0 to 3,

m and n are each an integer of 1 to 3, and

R 4 is selected from the group consisting of a hydrogen, a deuterium, a halogen, a cyano group, a nitro group, an amino group, a C 1 -C 40 alkyl group, a C 2 -C 40 alkenyl group, a C 2 -C 40 alkynyl group, a C 3 -C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 -C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 -C 40 alkyloxy group, a C 6 -C 60 aryloxy group, a C 1 -C 40 alkylsilyl group, a C 6 -C 60 arylsilyl group, a C 1 -C 40 alkylboron group, a C 6 -C 60 arylboron group, a C 1 -C 40 phosphine group, a C 1 -C 40 phosphine oxide group, and a C 6 -C 60 arylamine group, or bonded to an adjacent substituent to form a fused ring,

with the proviso that the compound, in which n is 1, L is a single bond, c is 1, and R1 is a C6-C60 aryl group, is excluded,

wherein the alkyl and aryl groups of R a and R b and the alkyl, alkenyl, alkynyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, alkyloxy, aryloxy, alkylsilyl, arylsilyl, alkylboron, arylboron, phosphine, phosphine oxide, and arylamine groups of R 1 to R 4 ; and the arylene and heteroarylene groups of L are optionally each independently unsubstituted or substituted with at least one selected from the group consisting of a deuterium, a halogen, a cyano group, a nitro group, an amino group, a C 1 -C 40 alkyl group, a C 2 -C 40 alkenyl group, a C 2 -C 40 alkynyl group, a C 3 -C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 -C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 -C 40 alkyloxy group, a C 6 -C 60 aryloxy group, a C 1 -C 40 alkylsilyl group, a C 6 -C 60 arylsilyl group, a C 1 -C 40 alkylboron group, a C 6 -C 60 arylboron group, a C 1 -C 40 phosphine group, a C 1 -C 40 phosphine oxide group, and a C 6 -C 60 arylamine group, provided that when the substituent is present in a plural number, plural substituents are the same or different from each other.

2. The organic electroluminescent element of claim 1 , wherein the compound is selected from the group consisting of the compounds of the following Formula 2 to 4:

wherein,

R a , R b , R 1 to R 3 , Z 1 to Z 5 , c, d, and e are the same as defined in claim 1 .

3. The organic electroluminescent element of claim 1 , wherein the structure represented by

wherein * is a site where to bond with L, in Formula 1 is selected from the group consisting of the structures of the following C-1 to C-8, and C-10 to C-15:

wherein,

R 4 is the same as defined in claim 1 ,

R 5 is selected from the group consisting of a hydrogen, a deuterium, a halogen, a cyano group, a nitro group, a C 1 -C 40 alkyl group, a C 2 -C 40 alkenyl group, a C 2 -C 40 alkynyl group, a C 3 -C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 -C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 6 -C 60 aryloxy group, a C 1 -C 40 alkyloxy group, a C 6 -C 60 arylamine group, a C 1 -C 40 alkylsilyl group, a C 1 -C 40 alkylboron group, a C 6 -C 60 arylboron group, a C 6 -C 60 arylphosphine group, a C 6 -C 60 arylphosphine oxide group, and a C 6 -C 60 arylsilyl group, or combines with an adjacent substituent to form a fused ring,

p is an integer of 1 to 4, and

the alkyl, alkenyl, alkynyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, aryloxy, alkyloxy, arylamine, alkylsilyl, alkylboron, arylboron, arylphosphine, arylphosphine oxide and arylsilyl groups of R 5 are optionally each independently unsubstituted or substituted with at least one selected from the group consisting of a deuterium, a halogen, a cyano group, a nitro group, a C 1 -C 40 alkyl group, a C 2 -C 40 alkenyl group, a C 2 -C 40 alkynyl group, a C 6 -C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 6 -C 60 aryloxy group, a C 1 -C 40 alkyloxy group, a C 6 -C 60 arylamine group, a C 3 -C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 1 -C 40 alkylsilyl group, a C 1 -C 40 alkylboron group, a C 6 -C 60 arylboron group, a C 6 -C 60 arylphosphine group, a C 6 -C 60 , arylphosphine oxide group and a C 6 -C 60 arylsilyl group, and provided that when the substituent is present in a plural number, plural substituents are the same or different from each other.

4. The organic electroluminescent element of claim 1 , wherein R a and R b are each independently a methyl or a phenyl.

5. The organic electroluminescent element of claim 1 , wherein L is selected from the group consisting of the structures of the following L-1 to L-7:

wherein * is a site where to bond.

6. The organic electroluminescent element of claim 2 , wherein the compound of Formula 2 is selected from the group consisting of the following Compounds 5 to 20, 73 to 88, 253 to 260, 285 to 291, 294 to 299:

7. The organic electroluminescent element of claim 2 , wherein the compound of Formula 3 is selected from the group consisting of the following Compounds 29 to 60, 66, 68, 97 to 128, 205, 206, 208, 209, 211 to 216, 261, 262, 264, 265, 267, 268, 270, 271, 273, 274, 276, 277, 279 to 283, 303 to 308, 312 to 317, 321 to 326, 330 to 331, 354 to 366:

8. The organic electroluminescent element of claim 2 , wherein the compound represented by Formula 4 is selected from the group consisting of the following Compounds 63, 64, 333, 334, 336, 337, 339 to 340, 342 to 343, 345 to 346, 348 to 349, 351 to 353: