Processes for producing trifluoroiodomethane using metal trifluoroacetates
The present disclosure provides a process for producing trifluoroiodomethane. The process includes providing a metal trifluoroacetate, iodine monochloride, and a solvent, and reacting the metal trifluoroacetate and iodine monochloride in the presence of the solvent to produce trifluoroiodomethane.
1. A process for producing trifluoroiodomethane (CF 3 I), the process comprising:
providing a metal trifluoroacetate, iodine monochloride, and a solvent; and
reacting the metal trifluoroacetate and iodine monochloride in the presence of the solvent to produce trifluoroiodomethane.
2. The process of claim 1 , wherein in the providing step, a mole ratio of the metal trifluoroacetate to the iodine monochloride is from about 0.1:1 to about 2.0:1.
3. The process of claim 1 , wherein in the providing step, the metal trifluoroacetate is at least one selected from the group of lithium trifluoroacetate, potassium trifluoroacetate, sodium trifluoroacetate, rubidium trifluoroacetate, cesium trifluoroacetate, calcium trifluoroacetate, magnesium trifluoroacetate, iron trifluoroacetate, zinc trifluoroacetate, and copper trifluoroacetate.
4. The process of claim 1 , wherein in the providing step, the solvent comprises less than about 500 ppm by volume of water.
5. The process of claim 1 , wherein in the providing step, the solvent is at least one selected from the group of an ionic liquid and a polar aprotic solvent.
6. The process of claim 5 , wherein the solvent is at least one selected from the group of imidazolium salts, caprolactamium hydrogen sulfate, sulfolane, N,N-dimethylacetamide, and dimethyl sulfone.
7. The process of claim 6 , wherein the solvent consists of sulfolane.
8. The process of claim 1 , wherein reacting the metal trifluoroacetate and iodine monochloride is further in the presence of a catalyst.
9. The process of claim 8 , wherein the catalyst includes at least one selected from the group of copper (I) iodide, ferrous chloride, and zinc (II) iodide.
10. The process of claim 1 , wherein in the reacting step, the metal trifluoroacetate, the iodine monochloride, and the solvent are at a temperature from about 100° C. to about 250° C.
11. A process for producing trifluoroiodomethane (CF 3 I), the process comprising:
mixing a metal trifluoroacetate, iodine monochloride, and a solvent; and
heating the metal trifluoroacetate, iodine monochloride, and the solvent to react the metal trifluoroacetate and iodine monochloride to produce trifluoroiodomethane and a metal chloride.
12. The process of claim 11 , further including separating the trifluoroiodomethane from the metal chloride.
13. The process of claim 11 , wherein the process is a continuous process.
14. The process of claim 11 , wherein the process is a batch process.
15. The process of claim 11 , wherein the metal trifluoroacetate is at least one selected from the group of lithium trifluoroacetate, potassium trifluoroacetate, sodium trifluoroacetate, rubidium trifluoroacetate, cesium trifluoroacetate, calcium trifluoroacetate, magnesium trifluoroacetate, iron trifluoroacetate, zinc trifluoroacetate, and copper trifluoroacetate.
16. The process of claim 11 , wherein the solvent is at least one selected from the group of an ionic liquid and a polar aprotic solvent.
17. The process of claim 16 , wherein the solvent is at least one selected from the group of imidazolium salts, caprolactamium hydrogen sulfate, sulfolane, N,N-dimethylacetamide, and dimethyl sulfone.
18. The process of claim 11 , wherein the metal trifluoroacetate and iodine monochloride react in the presence of a catalyst.
19. The process of claim 18 , wherein the catalyst includes at least one selected from the group of copper (I) iodide, ferrous chloride, and zinc (II) iodide.
20. The process of claim 11 , wherein the metal trifluoroacetate, the iodine monochloride, and the solvent are heated to a temperature from about 100° C. to about 250° C.