Processes for producing trifluoroiodomethane using metal trifluoroacetates
The present disclosure provides a process for producing trifluoroiodomethane. The process includes providing a metal trifluoroacetate, an iodine source, a metal catalyst, and a solvent, and reacting the metal trifluoroacetate and the iodine source in the presence of the metal catalyst and the solvent to produce trifluoroiodomethane. The metal catalyst includes at least one selected from the group of ferrous chloride and zinc (II) iodide.
1. A process for producing trifluoroiodomethane (CF 3 I), the process comprising:
providing a metal trifluoroacetate, an iodine source, a metal catalyst and a solvent; and
reacting the metal trifluoroacetate, the iodine source, and the metal catalyst in the presence of the solvent to produce trifluoroiodomethane, wherein the metal catalyst includes at least one selected from the group of ferrous chloride and zinc (II) iodide.
2. The process of claim 1 , wherein in the providing step, a mole ratio of the metal trifluoroacetate to the iodine source is from about 0.1:1 to about 2.0:1.
3. The process of claim 1 , wherein in the providing step, the catalyst may be provided for the reaction at a mole percent of the metal trifluoroacetate of from about 0.5% to about 50%.
4. The process of claim 1 , wherein in the providing step, the metal trifluoroacetate is selected from the group of lithium trifluoroacetate, potassium trifluoroacetate, sodium trifluoroacetate, calcium trifluoroacetate, magnesium trifluoroacetate, and combinations thereof.
5. The process of claim 1 , wherein in the providing step, the iodine source is selected from the group of iodine, iodine monochloride, iodine pentafluoride, and combinations thereof.
6. The process of claim 1 , wherein in the providing step, the solvent comprises less than about 500 ppm by volume of water.
7. The process of claim 1 , wherein in the providing step, the solvent is selected from the group of an ionic liquid, a polar aprotic solvent, and combinations thereof.
8. The process of claim 7 , wherein the solvent is selected from the group of imidazolium salts, caprolactamium hydrogen sulfate, sulfolane, N,N-dimethylacetamide, N-methyl-2-pyrrolidone (NMP), dimethyl sulfone, and combinations thereof.
9. The process of claim 8 , wherein the solvent consists of sulfolane.
10. The process of claim 1 , wherein the metal catalyst comprises ferrous chloride.
11. The process of claim 1 , wherein in the reacting step, the metal trifluoroacetate, the iodine source, and the solvent are at a temperature from about 100° C. to about 250° C.
12. A process for producing trifluoroiodomethane (CF 3 I), the process comprising:
mixing a metal trifluoroacetate, an iodine source, a metal catalyst, and a solvent; and
heating the metal trifluoroacetate, the iodine source, the metal catalyst, and the solvent to react the metal trifluoroacetate and iodine source to produce trifluoroiodomethane and a metal salt, wherein the metal catalyst includes at least one selected from the group of ferrous chloride and zinc (II) iodide.
13. The process of claim 12 , further including separating the trifluoroiodomethane from the metal salt.
14. The process of claim 12 , wherein the process is a continuous process.
15. The process of claim 12 , wherein the process is a batch process.
16. The process of claim 12 , wherein the metal trifluoroacetate is selected from the group of lithium trifluoroacetate, potassium trifluoroacetate, sodium trifluoroacetate, calcium trifluoroacetate, magnesium trifluoroacetate, and combinations thereof.
17. The process of claim 12 , wherein the solvent is selected from the group of an ionic liquid, a polar aprotic solvent, and combinations thereof.
18. The process of claim 17 , wherein the solvent is selected from the group of imidazolium salts, caprolactamium hydrogen sulfate, sulfolane, N,N-dimethylacetamide, N-methyl-2-pyrrolidone (NMP), dimethyl sulfone, and combinations thereof.
19. The process of claim 12 , wherein in the metal catalyst comprises ferrous chloride.
20. The process of claim 12 , wherein in the reacting step, the metal trifluoroacetate, the iodine source, and the solvent are at a temperature from about 100° C. to about 250° C.