Invisible-fingerprint coatings and process for forming same
A process for forming a coating on a substrate comprises forming a non-fluorinated alkyl silane hydrolysate polymer and applying the non-fluorinated alkyl silane hydrolysate polymer to a surface of the substrate. The formed invisible-fingerprint coating can have an initial oil angle less than 50°.
1. An article, comprising:
a substrate comprising a glass, a glass ceramic, wood, a metal, a metal oxide, or a polymer; and
an invisible-fingerprint coating deposited on the substrate, the invisible-fingerprint coating comprising an alkyl silane hydrolysate polymer having a weight average molecular weight of less than 100,000 Da;
wherein the alkyl silane hydrolysate polymer is formed from:
(i) an alkyl silane having a structure: (R A ) 3 SiR B
wherein:
each R A is independently —OC 1 -C 10 alkyl, —OC 6 -C 10 alkylaryl, —OC 2 -C 10 alkenyl, or —OC 3 -C 10 alkynyl; and
R B is C 6 -C 20 alkyl; and
(ii) a crosslinking silane selected from the group consisting of formulas (II)-(IV):
(II) (SiX n )—Y 2 —(SiX n ),
(III) (SiX n )—Y 3 —(SiX n )—(SiX n ), and
(IV) (SiX n )—(SiX n )—Y 4 —(SiX n )—(SiX n )
wherein:
Y 2 is a (C 2 -C 30 ) linear, branched or cyclo alkyl, aryl alkyl, alkyl aryl and each silicon in the formula (II) is bonded to the same or different carbon atom in Y 2 ;
Y 3 is a (C 2 -C 30 ) linear, branched or cyclo alkyl, aryl alkyl, alkyl aryl and each silicon in the formula the formula (III) is bonded to the same or different carbon atom in Y 3 ;
Y 4 is a (C 2 -C 30 ) linear, branched or cyclo alkyl, aryl alkyl, alkyl aryl and each silicon in the formula (IV) is bonded to the same or different carbon atom Y 4 ;
each X is independently a (C 1 -C 6 )alkoxy; and
each n is 3; and
wherein the alkyl silane hydrolysate polymer comprises a halogen-substituted alkyl, with the proviso that the halogen of the halogen-substituted alkyl is chlorine, bromine, or iodine.
2. The article of claim 1 , wherein the invisible-fingerprint coating comprises a surface having an initial oil contact angle using diiodomethane of less than about 45°, an initial water contact angle of greater than about 70°, or both an initial oil contact angle using diiodomethane of less than about 45° and an initial water contact angle of greater than about 70°.
3. The article of claim 1 , wherein R B is substituted by halogen, —OH, —CN, —OR 1 , —CO 2 H, —NH 2 , NH(C 1 -C 6 alkyl), —N(C 1 -C 6 alkyl) 2 , —P(C 1 -C 6 alkyl) 2 , —P(O)(C 1 -C 6 alkyl) 2 , or —PO 3 H 2 , wherein R 1 is deuterium or —C 1 -C 10 alkyl-O—C 1 -C 10 alkyl.
4. The article of claim 1 , wherein the alkyl silane is selected from the group consisting of (chloroundecyl) (triethoxy) silane, (chloroundecyl) (trimethoxy) silane, (chlorohexyl) (triethoxy) silane, (chlorohexyl) (trimethoxy) silane, (chloroheptyl) (trimethoxy) silane, (chloroheptyl) (triethoxy) silane, (chlorooctyl) (trimethoxy) silane, (chlorooctyl) (triethoxy) silane, (chlorononyl) (trimethoxy) silane, and (chlorononyl) (triethoxy) silane.
5. The article of claim 1 , wherein the alkyl silane is 11-chloroundecyltriethoxysilane.
6. The article of claim 1 , wherein the crosslinking silane is a BIS silane of the formula (II) or a TRIS silane of the formula (III).
7. The article of claim 1 , wherein the invisible-fingerprint coating has a thickness in a range of about 0.1 nm to about 1000 nm.
8. The article of claim 1 , wherein the invisible-fingerprint coating has a coefficient of friction less than about 0.15.
9. The article of claim 1 , wherein the invisible-fingerprint coating is able to maintain a water contact angle of at least 50 degrees after 1500 cycles of eraser abrasion.
10. The article of claim 1 , non-fluorinated alkyl silane hydrolysate polymer has a weight average molecular weight of greater than or equal to 300 Da.
11. The article of claim 1 , wherein the substrate is glass.
12. The article of claim 5 , wherein the invisible-fingerprint coating is able to maintain a water contact angle of at least 50 degrees after 1500 cycles of eraser abrasion.
13. The article of claim 1 , wherein each hydrogen atom of R A is independently optionally replaced by deuterium, halogen, —OH, —CN, —OR 1 , —CO 2 H, —C(O) OR 1 , —C(O) NH 2 , —C(O)NH(C 1 -C 6 alkyl), —C(O) N(C 1 -C 6 alkyl) 2 , SC 1 -C 6 alkyl, S(O)C 1 -C 6 alkyl, —S(O) 2 C 1 -C 6 alkyl, —S(O)NH(C 1 -C 6 alkyl), —S(O) 2 NH(C 1 -C 6 alkyl), S(O)N(C 1 C 6 alkyl) 2 , —S(O) 2 N(C 1 -C 6 alkyl) 2 , —NH 2 , NH(C 1 -C 6 alkyl), —N(H)C 1 -C 6 alkyl-NH 2 , —N(H)C 1 -C 6 alkyl-Si(—OC 1 -C 6 alkyl) 3 , —N(R 1 )C 1 -C 6 alkyl-N(R 1 )C 1 -C 6 alkyl-Si(—OC 1 -C 6 alkyl) 3 -N(H)C 1 -C 6 alkyl-N(H)C 1 -C 6 alkyl-NH 2 , —P(C 1 -C 6 alkyl) 2 , —P(O)(C 1 -C 6 alkyl) 2 , —PO 3 H 2 , or —Si(—OC 1 -C 6 alkyl) 3 ; and
each R 1 is independently deuterium, C 1 -C 10 alkyl, C 1 -C 10 alkylaryl, C 2 -C 10 alkenyl, C 2 -C 10 alkynyl, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkylaryl, C 1 -C 10 alkyl-O—C 1 -C 10 alkyl, or C 1 -C 10 alkylaryl-O—C 1 -C 10 alkylaryl; wherein each C 1 -C 10 alkyl or C 1 -C 10 alkylaryl is optionally substituted with hydroxyl.
14. An article, comprising:
a substrate comprising a glass, a glass ceramic, wood, a metal, a metal oxide, or a polymer; and
an invisible-fingerprint coating deposited on the substrate, the invisible-fingerprint coating comprising an alkyl silane hydrolysate polymer having a weight average molecular weight of less than 100,000 Da;
wherein the alkyl silane hydrolysate polymer is formed from:
(i) an alkyl silane having a structure: (R A ) 3 SiR B
wherein:
each R A is independently —OC 1 -C 10 alkyl, —OC 6 -C 10 alkylaryl, —OC 2 -C 10 alkenyl, or —OC 3 -C 10 alkynyl; and
R B is C 6 -C 20 alkyl; and
(ii) a crosslinking silane; and
wherein the alkyl silane hydrolysate polymer comprises a halogen-substituted alkyl, with the proviso that the halogen of the halogen-substituted alkyl is chlorine, bromine, or iodine.