IP Library Granted Patent US 11,566,331
Granted Patent B2
US 11,566,331 · App. 16/812,946 · Granted Jan 31, 2023

Calcium-magnesium-alumino-silicate resistant thermal barrier coatings

Inventor: Masamichi Hongoh (Manchester, CT)
Assignee: RAYTHEON TECHNOLOGIES CORPORATION
C23C24/10C23C4/02C23C4/11C23C4/134C23C14/024C23C14/083C23C14/30C23C28/042F05D2220/32F05D2230/312F05D2230/313F05D2300/211F05D2300/2118F05D2300/502
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Quick Facts
Patent No.
US 11,566,331
App. No.
16/812,946
Granted
Jan 31, 2023
Kind
B2
Abstract

A method for forming a coating system on a component includes depositing a reactive layer with predetermined CMAS reaction kinetics on at least a portion of a thermal barrier coating. The method also includes activating the reactive layer with a scanning laser. A component, such as a gas turbine engine component, includes a substrate, a thermal barrier coating and a reactive layer. The thermal barrier coating is deposited on at least a portion of the substrate. The reactive layer is deposited on at least a portion of the thermal barrier coating. The reactive layer has predetermined CMAS reaction kinetics activated by laser scanning.

Claims (13)

1. A component subjected to elevated temperature during operation comprising:

a substrate;

a thermal barrier coating deposited on at least a portion of the substrate; and

a reactive layer deposited on at least a portion of the thermal barrier coating, the reactive layer having predetermined CMAS reaction kinetics activated by laser scanning.

2. A component as recited in claim 1 , wherein the reactive layer includes a CMAS powder mixture, wherein the powder mixture includes chemically conditioned CMAS and Y 2 Zr 2 O 7 .

3. A component as recited in claim 1 , wherein at least a portion of the reactive layer and a portion of the thermal barrier coating are fused when the reactive layer is activated by laser scanning.

4. A component as recited in claim 1 , further comprising a bond coat between the substrate and the thermal barrier coating.

5. A component as recited in claim 1 , wherein the thermal barrier coating includes a stabilized zirconia.

6. A component as recited in claim 1 , wherein the thermal barrier coating includes a stabilized zirconia having at least one crystallization promoting material selected from the group consisting of La 2 Zr 2 O 7 , GD 2 Zr 2 O 7 , Al 2 O 3 , TiO 2 , Y 2 Zr 2 O 7 , and mixtures thereof.

7. A component as recited in claim 1 , wherein the reactive layer includes at least one of Y 2 Zr 2 O 7 , GD 2 Zr 2 O 7 and TiO 2 .

8. A component as recited in claim 1 , wherein the component is a gas turbine engine component.

9. A component as recited in claim 1 , wherein the melt temperature of the reactive layer is at least 50 degrees Fahrenheit (10 degrees Celsius) higher than the melt temperature of environmental CMAS.

10. A component as recited in claim 1 , wherein the reactive layer has graded characteristics from an interface with the thermal barrier coating to an external surface of the reactive layer.

Assignments (4)
CHANGE OF NAME Recorded Jul 27, 2023
From: RAYTHEON TECHNOLOGIES CORPORATION
To: RTX CORPORATION
Reel/Frame 064714/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE AND REMOVE PATENT APPLICATION NUMBER 11886281 AND ADD PATENT APPLICATION NUMBER 14846874. TO CORRECT THE RECEIVING PARTY ADDRESS PREVIOUSLY RECORDED AT REEL: 054062 FRAME: 0001. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF ADDRESS. Recorded Mar 4, 2021
From: UNITED TECHNOLOGIES CORPORATION
To: RAYTHEON TECHNOLOGIES CORPORATION
Reel/Frame 055659/0001 →
CHANGE OF NAME Recorded Sep 4, 2020
From: UNITED TECHNOLOGIES CORPORATION
To: RAYTHEON TECHNOLOGIES CORPORATION
Reel/Frame 054062/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 9, 2020
From: HONGOH, MASAMICHI
To: UNITED TECHNOLOGIES CORPORATION
Reel/Frame 052055/0219 →
Continuity (3)
Division 15034059
Provisional Application 61899535 · Nov 4, 2013
Related Publication 20200208272A1 · Jul 2, 2020