Low-friction fluorinated coatings
Low-friction fluorinated coatings are disclosed herein. A preferred low-friction material contains a low-surface-energy fluoropolymer having a surface energy between about 5 mJ/m 2 to about 50 mJ/m 2 , and a hygroscopic material that is covalently connected to the fluoropolymer in a triblock copolymer, such as PEG-PFPE-PEG. The material forms a lubricating surface layer in the presence of humidity. An exemplary copolymer comprises fluoropolymers with average molecular weight from 500 g/mol to 20,000 g/mol, wherein the fluoropolymers are (α,ω)-hydroxyl-terminated and/or (α,ω)-amine-terminated, and wherein the fluoropolymers are present in the triblock structure T-(CH 2 —CH 2 —O)—CH 2 —CF 2 —O—(CF 2 —CF 2 —O) m (CF 2 —O) n —CF 2 —CH 2 —(O—CH 2 —CH 2 ) p -T where T is a hydroxyl or amine terminal group, p=1 to 50, m=1 to 100, and n=1 to 100. The copolymer also contains isocyanate species and polyol or polyamine chain extenders or crosslinkers possessing a functionality of preferably 3 or greater. These durable, solvent-resistant, and transparent coatings reduce insect debris following impact.
1. A copolymer composition comprising:
(a) fluoropolymers having an average molecular weight from about 500 g/mol to about 20,000 g/mol, wherein said fluoropolymers are (a,ω)-hydroxyl-terminated and/or (a,ω)-amine-terminated, and wherein said fluoropolymers are present in the triblock structure:
wherein:
X, Y=CH 2 -(O-CH 2 -CH 2 ) p -T, and X and Y are independently selected;
p=4 to 50;
T is a hydroxyl or amine terminal group;
m=1 to 100; and
n=1 to 100;
(b) one or more isocyanate species possessing an average isocyanate functionality of about 2 or greater, or a reacted form thereof; and
(c) one or more polyol or polyamine chain extenders or crosslinkers possessing an average functionality of about 3 or greater, or a reacted form thereof.
2. The copolymer composition of claim 1 , wherein said fluoropolymers have an average molecular weight from about 1,000 g/mol to about 10,000 g/mol.
3. The copolymer composition of claim 1 , wherein X and Y are the same.
4. The copolymer composition of claim 1 , wherein X and Y are different.
5. The copolymer composition of claim 1 , wherein p is selected from 6 to 50 for each of X and Y.
6. The copolymer composition of claim 5 , wherein p is selected from 10 to 20 for each of X and Y.
7. The copolymer composition of claim 1 , wherein said isocyanate species are selected from the group consisting of 4,4′-methylenebis(cyclohexyl isocyanate), hexamethylene diisocyanate, cycloalkyl-based diisocyanates, tolylene-2,4-diisocyanate, 4,4′-methylenebis(phenyl isocyanate), isophorone diisocyanate, and combinations or derivatives thereof.
8. The copolymer composition of claim 1 , wherein said polyol or polyamine chain extenders or crosslinkers are selected from the group consisting of glycerol, trimethylolpropane, 1,2,6-hexanetriol, triethanolamine, pentaerythritol, N,N,N′,N′-tetrakis(2-hydroxypropyl) ethylenediamine, and homologues, derivatives, or combinations thereof.
9. The copolymer composition of claim 1 , wherein said composition contains, in a hard segment, said reacted form of said one or more isocyanate species, combined with said reacted form of said one or more polyol or polyamine chain extenders or crosslinkers.
10. The copolymer composition of claim 1 , wherein said copolymer composition is present in a coating.
11. The copolymer composition of claim 10 , wherein said coating is characterized by a coefficient of friction less than 0.5.
12. The copolymer composition of claim 10 , wherein said coating is optically transparent.
13. A fluoropolymer having an average molecular weight from about 500 g/mol to about 20,000 g/mol, wherein said fluoropolymer is present in the triblock structure:
wherein:
X=CH 2 -(O-CH 2 -CH 2 ) p1 -T;
Y=CH 2 -(O-CH 2 -CH 2 ) p2 -T;
X and Y are independently selected and p1 and p2 are independently selected;
either {pl=6 to 50 and p2=0 to 50}, or {p1=0 to 50 and p2=6 to 50};
T is a hydroxyl or amine terminal group;
m=1 to 100; and
n=1 to 100.
14. A copolymer composition comprising:
(a) fluoropolymers having an average molecular weight from about 500 g/mol to about 20,000 g/mol, wherein said fluoropolymers are (a,ω)-hydroxyl-terminated and/or (a,ω)-amine-terminated, and wherein said fluoropolymers are present in the triblock structure:
wherein:
X, Y=CH 2 -(O-CH 2 -CH 2 ) p -T, and X and Y are independently selected;
p=6 to 50;
T is a hydroxyl or amine terminal group;
m=1 to 100; and
n=1 to 100;
(b) one or more isocyanate species possessing an average isocyanate functionality of about 2 or greater, or a reacted form thereof; and
(c) one or more polyol or polyamine chain extenders or crosslinkers possessing an average functionality of about 3 or greater, or a reacted form thereof.
15. The copolymer composition of claim 14 , wherein said fluoropolymers have an average molecular weight from about 1,000 g/mol to about 10,000 g/mol.
16. The copolymer composition of claim 14 , wherein said isocyanate species are selected from the group consisting of 4,4′-methylenebis(cyclohexyl isocyanate), hexamethylene diisocyanate, cycloalkyl-based diisocyanates, tolylene-2,4-diisocyanate, 4,4′-methylenebis(phenyl isocyanate), isophorone diisocyanate, and combinations or derivatives thereof.
17. The copolymer composition of claim 14 , wherein said polyol or polyamine chain extenders or crosslinkers are selected from the group consisting of glycerol, trimethylolpropane, 1,2,6-hexanetriol, triethanolamine, pentaerythritol, N,N,N′,N′-tetrakis(2-hydroxypropyl) ethylenediamine, and homologues, derivatives, or combinations thereof.
18. The copolymer composition of claim 14 , wherein said composition contains, in a hard segment, said reacted form of said one or more isocyanate species, combined with said reacted form of said one or more polyol or polyamine chain extenders or crosslinkers.
19. The copolymer composition of claim 14 , wherein said copolymer composition is present in a coating.
20. The copolymer composition of claim 19 , wherein said coating is characterized by a coefficient of friction less than 0.5.