PERSONAL CARE AEROSOL COMPOSITIONS, METHODS AND DEVICES
Disclosed are personal care formulations for delivery to the skin of a person in the form of an aerosol comprising: (1) non-propellant components comprising at least one active ingredient in the form of finely divided particles, at least one hydrophobized clay, a hydrophobic carrier comprising trans-1-chloro-3,3,3-trifluoropropene (trans-1233zd) and at least one co-carrier wherein: (i) the weight ratio of said trans-1233zd:co-carrier is from about 0.25:1 to about 4:1; (ii) said trans-1233zd and said co-carrier together comprise at least about 40% by weight of said hydrophobic carrier.
1 . A personal care formulation for delivery to the skin of a person in the form of an aerosol comprising:
(1) non-propellant components comprising:
(a) from about 0.5% to about 80% by weight of at least one active ingredient in the form of finely divided particles;
(b) from about 0.5% to about 15% by weight of at least one hydrophobized clay;
(c) from about 10% to about 85% by weight of a hydrophobic carrier comprising trans-1-chloro-3,3,3-trifluoropropene (trans-1233zd) and at least one co-carrier wherein: (i) the weight ratio of said trans-1233zd:co-carrier is from about 0.25:1 to about 4:1; (ii) said trans-1233zd and said co-carrier together comprise at least about 40% by weight of said hydrophobic carrier; and
(d) optionally one or more non-propellant adjuvants, wherein said percentages for components (a)-(d) are based on the total weight of components (a)-(d) in the formulation; and
(2) propellant for imparting motive force to said non-propellant components (a)-(d), wherein said propellant can be interfaced with and/or separated from said components (a)-(d).
2 . The formulation of claim 1 wherein said at least one co-carrier comprises one or more of: (i) triglycerides of linear or branched, saturated or unsaturated, C8-30 fatty acids; (ii) esters of at least one C 2 -C 9 monocarboxylic, dicarboxylic or tricarboxylic acid and at least one linear or branched, saturated or unsaturated alcohol having 1 to 30 carbon atoms; (iii) C 10 -C 20 iso paraffin; (iv) volatile silicone fluids other than D-4 and D-5, and combinations of two or more of these.
3 . The formulation of claim 1 wherein said at least one active ingredient from about 1% to about 60% by weight of the formulation.
4 . The formulation of claim 1 wherein said co-carrier is of a type and present in an amount to provide said formulation with a dry silky feel when sprayed in the form of an aerosol onto the skin of the person.
5 . The formulation of claim 1 wherein said at least one co-carrier comprises at least about 20% by weight of all the carrier components and consists essentially of one or more triglycerides of linear or branched, saturated or unsaturated, C 8-30 fatty acids and combinations of two or more of these.
6 . The formulation of claim 5 wherein said hydrophobic carrier comprises at least about 20% by weight of all the carrier components of trans-1-chloro-3,3,3-trifluoropropene (trans-1233zd).
7 . The formulation of claim 1 wherein said at least one co-carrier consists essentially of one or more triglycerides that are natural oils.
8 . The formulation of claim 1 wherein said at least one co-carrier is selected from the group consisting of soy bean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, olive oil, rapeseed oil, sesame oil, safflower oil, wheat germ oil, peach kernel oil, the liquid components of coconut oil and the combination of two or more of these.
8 . The formulation of claim 1 wherein said at least one co-carrier comprises safflower oil.
9 . The formulation of claim 1 wherein said at least one co-carrier comprises safflower oil present in an amount of at least about 20% by weight based on all the carrier components.
10 . The formulation of claim 1 in the form of an antiperspirant formulation for delivery to the skin of a person in the form of an aerosol and wherein said active ingredient comprises perspiration-inhibiting antiperspirant active ingredient.
11 . A drop-in replacement fluid for silicone fluids in personal care compositions, said replacement fluid comprising:
(a) trans-1-chloro-3,3,3-trifluoropropene (trans-1233zd) and
(b) at least one co-carrier wherein: (i) the weight ratio of said trans-1233zd:co-carrier is from about 0.25:1 to about 4:1; and (ii) said trans-1233zd and said co-carrier together comprise at least about 90% by weight of said replacement fluid.
12 . The drop-in replacement fluid of claim 11 wherein said co-carrier is of a type and present in an amount to provide said personal care composition with a dry silky feel when sprayed in the form of an aerosol onto the skin of the person.
13 . The drop-in replacement fluid of claim 11 wherein said at least one co-carrier comprises one or more of: (i) triglycerides of linear or branched, saturated or unsaturated, C 8-30 fatty acids; (ii) esters of at least one C 2 -C 9 monocarboxylic, dicarboxylic or tricarboxylic acid and at least one linear or branched, saturated or unsaturated alcohol having 1 to 30 carbon atoms; (iii) C 10 -C 20 iso paraffin; (iv) volatile silicone fluids other than D-4 and D-5, and combinations of two or more of these.
14 . The drop-in replacement fluid of claim 11 wherein said co-carrier is of a type and present in an amount to provide said formulation with a dry silky feel when sprayed in the form of an aerosol onto the skin of the person.
15 . The drop-in replacement fluid of claim 11 wherein said at least one co-carrier: (i) comprises at least about 20% by weight of all the carrier components; and (2) consists essentially of one or more triglycerides of linear or branched, saturated or unsaturated, C 8-30 fatty acids and combinations of two or more of these.
16 . The drop-in replacement fluid of claim 15 wherein said replacement fluid comprises at least about 20% by weight of trans-1-chloro-3,3,3-trifluoropropene (trans-1233zd).
17 . The drop-in replacement fluid of claim 11 wherein said at least one co-carrier consists essentially of one or more triglycerides that are natural oils.
18 . The drop-in replacement fluid of claim 11 wherein said at least one co-carrier is selected from the group consisting of soy bean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, olive oil, rapeseed oil, sesame oil, safflower oil, wheat germ oil, peach kernel oil, the liquid components of coconut oil and the combination of two or more of these.
19 . The drop-in replacement fluid of claim 11 wherein said at least one co-carrier comprises safflower oil.
20 . The drop-in replacement fluid of claim 11 wherein said at least one co-carrier is present in an amount of at least about 20% by weight based on all the carrier components.