High-yield pitch synthesis process for producing carbon fiber
View Patent ↗Systems and methods of processing coal to form mesophase pitch include performing a low-severity direct coal liquefaction (LSDCL) process on a coal feedstock to produce a coal tar pitch therefrom. The systems and methods can include contacting coal directly with a catalyst in the presence of a solvent, pressurizing the coal in direct contact with the catalyst in the presence of the solvent to a predetermined pressure of about 1000 psia or less, heating the coal in direct contact with the catalyst in the presence of the solvent to a predetermined temperature of about 380° C. or less, and liquefying the coal to form a coal tar pitch. The coal tar pitch can be thermally treated to a liquid crystal phase exhibiting anisotropic spheres of mesophase and spun to form carbon fibers.
1. A method of processing coal, comprising:
analyzing an amount of coal with an auto-clave apparatus to assess the reactivity of the amount of coal;
removing the amount of coal from the auto-clave apparatus and washing the auto-clave apparatus to form a filter cake of ash and insoluble organic matter from a filter wash material;
contacting the amount of coal directly with a catalyst in the presence of a solvent and hydrogen gas added to the coal, wherein the hydrogen gas is provided by gasifying coal, biomass, or a liquefaction residue;
exerting a predetermined pressure between about 500 pounds per square inch absolute (psia) and about 1000 pounds per square inch absolute (psia) on the amount of coal and the solvent, the hydrogen gas added to exert the predetermined pressure and break down the amount of coal into soluble products;
heating the amount of coal and the solvent to a predetermined temperature of about 380° C. or less; and
liquefying at least some of the amount of coal to form a coal tar pitch.
2. The method of claim 1 , wherein the predetermined pressure is one of about 900, about 800, about 700, about 600, or about 500 psia.
3. The method of claim 2 , wherein the predetermined temperature is about 375° C. or less.
4. The method of claim 2 , wherein the predetermined temperature is about 365° C. or less.
5. The method of claim 2 , wherein the predetermined temperature is about 355° C. or less.
6. The method of claim 1 , further comprising thermally treating the coal tar pitch to a liquid crystal phase exhibiting anisotropic spheres of a mesophase pitch.
7. The method of claim 6 , further comprising spinning the mesophase pitch to form carbon fibers.
8. The method of claim 6 , wherein a carbon fiber yield of the method is about 200 kg or more per ton of the amount of coal contacted directly with the catalyst in the presence of the solvent.
9. The method of claim 6 , wherein a carbon fiber yield of the method is about 300 kg or more per ton of the amount of coal contacted directly with the catalyst in the presence of the solvent.