IP Library Granted Patent US 11,326,091
Granted Patent B2
US 11,326,091 · App. 16/830,530 · Granted May 10, 2022

Water-based friction reducing additives

Inventors: Leiming Li (Sugar Land, TX); Liang Xu (The Woodlands, TX); James William Ogle (Pittsburgh, PA)
Assignee: Halliburton Energy Services, Inc.
C09K8/68E21B43/26C09K2208/28
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Quick Facts
Patent No.
US 11,326,091
App. No.
16/830,530
Granted
May 10, 2022
Kind
B2
Abstract

Methods and compositions for treating aqueous fluids that may be included in treatment fluids that are used for treating a subterranean formation. In some embodiments, the methods include: providing a water-based friction reducing additive that includes an aqueous base fluid, a salt, a first friction reducing polymer, and a suspension agent; introducing the water-based friction reducing additive into a treatment fluid; and introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation at a pressure sufficient to create or enhance one or more fractures within the subterranean formation.

Claims (34)

1. A method comprising:

forming a water-based friction reducing additive that comprises:

an aqueous base fluid,

a salt,

a first friction reducing polymer in an amount from about 10 wt % to about 70 wt % by weight of the additive, and

a suspension agent comprising: a clay in an amount from about 0.1 wt % to about 30 wt % by weight of the additive or a second friction reducing polymer in an amount from about 0.01 wt % to 10 wt % by weight of the additive, wherein the second friction reducing polymer is selected from the group consisting of: polyacrylate, a polyacrylate derivative, a polyacrylate copolymer, a polymethacrylate, a polymethacrylate derivative, a polymethacrylate copolymer, a polyacrylamide, polyacrylamide derivative, a polyacrylamide copolymer, a acrylamide copolymer, guar, a guar derivative, a polysaccharide copolymer, a synthetic polymer, a superabsorbent polymer, and any combination thereof,

wherein the water-based friction reducing additive does not comprise a surfactant;

adding the formed water-based friction reducing additive into a treatment fluid comprising a base fluid; and

introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation at a pressure sufficient to create or enhance one or more fractures within the subterranean formation.

2. The method of claim 1 , wherein the first friction reducing polymer comprises at least one polymer selected from the group consisting of an acrylamide copolymer, an anionic acrylamide copolymer, a cationic acrylamide copolymer, a nonionic acrylamide copolymer, an amphoteric acrylamide copolymer, a polyacrylamide, a polyacrylamide derivative, a polyacrylate, a polyacrylate derivative, a polymethacrylate, a polymethacrylate derivative, and any combination thereof.

3. The method of claim 1 , wherein the first friction reducing polymer comprises at least one monomer selected from the group consisting of a 2-acrylamido-2-methylpropane sulfonic acid, an acrylamido tertiary butyl sulfonic acid, an acrylic acid, a salt of any of the foregoing, and any combination thereof.

4. The method of claim 1 , wherein the first friction reducing polymer comprises at least one polymer selected from the group consisting of a nonionic polymer, an anionic polymer, a cationic polymer, an amphoteric polymer, and any combination thereof.

5. The method of claim 1 , wherein the formed water-based friction reducing additive is present in the treatment fluid in an amount from about 0.1 gpt to about 100 gpt by volume of the treatment fluid.

6. The method of claim 1 , wherein the salt comprises at least one salt selected from the group consisting of a carbonate salt, a sulfate salt, a phosphate salt, a magnesium salt, a bromide salt, a formate salt, an acetate salt, a chloride salt, a fluoride salt, a bicarbonate salt, a nitrate salt, a phosphate salt, and any combination thereof.

7. A composition comprising:

an aqueous base fluid;

a salt;

a first friction reducing polymer present in the composition in an amount from about 10 wt % to about 70 wt % by weight of the composition; and

a second friction reducing polymer in an amount from about 0.01 wt % to 10 wt % by weight of the additive, wherein the second friction reducing polymer is selected from the group consisting of: polyacrylate, a polyacrylate derivative, a polyacrylate copolymer, a polymethacrylate, a polymethacrylate derivative, a polymethacrylate copolymer, a polyacrylamide, polyacrylamide derivative, a polyacrylamide copolymer, a acrylamide copolymer, guar, a guar derivative, a polysaccharide copolymer, a synthetic polymer, a superabsorbent polymer, and any combination thereof,

wherein at least a portion of the first friction reducing polymer is suspended in the composition, and

wherein the composition does not comprise a surfactant.

8. The composition of claim 7 , wherein the first friction reducing polymer comprises at least one polymer selected from the group consisting of an acrylamide copolymer, an anionic acrylamide copolymer, a cationic acrylamide copolymer, a nonionic acrylamide copolymer, an amphoteric acrylamide copolymer, a polyacrylamide, a polyacrylamide derivative, a polyacrylate, a polyacrylate derivative, a polymethacrylate, a polymethacrylate derivative, and any combination thereof.

9. The composition of claim 7 , wherein the first friction reducing polymer comprises at least one monomer selected from the group consisting of a 2-acrylamido-2-methylpropane sulfonic acid, an acrylamido tertiary butyl sulfonic acid, an acrylic acid, a salt of any of the foregoing, and any combination thereof.

10. The composition of claim 7 , wherein the salt comprises at least one salt selected from the group consisting of a carbonate salt, a sulfate salt, a phosphate salt, a magnesium salt, a bromide salt, a formate salt, an acetate salt, a chloride salt, a fluoride salt, a bicarbonate salt, a nitrate salt, a phosphate salt, and any combination thereof.

11. A method comprising:

forming a water-based friction reducing additive that comprises:

an aqueous base fluid,

an ammonium sulfate salt,

a first friction reducing polymer in an amount from about 10 wt % to about 70 wt % by weight of the additive, and

a second friction reducing polymer in an amount from about 0.01 wt % to 10 wt % by weight of the additive, wherein the second friction reducing polymer is selected from the group consisting of: polyacrylate, a polyacrylate derivative, a polyacrylate copolymer, a polymethacrylate, a polymethacrylate derivative, a polymethacrylate copolymer, a polyacrylamide, polyacrylamide derivative, a polyacrylamide copolymer, a acrylamide copolymer, guar, a guar derivative, a polysaccharide copolymer, a synthetic polymer, a superabsorbent polymer, and any combination thereof, wherein at least a portion of the first friction reducing polymer is suspended in the formed water-based friction reducing additive, and wherein the water-based friction reducing additive does not comprise a surfactant;

adding the formed water-based friction reducing additive into a treatment fluid comprising a base fluid; and

introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation at a pressure sufficient to create or enhance one or more fractures within the subterranean formation.

12. The method of claim 11 , wherein both the first friction reducing polymer and the second friction reducing polymer comprise polyacrylamide and 2-acrylamido-2-methylpropane sulfonic acid.

13. The method of claim 11 , wherein the formed water-based friction reducing additive is present in the treatment fluid in an amount from about 0.1 gpt to about 100 gpt by volume of the treatment fluid.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2021
From: MULTI-CHEM GROUP, LLC
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 056681/0849 →
CORRECTIVE ASSIGNMENT TO CORRECT THE SECOND INVENTOR'S EXECUTION DATE PREVIOUSLY RECORDED AT REEL: 052890 FRAME: 0602. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Sep 2, 2020
From: LI, LEIMING; XU, LIANG; OGLE, JAMES WILLIAM
To: MULTI-CHEM GROUP, LLC
Reel/Frame 053670/0407 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 10, 2020
From: LI, LEIMING; XU, LIANG; OGLE, JAMES WILLIAM
To: MULTI-CHEM GROUP, LLC
Reel/Frame 052890/0602 →
Continuity (1)
Related Publication 20210301195A1 · Sep 30, 2021
Cited By (3)
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