Johnson thermo-electrochemical converter
A converter includes a working fluid, a housing, a heat sink, a heat source that is at an elevated temperature relative to the heat sink, a first electrochemical cell disposed within the housing, and a micro/nano porous media disposed within the housing. The first electrochemical cell includes a first membrane electrode assembly across which the working fluid is configured to flow. The first membrane electrode assembly includes a first porous electrode and a second porous electrode and at least one ion conductive membrane sandwiched between the first and second porous electrodes. The first electrochemical cell is arranged between the heat source and the heat sink. The working fluid is contained within the micro/nano porous media. The micro/nano porous media is thermally coupled between the heat source and the heat sink, and creates a pressure differential across the first electrochemical cell by transpiration pumping of the working fluid.
1. An electrochemical direct heat to electricity converter comprising:
a working fluid;
a housing;
a heat source and a heat sink, the heat source being at an elevated temperature above a temperature of the heat sink;
a first electrochemical cell disposed within the housing and comprising a first membrane electrode assembly across which the working fluid is configured to flow, the first membrane electrode assembly of the first electrochemical cell including a first porous electrode and a second porous electrode and at least one ion conductive membrane sandwiched between the first and second porous electrodes, the first electrochemical cell being arranged between the heat source and the heat sink; and
a micro/nano porous media disposed within the housing, the working fluid being contained within the micro/nano porous media, the micro/nano porous media being thermally coupled between the heat source and the heat sink and creating a pressure differential across the first electrochemical cell by transpiration pumping of the working fluid.
2. The electrochemical direct heat to electricity converter of claim 1 , wherein the working fluid is an ionizable gas.
3. The electrochemical direct heat to electricity converter of claim 2 , wherein at least a portion of the micro/nano porous media includes graduated pore structures, and wherein pores of the graduated pore structures are smaller in regions of high pressure where gas mean free paths are shorter and are larger in regions of low pressure where gas mean free paths are longer.
4. The electrochemical direct heat to electricity converter of claim 3 , wherein graduation in pore size is a continuous gradient.
5. The electrochemical direct heat to electricity converter of claim 2 , wherein the micro/nano porous media includes a first section arranged between the heat sink and the first membrane electrode assembly and a second section arranged between the first membrane electrode assembly and the heat source.
6. The electrochemical direct heat to electricity converter of claim 5 , wherein the first membrane electrode assembly is positioned closer to the heat source than the heat sink, such that the first electrochemical cell constitutes a high temperature side of the converter.
7. The electrochemical direct heat to electricity converter of claim 5 , wherein a pore size of a minimum temperature region of the first section of nano/micro porous media proximate the heat sink is smaller than a pore size of a maximum temperature region of the second section of the nano/micro porous media proximate the heat source.
8. The electrochemical direct heat to electricity converter of claim 1 , wherein the housing includes a return fluid conduit configured to allow working fluid under increased pressure due to transpiration pumping into a region proximate the heat source to flow into a region proximate the heat sink.
9. The electrochemical direct heat to electricity converter of claim 8 , further comprising one or more recuperative heat exchangers positioned within the housing and configured to transfer heat from working fluid flowing in the return fluid conduit to working fluid flowing through the nano/micro porous media.
10. The electrochemical direct heat to electricity converter of claim 1 , further comprising a second electrochemical cell disposed within the housing and comprising a second membrane electrode assembly across which the working fluid is configured to flow, the second membrane electrode assembly of the second electrochemical cell including a first porous electrode and a second porous electrode and at least one ion conductive membrane sandwiched between the first and second porous electrodes, the second electrochemical cell constituting a low temperature side of the converter and being arranged between the first electrochemical cell and the heat sink,
wherein the micro/nano porous media creates a pressure differential across the second electrochemical cell by transpiration pumping.