Post-treatment method of lithium secondary battery
Provided is a post-treatment method of a lithium secondary battery including: an activation step of charging a heated lithium secondary battery to an activation voltage and maintaining the battery at the voltage, in a state in which the lithium secondary battery including a positive electrode including a nickel-rich (Ni-rich) lithium-transition metal composite oxide having a layered structure containing 0.8 moles or more of Ni based on a total of 1 mole of transition metals as a positive electrode active material; a negative electrode; a separator interposed between the positive electrode and the negative electrode; and an electrolyte solution, which are built in a battery case, is heated, the activation voltage being equal to or higher than a voltage generating phase transition of the lithium-transition metal composite oxide.
1. A degassing method for a lithium secondary battery, the degassing method comprising:
an activation step of charging a heated lithium secondary battery to an activation voltage and maintaining the battery at the voltage, in a state in which the lithium secondary battery including a positive electrode including a nickel-rich (Ni-rich) lithium-transition metal composite oxide having a layered structure containing 0.8 moles or more of Ni based on a total of 1 mole of transition metals as a positive electrode active material; a negative electrode; a separator interposed between the positive electrode and the negative electrode; and an electrolyte solution, which are built in a battery case, is heated, the activation voltage being equal to or higher than a voltage generating phase transition of the lithium-transition metal composite oxide, and
degassing step of removing gas generated in the activation step,
wherein the activation voltage is 4.15 V to 4.30 V, and wherein a first activation voltage charge state and a second activation voltage charge state which are different from each other are alternated in the activation step.
2. The degassing method of a lithium secondary battery of claim 1 , wherein the charging of the lithium secondary battery to the activation voltage is performed at a C-rate of 0.2 C or less.
3. The degassing method of a lithium secondary battery of claim 1 , wherein a temperature of the heated lithium secondary battery is 45° C. to 60° C.
4. The degassing method of a lithium secondary battery of claim 1 , wherein the activation step is performed for 0.5 days to 1 day.
5. The degassing method of a lithium secondary battery of claim 1 , wherein the lithium-transition metal composite oxide satisfies the following Chemical Formula 1:
Li 1+α (Ni x M (1-x) )O 2 (Chemical Formula 1)
wherein M includes one or more selected from the group consisting of Mn, Co, Fe, Cr, V, Cu, Zn, and Ti, α is a real number of 0≤α≤0.50, and x is a real number of 0.80≤x≤0.95.