Adhesive film for polarizing plate, polarizing plate comprising the same, and optical display apparatus comprising the same
An adhesive film for polarizing plates, a polarizing plate including the same, and an optical display apparatus including the same are provided. An adhesive film for polarizing plates includes: a (meth)acrylic copolymer, a curing agent, a (meth)acrylic oligomer, and an antistatic agent, and has a modulus of about 0.5 MPa or more at about 25° C. and a surface resistance difference ΔSR of about 1.0 log (Ω/□) or less, as calculated by Equation 1 herein.
1. An adhesive film for polarizing plates, comprising a (meth)acrylic copolymer, a curing agent, a (meth)acrylic oligomer, and an antistatic agent, the adhesive film having:
a storage modulus of about 0.5 MPa to 1.0 MPa at about 25° C., as measured on a 0.8 mm thick specimen of the adhesive film, by temperature sweep testing (strain: 5%, normal force: 100 N) at 1 Hz while increasing the temperature from about 0° C. to 120 ° C. at a heating rate of about 10° C/min;
an initial peel strength of about 100 gf/25 mm to 300 gf/25 mm, and a peel strength of about 500 gf/25 mm to 800 gf/25 mm when left under conditions of about 85° C. and about 85% relative humidity for about 250 hours, wherein the term “peel strength” refers to 180° peel strength between the adhesive film for polarizing plates and a glass plate, as measured at 25° C. in accordance with JIS 2107;
each of an initial surface resistance and a surface resistance of the adhesive film left under conditions of about 85° C. and about 85% relative humidity for about 250 hours, of from 1×10 8 Ω/□ to 1×10 11 Ω/□; and
a surface resistance difference ΔSR of about 1.0 log (Ω/□) or less, as calculated by the following Equation 1:
ΔSR=SR2−SR1,
where SR1 is a log base 10 value (unit: log (Ω/□)) of the initial surface resistance of the adhesive film, and SR2 is a log base 10 value (unit: log(Ω/□)) of the surface resistance of the adhesive film left under conditions of about 85° C. and about 85% relative humidity for about 250 hours,
wherein relative to 100 parts by weight of the (meth)acrylic copolymer, the antistatic agent is 6 parts by weight to 10 parts by weight in amount.
2. The adhesive film for polarizing plates according to claim 1 , wherein the adhesive film has a modulus of about 0.05 MPa or less at about 85° C.
3. The adhesive film for polarizing plates according to claim 1 , wherein the adhesive film has a modulus difference (ΔG) of about 0.06 MPa or more, as calculated by the following Equation 2:
Δ G=G 1− G 2,
where G1 is the modulus at about 25° C. (unit: MPa) of the adhesive film, and G2 is a modulus at about 85° C. (unit: MPa) of the adhesive film.
4. The adhesive film for polarizing plates according to claim 1 , wherein the antistatic agent comprises a cationic antistatic agent, an anionic antistatic agent, an amphoteric antistatic agent, a non-ionic antistatic agent, or an ion conductive polymer obtained through polymerization or copolymerization of a monomer having an ion conductive group of the cationic antistatic agent, the anionic antistatic agent, or the amphoteric antistatic agent.
5. The adhesive film for polarizing plates according to claim 1 , wherein the antistatic agent comprises at least one selected from the group consisting of a surfactant, an ionic liquid, an alkali metal salt, a metal oxide, fine metal particles, a conductive polymer, carbon, and carbon nanotubes.
6. The adhesive film for polarizing plates according to claim 1 , wherein the antistatic agent comprises an ionic liquid.
7. The adhesive film for polarizing plates according to claim 1 , wherein the (meth)acrylic oligomer has a glass transition temperature of about 20° C. to about 60° C.
8. The adhesive film for polarizing plates according to claim 1 , wherein the (meth)acrylic oligomer has a weight average molecular weight of about 1,000 g/mol to 30,000 g/mol.
9. The adhesive film for polarizing plates according to claim 1 , wherein the (meth)acrylic oligomer comprises at least one oligomer selected from the group consisting of t-butyl methacrylate, methyl acrylate, and hydroxyethyl methacrylate.
10. The adhesive film for polarizing plates according to claim 1 , wherein the curing agent comprises a polyisocyanate curing agent comprising a plurality of units containing a urethane bond and an alkylene group having a carbon number of 2 or more.
11. The adhesive film for polarizing plates according to claim 10 , wherein the curing agent comprises a plurality of units represented by the following Formula 1:
*-R 1 —O—(C═O)NH—R 2 —NCO,
where * is a linking site, and R 1 and R 2 are identical to or different from each other and are a bivalent C 2 to C 20 aliphatic hydrocarbon group.
12. The adhesive film for polarizing plates according to claim 1 , wherein the (meth)acrylic copolymer comprises a copolymer of a monomer mixture comprising a C 1 to C 20 alkyl group-containing (meth)acrylic monomer and a hydroxyl group-containing (meth)acrylic monomer.
13. The adhesive film for polarizing plates according to claim 12 , wherein the monomer mixture further comprises an aromatic group-containing (meth)acrylic monomer.
14. The adhesive film for polarizing plates according to claim 1 , comprising:
about 100 parts by weight of the (meth)acrylic copolymer;
greater than 0 to 5 parts by weight or less of the curing agent;
about 1 part by weight to 30 parts by weight of the (meth)acrylic oligomer; and
6 parts by weight to 10 parts by weight of the antistatic agent.
15. A polarizing plate comprising:
a polarizer; and
the adhesive film for polarizing plates according to claim 1 stacked on a surface of the polarizer.
16. An optical display apparatus comprising the polarizing plate according to claim 15 .