Method of preparing electrode for secondary battery, and secondary battery including the electrode
A method of manufacturing an electrode for a secondary battery includes preparing an electrode current collector in which a plurality of through-holes are formed; applying a first slurry including an electrode active material, a binder, and a conductive material to at least one surface of the electrode current collector; and applying a second slurry including an electrode active material, a binder, and a conductive material on the first slurry. In manufacturing an electrode including an electrode current collector with a plurality of through-holes, processability may be secured by preventing leakage of a slurry, and thus, a uniform electrode mixture layer may be formed.
1. A method of manufacturing an electrode for a secondary battery, comprising:
preparing an electrode current collector in which a plurality of through-holes are formed;
applying a first slurry including a first electrode active material, a first binder, a first conductive material, and a first thickener to at least one surface of the electrode current collector; and
applying a second slurry including a second electrode active material, a second binder, and a second conductive material on the first slurry,
wherein viscosity of the first slurry is greater than viscosity of the second slurry,
wherein the first thickener included in the first slurry is included in an amount of 0.5 to 2% by weight, based on a total weight of the first slurry, and
wherein the first and second electrode active materials are the same or different, the first and second binders are the same or different, and the first and second conductive materials are the same or different.
2. The method of claim 1 , wherein the viscosity of the first slurry is 10000 cp to 15000 cp.
3. The method of claim 1 , wherein the viscosity of the second slurry is 5000 cp to 7000 cp.
4. The method of claim 1 , wherein a solid content weight of the first slurry is 51 to 55% by weight.
5. The method of claim 1 , wherein a solid content weight of the second slurry is 45 to 50% by weight.
6. The method of claim 1 , wherein the second slurry further comprises a second thickener in a weight less than a weight of the first thickener included in the first slurry,
wherein the first thickener is the same as or different from the second thickener.
7. The method of claim 1 , wherein the first thickener is at least one selected from carboxy methyl cellulose (CMC), methyl cellulose (MC), hydroxypropyl cellulose (HPC), methyl hydroxypropyl cellulose (MHPC), ethyl hydroxyethyl cellulose (EHEC), methyl ethyl hydroxyethyl cellulose (MEHEC) and cellulose gum.
8. The method of claim 6 , wherein the second thickener is at least one selected from carboxy methyl cellulose (CMC), methyl cellulose (MC), hydroxypropyl cellulose (HPC), methyl hydroxypropyl cellulose (MHPC), ethyl hydroxyethyl cellulose (EHEC), methyl ethyl hydroxyethyl cellulose (MEHEC) and cellulose gum.
9. A secondary battery comprising:
an electrode current collector in which a plurality of through-holes are formed;
a first electrode mixture layer provided by coating at least one surface of the electrode current collector with a first slurry including a first electrode active material, a first binder, a first conductive material, and a first thickener; and
a second electrode mixture layer provided by applying a second slurry including a second electrode active material, a second binder, and a second conductive material on the first electrode mixture layer,
wherein the first thickener included in the first slurry is included in an amount of 0.5 to 2% by weight, based on a total weight of the first slurry, and
wherein the first and second electrode active materials are the same or different, the first and second binders are the same or different, and the first and second conductive materials are the same or different.
10. The secondary battery of claim 9 , wherein the second slurry further comprises a second thickener in a weight less than a weight of the first thickener included in the first slurry,
wherein the first thickener is the same as or different from the second thickener.
11. The secondary battery of claim 9 , wherein the first thickener is at least one selected from carboxy methyl cellulose (CMC), methyl cellulose (MC), hydroxypropyl cellulose (HPC), methyl hydroxypropyl cellulose (MHPC), ethyl hydroxylethyl cellulose (EHEC), methyl ethyl hydroxyethyl cellulose (MEHEC) and cellulose gum.
12. The secondary battery of claim 10 , wherein the second thickener is at least one selected from carboxy methyl cellulose (CMC), methyl cellulose (MC), hydroxypropyl cellulose (HPC), methyl hydroxypropyl cellulose (MHPC), ethyl hydroxylethyl cellulose (EHEC), methyl ethyl hydroxyethyl cellulose (MEHEC) and cellulose gum.