IP Library Granted Patent US 11,441,067
Granted Patent B2
US 11,441,067 · App. 16/842,438 · Granted Sep 13, 2022

Screening method for friction reducer precipitation

Inventors: Leiming Li (Sugar Land, TX); Scot Harris Bodnar (Houston, TX); Liang Xu (The Woodlands, TX); James William Ogle (Livingston, TX); Todd Allen Collier (Oklahoma City, OK)
Assignee: Halliburton Energy Services, Inc.
C09K8/68C09K8/80C09K8/882C09K2208/28
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Quick Facts
Patent No.
US 11,441,067
App. No.
16/842,438
Granted
Sep 13, 2022
Kind
B2
Abstract

A method of preparing a fracturing fluid comprising: preparing or providing an aqueous fluid containing iron ions; screening a plurality of friction reducers against the aqueous fluid wherein the plurality of friction reducers are anionic, cationic, nonionic, amphoteric, or combinations thereof; selecting at least one friction reducer from the plurality of friction reducers based at least in part on the step of screening; and preparing a fracturing fluid including the at least one friction reducer.

Claims (26)

1. A method of preparing a fracturing fluid comprising:

preparing a laboratory treatment fluid based at least in part on a treatment fluid model;

screening a plurality of friction reducers against the laboratory treatment fluid, the screening comprising:

dissolving at least 2,000 ppm of Fe 2+ ions into water and adding about 2 gpt to about 5 gpt of a friction reducer;

storing the water for at least about a day and monitoring formation of precipitates of hydrated friction reducing polymers;

filtering the precipitates,

drying the precipitates, and

weighing the precipitates;

selecting at least one friction reducer from the plurality of friction reducers based at least in part on the step of screening and the presence of precipitate; and

preparing a fracturing fluid including the at least one friction reducer.

2. The method of claim 1 wherein the diluted treatment fluid model includes a concentration of dissolved species in a diluted formation fluid, wherein the dissolved species comprises at least iron.

3. The method of claim 2 wherein the step of preparing a laboratory treatment fluid comprises dissolving an iron containing compound in water or reacting an iron containing compound to release iron ions in water.

4. The method of claim 2 wherein the diluted treatment fluid model further includes a concentration of at least one ion selected from the group consisting of calcium ions, magnesium ions, sodium ions, barium ions, chloride ions, and combinations thereof.

5. The method of claim 4 wherein the step of preparing a laboratory treatment fluid comprises dissolving a compound containing at least one of iron ions, calcium ions, magnesium ions, sodium ions, barium ions, chloride ions, and combinations thereof, in water such that a concentration of ions in the laboratory treatment fluid in the range of 50% to about 500% of the diluted treatment fluid model.

6. The method of claim 1 wherein the diluted treatment fluid model is based at least in part on measurement of a volume of formation brine and concentration of dissolved species therein and a volume of treatment fluid and concentration of dissolved species therein.

7. The method of claim 1 wherein the plurality of friction reducers comprise at least one of a polyacrylamide, a polyacrylamide derivative, a synthetic polymer, an acrylamide copolymer, an anionic acrylamide copolymer, a cationic acrylamide copolymer, a nonionic acrylamide copolymer, an amphoteric acrylamide copolymer, a polyacrylate, a polyacrylate derivative, a polymethacrylate, a polymethacrylate derivative, polymers synthesized from one or more monomeric units selected from the group consisting of acrylamide, acrylic acid, 2-acrylamido-2-methylpropane sulfonic acid, acrylamido tertiary butyl sulfonic acid, N,N-dimethylacrylamide, vinyl sulfonic acid, N-vinyl acetamide, N-vinyl formamide, itaconic acid, methacrylic acid, acrylic acid esters, or methacrylic acid esters, their corresponding salts, their corresponding esters, or combinations thereof.

8. The method of claim 1 , wherein the fracturing fluid comprises water, the at least one friction reducer, and a proppant.

9. The method of claim 1 , further comprising introducing the fracturing fluid into a subterranean formation.

10. The method of claim 1 , wherein the friction reducers are in an acid form or a salt form.

11. The method of claim 3 , wherein the concentration of iron in the laboratory treatment fluid is in the range of about 50% to about 500% of the diluted treatment fluid model.

12. The method of claim 1 , wherein the diluted treatment fluid model is based at least in part on measurements made using open-hole, cased hole, and seismic logging techniques to determine a volume of formation brine and concentration of dissolved species therein and a volume of treatment fluid and concentration of dissolved species therein.

13. The method of claim 1 , further comprising subjecting the fracturing fluid to a wellbore pressure and a wellbore temperature to simulate a wellbore condition.

14. The method of claim 8 , wherein the water comprises at least one of fresh water, produced water, sea water, ground water, or surface water.

15. The method of claim 2 , wherein the iron containing compound is FeCl 2 .

16. The method of claim 5 , further comprising subjecting the fracturing fluid to a wellbore pressure and a wellbore temperature to simulate a wellbore condition.

17. The method of claim 8 wherein the proppant is present at a point ranging from about 0.1 pounds per gallon to about 14 pounds per gallon.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2021
From: MULTI-CHEM GROUP, LLC
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 056681/0849 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 22, 2020
From: LI, LEIMING; BODNAR, SCOT HARRIS; XU, LIANG; OGLE, JAMES WILLIAM; COLLIER, TODD ALLEN
To: MULTI-CHEM GROUP, LLC
Reel/Frame 052999/0001 →
Continuity (2)
Provisional Application 62902040 · Sep 18, 2019
Related Publication 20210079291A1 · Mar 18, 2021