Dual Function Inhibitor Compounds For Deepwater Umbilical Applications
A method is disclosed that includes introducing one or more dual function inhibitor compounds through an umbilical into a deepwater environment such that the one or more dual function inhibitor compounds are introduced into a fluid in the deepwater environment. The dual function inhibitor is a corrosion inhibitor and a hydrate inhibitor.
1 . A method comprising:
introducing one or more dual function inhibitor compounds through an umbilical into a deepwater environment such that the one or more dual function inhibitor compounds are introduced into a fluid in the deepwater environment, wherein the one or more dual function inhibitor compounds have the following structural formula:
wherein each dual function inhibitor compound is both a corrosion inhibitor and a hydrate inhibitor.
2 . The method of claim 1 , wherein each of R 1 , R 2 , and R 3 is each independently a C 1 to C 6 hydrocarbon chain, wherein the C 1 to C 6 hydrocarbon chain comprises one or more hydrocarbon groups selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, arylalkyl, arylalkenyl, alkylaryl, alkenylaryl, and combinations thereof; wherein R 4 and R 5 are each independently selected from the group consisting of a hydrocarbon and a C 1 to C 50 hydrocarbon chain; and wherein X − is a counter anion, and wherein each of a and b is independently an integer from 1 to 10.
3 . The method of claim 1 , wherein any one or more of R 2 , and R 3 is branched, unbranched, non-cyclic, cyclic, saturated, unsaturated, or combinations thereof.
4 . The method of claim 1 , wherein R 4 and R 5 are branched, unbranched, non-cyclic, cyclic, saturated, unsaturated, or combinations thereof.
5 . The method of claim 1 , wherein R 4 and R 5 are selected from the group consisting of alkyl, alkenyl, aryl, and combinations thereof.
6 . The method of claim 1 , wherein the one or more dual function inhibitor compounds comprise a linking moiety.
7 . The method of claim 6 , wherein the linking moiety comprises one or more hydrocarbon chains, wherein the hydrocarbon chains comprise C 1 to Cao chains or longer.
8 . The method of claim 7 , wherein the linking moiety is selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, and combinations thereof.
9 . The method of claim 1 , wherein the one or more dual function inhibitor compounds comprise a hydrophobic portion and a hydrophilic portion.
10 . The method of claim 1 further comprising contacting a metal surface with the fluid after introduction of the one or more dual function inhibitor compounds.
11 . The method of claim 10 further comprising suppressing corrosion of the metal surface by the fluid through inclusion of the one or more dual function inhibitor compounds in the fluid.
12 .- 19 . (canceled)
20 . A method comprising:
introducing one or more dual function inhibitor compounds into a fluid comprising a hydrocarbon and water such that the one or more dual function inhibitor compounds inhibits hydrate formation in the fluid, wherein the one or more dual function inhibitor compounds have the following structural formula:
contacting a metal surface with the fluid after introduction of the one or more dual function inhibitor compounds; and
suppressing corrosion of the metal surface by the fluid through inclusion of the one or more dual function inhibitor compounds in the fluid,
wherein each dual function inhibitor compound is both a corrosion inhibitor and a hydrate inhibitor.
21 . The method of claim 1 , wherein the dual function inhibitor compounds are introduced into the fluid in an amount from about 0.1% to about 10% by volume based on the volume of water in the fluid.
22 . The method of claim 20 , further comprising introducing the dual function inhibitor compound into a deepwater environment through an umbilical line.
23 . The method of claim 20 , further comprising introducing the dual function inhibitor compound into horizontal, vertical, deviated, or otherwise nonlinear wellbores in a subterranean formation.
24 . The method of claim 20 , wherein the one or more dual function inhibitor compounds comprise a hydrophobic portion and a hydrophilic portion.
25 . The method of claim 20 , wherein the compound further comprises a linking moiety selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, and combinations thereof.
26 . The method of claim 20 , wherein the dual function inhibitor compound is introduced into a composition prior to being introduced into the fluid, wherein the composition may comprise a solvent for the dual function inhibitor compound.
27 . The method of claim 26 , wherein the solvent is selected from the group consisting of methanol, isopropyl alcohol, glycol, ethylene glycol, any organic solvent, toluene, xylene, monobutyl ether, hexane, cyclohexane, and any combinations thereof.
28 . The method of claim 20 , wherein the dual function inhibitor compounds are introduced into the fluid in an amount from about 0.1% to about 10% by volume based on the volume of water in the fluid.