Multi-layered perovskites, devices, and methods of making the same
Methods are described that include contacting an alkyl ammonium metal halide film with an alkyl ammonium halide, where the alkyl ammonium metal halide film includes a first halogen and a metal, the alkyl ammonium halide includes a second halogen, such that the contacting forms an alkyl ammonium metal mixed-halide film that interfaces with the alkyl ammonium metal halide film, where the alkyl ammonium metal mixed-halide film includes the first halogen, the second halogen, and the metal.
1. A device comprising:
an alkyl ammonium metal halide film comprising lead and a first halogen; and
an alkyl ammonium metal mixed-halide film comprising the first halogen and a second halogen, wherein:
the alkyl ammonium metal mixed-halide film is adjacent to the alkyl ammonium metal halide film,
the alkyl ammonium metal mixed-halide film comprises grains having a characteristic length between 1 micron and 2 microns, inclusively,
the alkyl ammonium metal mixed-halide film has less than 0.25 pin-holes/μm 2 ,
the alkyl ammonium metal halide film has a thickness between 1 nanometer and 1000 nanometers, inclusively, and
the alkyl ammonium metal mixed-halide film has a second thickness that is less than the first thickness.
2. The device of claim 1 , wherein the second thickness is between 1 nanometer and 1000 nanometers, inclusively.
3. The device of claim 1 , wherein at least one of the alkyl ammonium metal halide film or the alkyl ammonium metal mixed-halide film further comprises at least one of tin or germanium.
4. The device of claim 1 , wherein the alkyl ammonium metal halide film comprises at least one of CH 3 NH 3 PbI 3 or CH(NH 2 ) 2 PbI 3 .
5. The device of claim 1 , wherein:
the alkyl ammonium lead mixed-halide film comprises at least one of CH 3 NH 3 PbI 3-x Br x or CH(NH 2 ) 2 PbI 3-x Br x , and
x is between greater than 0 and less than 3.
6. The device of claim 1 , wherein the first thickness is between 3 nanometers and 300 nanometers, inclusively.
7. The device of claim 1 , wherein the alkyl ammonium metal mixed-halide film further comprises a peak location at 14.14 degrees.